A Bis(μ‐oxido)dinickel(III) Complex with a Triplet Ground State

A bis(μ‐oxido)dinickel(III) complex was synthesized and characterized by single crystal X‐ray diffraction, resonance Raman, and ESI‐mass measurements. Magnetic susceptibility measurements by SQUID and EPR spectroscopy reveal that the complex has a triplet ground state, which is unprecedented for hig...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-06, Vol.57 (26), p.7640-7643
Hauptverfasser:	Morimoto, Yuma, Takagi, Yusaku, Saito, Toru, Ohta, Takehiro, Ogura, Takashi, Tohnai, Norimitsu, Nakano, Motohiro, Itoh, Shinobu
Format:	Artikel
Sprache:	eng
Schlagworte:	bis(μ-oxido) complexes Coordination compounds Diamonds Ferromagnetism Ground state Magnetic permeability magnetic properties Magnetic resonance Magnetic susceptibility Nickel oxidation Oxygenation reactive intermediates Single crystals Spectroscopy Substrates Superconducting quantum interference devices X-ray diffraction
Online-Zugang:	Volltext
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