Hoveyda–Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions

Hoveyda–Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions

A one-pot reaction to synthesize functionalized 2H-azirines through visible-light-mediated ring contraction and olefin metathesis of isoxazoles is described. Hoveyda–Grubbs II catalyst was found to function as a photocatalyst for these transformations, allowing these processes to be carried out in a...

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Veröffentlicht in:Organic letters 2018-05, Vol.20 (9), p.2774-2777
Hauptverfasser: Ge, Yun, Sun, Wangbin, Pei, Bingbing, Ding, Jia, Jiang, Yaojia, Loh, Teck-Peng
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container_issue 9
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container_title Organic letters
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creator Ge, Yun
Sun, Wangbin
Pei, Bingbing
Ding, Jia
Jiang, Yaojia
Loh, Teck-Peng
description A one-pot reaction to synthesize functionalized 2H-azirines through visible-light-mediated ring contraction and olefin metathesis of isoxazoles is described. Hoveyda–Grubbs II catalyst was found to function as a photocatalyst for these transformations, allowing these processes to be carried out in a one-pot manner. This study offers a new entry for the application of Grubbs catalysts as efficient photocatalysts and the possibilities of carrying out other photoreactions and olefin metathesis in a one-pot process.
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title Hoveyda–Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions
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