Palladium-Catalyzed Carbene Migratory Insertion and Trapping with Sulfinic Acid Salts toward Allylic Sulfones

Allylic sulfones were synthesized with excellent selectivity and good yield via Pd-catalyzed cross-coupling of vinyl iodide with N-tosylhydrazone. This process involves palladium carbene migratory insertion/​trapping with sulfinic acid salts. For the previous Pd-catalyzed N-tosylhydrazone cross-coup...

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Veröffentlicht in:	Journal of organic chemistry 2018-04, Vol.83 (8), p.4762-4768
Hauptverfasser:	Zhou, Ping-Xin, Zhang, Yalei, Ge, Chunbo, Liang, Yong-Min, Li, Changzheng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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