One-step sonochemical synthesis of 1D β-stannous tungstate nanorods: An efficient and excellent electrocatalyst for the selective electrochemical detection of antipsychotic drug chlorpromazine
[Display omitted] •One-dimensional β-SnW nanorods were prepared by simple sonochemical approach.•The β-SnW NRs based sensor exhibit excellent performance towards CPZ detection.•The proposed sensor showed a low detection limit and good selectivity.•The proposed sensor was successfully applied in dete...
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Veröffentlicht in: | Ultrasonics sonochemistry 2018-06, Vol.44, p.231-239 |
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creator | Kokulnathan, Thangavelu Kumar, Jeyaraj Vinoth Chen, Shen-Ming Karthik, Raj Elangovan, Arumugam Muthuraj, Velluchamy |
description | [Display omitted]
•One-dimensional β-SnW nanorods were prepared by simple sonochemical approach.•The β-SnW NRs based sensor exhibit excellent performance towards CPZ detection.•The proposed sensor showed a low detection limit and good selectivity.•The proposed sensor was successfully applied in detection of CPZ in real samples.
In the modern world, the contamination of ecosystem by human and veterinary pharmaceutical drugs through the metabolic excretion, improper disposal/industrial waste has been subjected to a hot issue. Therefore, exploitation of exclusive structured material and reliable technique is a necessary task to the precise detection of drugs. With this regards, we made an effort for the fabrication of novel one-dimensional (1D) stannous tungstate nanorods (β-SnW NRs) via simple sonochemical approach and used as an electrochemical sensor for the detection of antipsychotic drug chlorpromazine (CPZ) for the first time. The crystallographic structure, surface topology, elemental compositions and their distributions and ionic states were enquired by different spectroscopic techniques such as XRD, FTIR, SEM, EDS, elemental mapping and XPS analysis. The developed β-SnW NRs/GCE sensor exhibits a rapid and sensitive electrochemical response towards CPZ sensing with wide linear response range (0.01–457 µM), high sensitivity (2.487 µA µM−1 cm−2), low detection limit (0.003 µM) and excellent selectivity. Besides, the as-proposed electrochemical sensor was successfully applied to real sample analysis in commercial CPZ drug and biological fluids and the acquired recovery results are quite satisfactory. The proposed sonochemical method for the preparation of β-SnW NRs is low cost, very simple, fast and efficient for sensor applications. |
doi_str_mv | 10.1016/j.ultsonch.2018.02.025 |
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•One-dimensional β-SnW nanorods were prepared by simple sonochemical approach.•The β-SnW NRs based sensor exhibit excellent performance towards CPZ detection.•The proposed sensor showed a low detection limit and good selectivity.•The proposed sensor was successfully applied in detection of CPZ in real samples.
In the modern world, the contamination of ecosystem by human and veterinary pharmaceutical drugs through the metabolic excretion, improper disposal/industrial waste has been subjected to a hot issue. Therefore, exploitation of exclusive structured material and reliable technique is a necessary task to the precise detection of drugs. With this regards, we made an effort for the fabrication of novel one-dimensional (1D) stannous tungstate nanorods (β-SnW NRs) via simple sonochemical approach and used as an electrochemical sensor for the detection of antipsychotic drug chlorpromazine (CPZ) for the first time. The crystallographic structure, surface topology, elemental compositions and their distributions and ionic states were enquired by different spectroscopic techniques such as XRD, FTIR, SEM, EDS, elemental mapping and XPS analysis. The developed β-SnW NRs/GCE sensor exhibits a rapid and sensitive electrochemical response towards CPZ sensing with wide linear response range (0.01–457 µM), high sensitivity (2.487 µA µM−1 cm−2), low detection limit (0.003 µM) and excellent selectivity. Besides, the as-proposed electrochemical sensor was successfully applied to real sample analysis in commercial CPZ drug and biological fluids and the acquired recovery results are quite satisfactory. The proposed sonochemical method for the preparation of β-SnW NRs is low cost, very simple, fast and efficient for sensor applications.</description><identifier>ISSN: 1350-4177</identifier><identifier>EISSN: 1873-2828</identifier><identifier>DOI: 10.1016/j.ultsonch.2018.02.025</identifier><identifier>PMID: 29680607</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Antipsychotic Agents - analysis ; Biological samples ; Chlorpromazine ; Chlorpromazine - analysis ; Electrochemical sensor ; Electrochemical Techniques - methods ; Limit of Detection ; Nanotubes ; Pharmaceutical drug ; Photoelectron Spectroscopy ; Powder Diffraction ; Sonication ; Sonochemical approach ; Spectrometry, X-Ray Emission ; Spectroscopy, Fourier Transform Infrared ; Stannous tungstate ; Tin - chemistry ; Tungsten - chemistry</subject><ispartof>Ultrasonics sonochemistry, 2018-06, Vol.44, p.231-239</ispartof><rights>2018 Elsevier B.V.</rights><rights>Copyright © 2018 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-325f2a0e5251a4c8ba0ded9a1a0192eb55e5e19bb8e58a4b380656c24c9b35b43</citedby><cites>FETCH-LOGICAL-c368t-325f2a0e5251a4c8ba0ded9a1a0192eb55e5e19bb8e58a4b380656c24c9b35b43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1350417718302256$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29680607$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kokulnathan, Thangavelu</creatorcontrib><creatorcontrib>Kumar, Jeyaraj Vinoth</creatorcontrib><creatorcontrib>Chen, Shen-Ming</creatorcontrib><creatorcontrib>Karthik, Raj</creatorcontrib><creatorcontrib>Elangovan, Arumugam</creatorcontrib><creatorcontrib>Muthuraj, Velluchamy</creatorcontrib><title>One-step sonochemical synthesis of 1D β-stannous tungstate nanorods: An efficient and excellent electrocatalyst for the selective electrochemical detection of antipsychotic drug chlorpromazine</title><title>Ultrasonics sonochemistry</title><addtitle>Ultrason Sonochem</addtitle><description>[Display omitted]
•One-dimensional β-SnW nanorods were prepared by simple sonochemical approach.•The β-SnW NRs based sensor exhibit excellent performance towards CPZ detection.•The proposed sensor showed a low detection limit and good selectivity.•The proposed sensor was successfully applied in detection of CPZ in real samples.
In the modern world, the contamination of ecosystem by human and veterinary pharmaceutical drugs through the metabolic excretion, improper disposal/industrial waste has been subjected to a hot issue. Therefore, exploitation of exclusive structured material and reliable technique is a necessary task to the precise detection of drugs. With this regards, we made an effort for the fabrication of novel one-dimensional (1D) stannous tungstate nanorods (β-SnW NRs) via simple sonochemical approach and used as an electrochemical sensor for the detection of antipsychotic drug chlorpromazine (CPZ) for the first time. The crystallographic structure, surface topology, elemental compositions and their distributions and ionic states were enquired by different spectroscopic techniques such as XRD, FTIR, SEM, EDS, elemental mapping and XPS analysis. The developed β-SnW NRs/GCE sensor exhibits a rapid and sensitive electrochemical response towards CPZ sensing with wide linear response range (0.01–457 µM), high sensitivity (2.487 µA µM−1 cm−2), low detection limit (0.003 µM) and excellent selectivity. Besides, the as-proposed electrochemical sensor was successfully applied to real sample analysis in commercial CPZ drug and biological fluids and the acquired recovery results are quite satisfactory. The proposed sonochemical method for the preparation of β-SnW NRs is low cost, very simple, fast and efficient for sensor applications.</description><subject>Antipsychotic Agents - analysis</subject><subject>Biological samples</subject><subject>Chlorpromazine</subject><subject>Chlorpromazine - analysis</subject><subject>Electrochemical sensor</subject><subject>Electrochemical Techniques - methods</subject><subject>Limit of Detection</subject><subject>Nanotubes</subject><subject>Pharmaceutical drug</subject><subject>Photoelectron Spectroscopy</subject><subject>Powder Diffraction</subject><subject>Sonication</subject><subject>Sonochemical approach</subject><subject>Spectrometry, X-Ray Emission</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Stannous tungstate</subject><subject>Tin - chemistry</subject><subject>Tungsten - chemistry</subject><issn>1350-4177</issn><issn>1873-2828</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFUdtu1DAQjRCIlsIvVH7kJcvYjrMOT1TlKlXqCzxbjj1pvErsxXYqls_iD_gBvgmH7fYVaSR7NGfO0ZxTVZcUNhRo-2a3WaacgjfjhgGVG2ClxJPqnMotr5lk8mn5cwF1Q7fbs-pFSjsA4B2D59UZ61oJLWzPq9-3HuuUcU8KWTAjzs7oiaSDzyMml0gYCH1P_vwqIO19WBLJi78rTUbitQ8x2PSWXHmCw-CMQ5-J9pbgD4PTtHY4ockxGJ31dEiZDCGSwk3Sv4G7x0fESdxiXifBr-LaZ7dPBzOG7AyxcbkjZpxC3Mcw65_O48vq2aCnhK8e3ovq28cPX68_1ze3n75cX93Uhrcy15yJgWlAwQTVjZG9Bou201QD7Rj2QqBA2vW9RCF10_NikGgNa0zXc9E3_KJ6feQtyt8XTFnNLq1Hao_FFsWguMpFB22BtkeoiSGliIPaRzfreFAU1Bqf2qlTfGqNTwErJcri5YPG0s9oH9dOeRXAuyMAy6X3DqNKq-cGrYvFM2WD-5_GX1Yvtuw</recordid><startdate>201806</startdate><enddate>201806</enddate><creator>Kokulnathan, Thangavelu</creator><creator>Kumar, Jeyaraj Vinoth</creator><creator>Chen, Shen-Ming</creator><creator>Karthik, Raj</creator><creator>Elangovan, Arumugam</creator><creator>Muthuraj, Velluchamy</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>201806</creationdate><title>One-step sonochemical synthesis of 1D β-stannous tungstate nanorods: An efficient and excellent electrocatalyst for the selective electrochemical detection of antipsychotic drug chlorpromazine</title><author>Kokulnathan, Thangavelu ; Kumar, Jeyaraj Vinoth ; Chen, Shen-Ming ; Karthik, Raj ; Elangovan, Arumugam ; Muthuraj, Velluchamy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-325f2a0e5251a4c8ba0ded9a1a0192eb55e5e19bb8e58a4b380656c24c9b35b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Antipsychotic Agents - analysis</topic><topic>Biological samples</topic><topic>Chlorpromazine</topic><topic>Chlorpromazine - analysis</topic><topic>Electrochemical sensor</topic><topic>Electrochemical Techniques - methods</topic><topic>Limit of Detection</topic><topic>Nanotubes</topic><topic>Pharmaceutical drug</topic><topic>Photoelectron Spectroscopy</topic><topic>Powder Diffraction</topic><topic>Sonication</topic><topic>Sonochemical approach</topic><topic>Spectrometry, X-Ray Emission</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Stannous tungstate</topic><topic>Tin - chemistry</topic><topic>Tungsten - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kokulnathan, Thangavelu</creatorcontrib><creatorcontrib>Kumar, Jeyaraj Vinoth</creatorcontrib><creatorcontrib>Chen, Shen-Ming</creatorcontrib><creatorcontrib>Karthik, Raj</creatorcontrib><creatorcontrib>Elangovan, Arumugam</creatorcontrib><creatorcontrib>Muthuraj, Velluchamy</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Ultrasonics sonochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kokulnathan, Thangavelu</au><au>Kumar, Jeyaraj Vinoth</au><au>Chen, Shen-Ming</au><au>Karthik, Raj</au><au>Elangovan, Arumugam</au><au>Muthuraj, Velluchamy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-step sonochemical synthesis of 1D β-stannous tungstate nanorods: An efficient and excellent electrocatalyst for the selective electrochemical detection of antipsychotic drug chlorpromazine</atitle><jtitle>Ultrasonics sonochemistry</jtitle><addtitle>Ultrason Sonochem</addtitle><date>2018-06</date><risdate>2018</risdate><volume>44</volume><spage>231</spage><epage>239</epage><pages>231-239</pages><issn>1350-4177</issn><eissn>1873-2828</eissn><abstract>[Display omitted]
•One-dimensional β-SnW nanorods were prepared by simple sonochemical approach.•The β-SnW NRs based sensor exhibit excellent performance towards CPZ detection.•The proposed sensor showed a low detection limit and good selectivity.•The proposed sensor was successfully applied in detection of CPZ in real samples.
In the modern world, the contamination of ecosystem by human and veterinary pharmaceutical drugs through the metabolic excretion, improper disposal/industrial waste has been subjected to a hot issue. Therefore, exploitation of exclusive structured material and reliable technique is a necessary task to the precise detection of drugs. With this regards, we made an effort for the fabrication of novel one-dimensional (1D) stannous tungstate nanorods (β-SnW NRs) via simple sonochemical approach and used as an electrochemical sensor for the detection of antipsychotic drug chlorpromazine (CPZ) for the first time. The crystallographic structure, surface topology, elemental compositions and their distributions and ionic states were enquired by different spectroscopic techniques such as XRD, FTIR, SEM, EDS, elemental mapping and XPS analysis. The developed β-SnW NRs/GCE sensor exhibits a rapid and sensitive electrochemical response towards CPZ sensing with wide linear response range (0.01–457 µM), high sensitivity (2.487 µA µM−1 cm−2), low detection limit (0.003 µM) and excellent selectivity. Besides, the as-proposed electrochemical sensor was successfully applied to real sample analysis in commercial CPZ drug and biological fluids and the acquired recovery results are quite satisfactory. The proposed sonochemical method for the preparation of β-SnW NRs is low cost, very simple, fast and efficient for sensor applications.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>29680607</pmid><doi>10.1016/j.ultsonch.2018.02.025</doi><tpages>9</tpages></addata></record> |
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subjects | Antipsychotic Agents - analysis Biological samples Chlorpromazine Chlorpromazine - analysis Electrochemical sensor Electrochemical Techniques - methods Limit of Detection Nanotubes Pharmaceutical drug Photoelectron Spectroscopy Powder Diffraction Sonication Sonochemical approach Spectrometry, X-Ray Emission Spectroscopy, Fourier Transform Infrared Stannous tungstate Tin - chemistry Tungsten - chemistry |
title | One-step sonochemical synthesis of 1D β-stannous tungstate nanorods: An efficient and excellent electrocatalyst for the selective electrochemical detection of antipsychotic drug chlorpromazine |
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