Group 3 metal trihalide complexes with neutral N-donor ligands - exploring their affinity towards fluoride

Fluorination of [ScCl3(Me3-tacn)] (Me3-tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) and [ScCl3(BnMe2-tacn)] (BnMe2-tacn = 1,4-dimethyl-7-benzyl-1,4,7-triazacyclononane) by Cl/F exchange with 3 mol. equiv. of anhydrous [NMe4]F in CH3CN solution yields the corresponding [ScF3(R3-tacn)] (R3 = Me3 or...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (17), p.6059-6068
Hauptverfasser:	Curnock, Emily, Levason, William, Light, Mark E, Luthra, Sajinder K, McRobbie, Graeme, Monzittu, Francesco M, Reid, Gillian, Williams, R Nathan
Format:	Artikel
Sprache:	eng
Schlagworte:	Bimetals Coordination compounds Crystal structure Decomposition Fluorides Fluorination Hydrates Lewis acid Ligands NMR Nuclear magnetic resonance Positron emission Precursors Scandium Tomography
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