Concentrations of booster biocides in sediment and clams from Vietnam

An analytical method for the simultaneous determination of five booster biocides (Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051 and Pyrithiones) and degradation product of Irgarol 1051 (M1) in sediment from Vietnam was developed by LC/MS-MS. The recovery rates and relative standard deviation of...

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Veröffentlicht in:Journal of the Marine Biological Association of the United Kingdom 2006-10, Vol.86 (5), p.1163-1170
Hauptverfasser: Harino, Hiroya, Midorikawa, Sayaka, Arai, Takaomi, Ohji, Madoka, Cu, Nguyen Duc, Miyazaki, Nobuyuki
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container_issue 5
container_start_page 1163
container_title Journal of the Marine Biological Association of the United Kingdom
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creator Harino, Hiroya
Midorikawa, Sayaka
Arai, Takaomi
Ohji, Madoka
Cu, Nguyen Duc
Miyazaki, Nobuyuki
description An analytical method for the simultaneous determination of five booster biocides (Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051 and Pyrithiones) and degradation product of Irgarol 1051 (M1) in sediment from Vietnam was developed by LC/MS-MS. The recovery rates and relative standard deviation of the booster biocides in the sediment were in the range of 71–108% and 1.5–12%, respectively, and the detection limits were in the range of 0.04–2 μg kg−1 dry. An analytical method for the simultaneous determination of three booster biocides (Sea-Nine 211, Duiron and Irgarol 1051) and M1 in clams was also developed by LC/MS-MS. The recovery rates and relative standard deviations of the booster biocides in the biological samples were in the range of 60–99% and 3.4–6.8%, respectively, and the detection limits were in the range of 0.24–1.1 μg kg−1. The booster biocides in sediment from the coastal area of northern and central Vietnam were measured using this analytical method. Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051, M1 and Pyrithiones were detected in the range of 0.09–1.3 μg kg−1 dry,
doi_str_mv 10.1017/S0025315406014147
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The recovery rates and relative standard deviation of the booster biocides in the sediment were in the range of 71–108% and 1.5–12%, respectively, and the detection limits were in the range of 0.04–2 μg kg−1 dry. An analytical method for the simultaneous determination of three booster biocides (Sea-Nine 211, Duiron and Irgarol 1051) and M1 in clams was also developed by LC/MS-MS. The recovery rates and relative standard deviations of the booster biocides in the biological samples were in the range of 60–99% and 3.4–6.8%, respectively, and the detection limits were in the range of 0.24–1.1 μg kg−1. The booster biocides in sediment from the coastal area of northern and central Vietnam were measured using this analytical method. Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051, M1 and Pyrithiones were detected in the range of 0.09–1.3 μg kg−1 dry, &lt;0.10–13 μg kg−1 dry, 0.11–3.0 μg kg−1 dry, 0.05–4.0 μg kg−1 dry, &lt;0.1–0.43 μg kg−1 dry and &lt;2–420 μg kg−1 dry, respectively. The detection frequencies of Dichlofluanid, M1 and Pyrithiones were low. The species and levels of detected booster biocides varied between sampling stations. Irgarol 1051 and its degradation product M1 were not detected in clams.</description><identifier>ISSN: 0025-3154</identifier><identifier>EISSN: 1469-7769</identifier><identifier>DOI: 10.1017/S0025315406014147</identifier><identifier>CODEN: JMBAAK</identifier><language>eng</language><publisher>Cambridge, UK: Cambridge University Press</publisher><subject>Analytical chemistry ; Analytical methods ; Animal and plant ecology ; Animal, plant and microbial ecology ; Biocides ; Biological and medical sciences ; Biological samples ; Coastal zone ; Coasts ; Detection limits ; Fundamental and applied biological sciences. 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Mar. Biol. Ass</addtitle><description>An analytical method for the simultaneous determination of five booster biocides (Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051 and Pyrithiones) and degradation product of Irgarol 1051 (M1) in sediment from Vietnam was developed by LC/MS-MS. The recovery rates and relative standard deviation of the booster biocides in the sediment were in the range of 71–108% and 1.5–12%, respectively, and the detection limits were in the range of 0.04–2 μg kg−1 dry. An analytical method for the simultaneous determination of three booster biocides (Sea-Nine 211, Duiron and Irgarol 1051) and M1 in clams was also developed by LC/MS-MS. The recovery rates and relative standard deviations of the booster biocides in the biological samples were in the range of 60–99% and 3.4–6.8%, respectively, and the detection limits were in the range of 0.24–1.1 μg kg−1. The booster biocides in sediment from the coastal area of northern and central Vietnam were measured using this analytical method. Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051, M1 and Pyrithiones were detected in the range of 0.09–1.3 μg kg−1 dry, &lt;0.10–13 μg kg−1 dry, 0.11–3.0 μg kg−1 dry, 0.05–4.0 μg kg−1 dry, &lt;0.1–0.43 μg kg−1 dry and &lt;2–420 μg kg−1 dry, respectively. The detection frequencies of Dichlofluanid, M1 and Pyrithiones were low. The species and levels of detected booster biocides varied between sampling stations. 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Mar. Biol. Ass</addtitle><date>2006-10-01</date><risdate>2006</risdate><volume>86</volume><issue>5</issue><spage>1163</spage><epage>1170</epage><pages>1163-1170</pages><issn>0025-3154</issn><eissn>1469-7769</eissn><coden>JMBAAK</coden><abstract>An analytical method for the simultaneous determination of five booster biocides (Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051 and Pyrithiones) and degradation product of Irgarol 1051 (M1) in sediment from Vietnam was developed by LC/MS-MS. The recovery rates and relative standard deviation of the booster biocides in the sediment were in the range of 71–108% and 1.5–12%, respectively, and the detection limits were in the range of 0.04–2 μg kg−1 dry. An analytical method for the simultaneous determination of three booster biocides (Sea-Nine 211, Duiron and Irgarol 1051) and M1 in clams was also developed by LC/MS-MS. The recovery rates and relative standard deviations of the booster biocides in the biological samples were in the range of 60–99% and 3.4–6.8%, respectively, and the detection limits were in the range of 0.24–1.1 μg kg−1. The booster biocides in sediment from the coastal area of northern and central Vietnam were measured using this analytical method. Sea-Nine 211, Dichlofluanid, Duiron, Irgarol 1051, M1 and Pyrithiones were detected in the range of 0.09–1.3 μg kg−1 dry, &lt;0.10–13 μg kg−1 dry, 0.11–3.0 μg kg−1 dry, 0.05–4.0 μg kg−1 dry, &lt;0.1–0.43 μg kg−1 dry and &lt;2–420 μg kg−1 dry, respectively. The detection frequencies of Dichlofluanid, M1 and Pyrithiones were low. The species and levels of detected booster biocides varied between sampling stations. Irgarol 1051 and its degradation product M1 were not detected in clams.</abstract><cop>Cambridge, UK</cop><pub>Cambridge University Press</pub><doi>10.1017/S0025315406014147</doi><tpages>8</tpages></addata></record>
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subjects Analytical chemistry
Analytical methods
Animal and plant ecology
Animal, plant and microbial ecology
Biocides
Biological and medical sciences
Biological samples
Coastal zone
Coasts
Detection limits
Fundamental and applied biological sciences. Psychology
Invertebrates
Marine
Meretrix
Mollusca
Mollusks
Research Article
Sea water ecosystems
Sediments
Standard deviation
Synecology
title Concentrations of booster biocides in sediment and clams from Vietnam
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