Pd-Catalyzed Aldehyde to Ester Conversion: A Hydrogen Transfer Approach

Aliphatic and aromatic aldehydes are successfully converted into their corresponding esters using Pd(OAc)2 and XPhos. This approach utilizes a hydrogen transfer protocol: concomitant reduction of acetone to isopropanol provides an inexpensive and sustainable approach that mitigates the need for othe...

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Veröffentlicht in:	Organic letters 2013-02, Vol.15 (3), p.500-503
Hauptverfasser:	Tschaen, Brittany A, Schmink, Jason R, Molander, Gary A
Format:	Artikel
Sprache:	eng
Schlagworte:	acetone aldehydes Aldehydes - chemistry Catalysis catalytic activity chemical reactions chemical structure Combinatorial Chemistry Techniques Esters hydrogen Hydrogen - chemistry isopropyl alcohol Molecular Structure oxidants Oxidation-Reduction palladium Palladium - chemistry
Online-Zugang:	Volltext
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