Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes

We describe the structural features and magnetic properties of two polynuclear copper(II) complexes containing a redox-active ligand. These neutral complexes each bear the formula RL4Cu4 (R = tBu, Me) with the ligand in a dianion-aminyl radical oxidation state. X-ray data and density functional the...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Inorganic chemistry 2018-05, Vol.57 (9), p.4837-4840
Hauptverfasser:	Bonanno, Nico M, Lough, Alan J, Lemaire, Martin T
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	4840
container_issue	9
container_start_page	4837
container_title	Inorganic chemistry
container_volume	57
creator	Bonanno, Nico M Lough, Alan J Lemaire, Martin T
description	We describe the structural features and magnetic properties of two polynuclear copper(II) complexes containing a redox-active ligand. These neutral complexes each bear the formula RL4Cu4 (R = tBu, Me) with the ligand in a dianion-aminyl radical oxidation state. X-ray data and density functional theory calculations support an aminyl-type radical character in these complexes, making these the first polynuclear metal aminyl radical complexes.
doi_str_mv	10.1021/acs.inorgchem.8b00785
format	Article
fullrecord	<record><control><sourceid>proquest_acs_j</sourceid><recordid>TN_cdi_proquest_miscellaneous_2031422583</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2031422583</sourcerecordid><originalsourceid>FETCH-LOGICAL-a230t-bfec65a02f0e12c893dc3591aa9f9eacc3713fda7186aec55e9e36d8b05851973</originalsourceid><addsrcrecordid>eNo9kNFLwzAQxoMoOKd_gtDH-dB5SZq2eZzF6WCgiIJvIUuv2pEmtVnB_fdmbPh03919HN_9CLmlMKfA6L02Yd46P3yZb-zm5QagKMUZmVDBIBUUPs_JBCBqmufyklyFsAUAybN8Qh5evd270VjUQ1KN2TpLKt_3OMxWq7tk0bVub5M3XbdG27jxQ906vWu9i03XW_zFcE0uGm0D3pzqlHwsH9-r53T98rSqFutUMw67dNOgyYUG1gBSZkrJa8OFpFrLRqI2hheUN7UuaJlrNEKgRJ7X8R1RCioLPiWz491-8D8jhp3q2mDQWu3Qj0Ex4DRjTJQ8WunRGtGorR8HF4MpCurASx2G_7zUiRf_A5jTYac</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2031422583</pqid></control><display><type>article</type><title>Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes</title><source>ACS Publications</source><creator>Bonanno, Nico M ; Lough, Alan J ; Lemaire, Martin T</creator><creatorcontrib>Bonanno, Nico M ; Lough, Alan J ; Lemaire, Martin T</creatorcontrib><description>We describe the structural features and magnetic properties of two polynuclear copper(II) complexes containing a redox-active ligand. These neutral complexes each bear the formula RL4Cu4 (R = tBu, Me) with the ligand in a dianion-aminyl radical oxidation state. X-ray data and density functional theory calculations support an aminyl-type radical character in these complexes, making these the first polynuclear metal aminyl radical complexes.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.8b00785</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Inorganic chemistry, 2018-05, Vol.57 (9), p.4837-4840</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-0452-8238</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b00785$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.8b00785$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Bonanno, Nico M</creatorcontrib><creatorcontrib>Lough, Alan J</creatorcontrib><creatorcontrib>Lemaire, Martin T</creatorcontrib><title>Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>We describe the structural features and magnetic properties of two polynuclear copper(II) complexes containing a redox-active ligand. These neutral complexes each bear the formula RL4Cu4 (R = tBu, Me) with the ligand in a dianion-aminyl radical oxidation state. X-ray data and density functional theory calculations support an aminyl-type radical character in these complexes, making these the first polynuclear metal aminyl radical complexes.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9kNFLwzAQxoMoOKd_gtDH-dB5SZq2eZzF6WCgiIJvIUuv2pEmtVnB_fdmbPh03919HN_9CLmlMKfA6L02Yd46P3yZb-zm5QagKMUZmVDBIBUUPs_JBCBqmufyklyFsAUAybN8Qh5evd270VjUQ1KN2TpLKt_3OMxWq7tk0bVub5M3XbdG27jxQ906vWu9i03XW_zFcE0uGm0D3pzqlHwsH9-r53T98rSqFutUMw67dNOgyYUG1gBSZkrJa8OFpFrLRqI2hheUN7UuaJlrNEKgRJ7X8R1RCioLPiWz491-8D8jhp3q2mDQWu3Qj0Ex4DRjTJQ8WunRGtGorR8HF4MpCurASx2G_7zUiRf_A5jTYac</recordid><startdate>20180507</startdate><enddate>20180507</enddate><creator>Bonanno, Nico M</creator><creator>Lough, Alan J</creator><creator>Lemaire, Martin T</creator><general>American Chemical Society</general><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0452-8238</orcidid></search><sort><creationdate>20180507</creationdate><title>Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes</title><author>Bonanno, Nico M ; Lough, Alan J ; Lemaire, Martin T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a230t-bfec65a02f0e12c893dc3591aa9f9eacc3713fda7186aec55e9e36d8b05851973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bonanno, Nico M</creatorcontrib><creatorcontrib>Lough, Alan J</creatorcontrib><creatorcontrib>Lemaire, Martin T</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bonanno, Nico M</au><au>Lough, Alan J</au><au>Lemaire, Martin T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2018-05-07</date><risdate>2018</risdate><volume>57</volume><issue>9</issue><spage>4837</spage><epage>4840</epage><pages>4837-4840</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>We describe the structural features and magnetic properties of two polynuclear copper(II) complexes containing a redox-active ligand. These neutral complexes each bear the formula RL4Cu4 (R = tBu, Me) with the ligand in a dianion-aminyl radical oxidation state. X-ray data and density functional theory calculations support an aminyl-type radical character in these complexes, making these the first polynuclear metal aminyl radical complexes.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.inorgchem.8b00785</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-0452-8238</orcidid></addata></record>
fulltext	fulltext
identifier	ISSN: 0020-1669
ispartof	Inorganic chemistry, 2018-05, Vol.57 (9), p.4837-4840
issn	0020-1669 1520-510X
language	eng
recordid	cdi_proquest_miscellaneous_2031422583
source	ACS Publications
title	Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T14%3A24%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_acs_j&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polynuclear%20Cu4L4%20Copper(II)%20Aminyl%20Radical%20Coordination%20Complexes&rft.jtitle=Inorganic%20chemistry&rft.au=Bonanno,%20Nico%20M&rft.date=2018-05-07&rft.volume=57&rft.issue=9&rft.spage=4837&rft.epage=4840&rft.pages=4837-4840&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.8b00785&rft_dat=%3Cproquest_acs_j%3E2031422583%3C/proquest_acs_j%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2031422583&rft_id=info:pmid/&rfr_iscdi=true