MOG-derived porous FeCo/C nanocomposites as a potential platform for enhanced catalytic activity and lithium-ion batteries performance
[Display omitted] The transition metal alloy nanoparticles (NPs) have received significant attention because of their unique physicochemical properties as well as low cost. Herein, we report a facile and clean synthetic route to prepare porous FeCo/C bimetallic alloy nanocomposites by using metal-or...
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| Veröffentlicht in: | Journal of colloid and interface science 2018-07, Vol.522, p.283-290 |
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| container_title | Journal of colloid and interface science |
| container_volume | 522 |
| creator | Ke, Fei Li, Yizhi Zhang, Chunyan Zhu, Jing Chen, Peirong Ju, Huanxin Xu, Qian Zhu, Junfa |
| description | [Display omitted]
The transition metal alloy nanoparticles (NPs) have received significant attention because of their unique physicochemical properties as well as low cost. Herein, we report a facile and clean synthetic route to prepare porous FeCo/C bimetallic alloy nanocomposites by using metal-organic gels (MOGs) as precursors. The bimetallic MOGs based on iron and cobalt bridged by tri-carboxylate organic ligands were first synthesized by a general and fast solvothermal method. The desired FeCo/C nanocomposites were then obtained by a one-step annealing process in which MOGs served as both the precursor and the self-sacrificing template. Significantly, the as-synthesized FeCo/C nanocomposites exhibit excellent catalytic activity and lithium-ion batteries performance. This fast and clean synthetic strategy is extended to synthesis diversity and range of potential applications of porous carbon-coated transition-metal alloy nanocomposites. |
| doi_str_mv | 10.1016/j.jcis.2018.03.081 |
| format | Article |
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The transition metal alloy nanoparticles (NPs) have received significant attention because of their unique physicochemical properties as well as low cost. Herein, we report a facile and clean synthetic route to prepare porous FeCo/C bimetallic alloy nanocomposites by using metal-organic gels (MOGs) as precursors. The bimetallic MOGs based on iron and cobalt bridged by tri-carboxylate organic ligands were first synthesized by a general and fast solvothermal method. The desired FeCo/C nanocomposites were then obtained by a one-step annealing process in which MOGs served as both the precursor and the self-sacrificing template. Significantly, the as-synthesized FeCo/C nanocomposites exhibit excellent catalytic activity and lithium-ion batteries performance. This fast and clean synthetic strategy is extended to synthesis diversity and range of potential applications of porous carbon-coated transition-metal alloy nanocomposites.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2018.03.081</identifier><identifier>PMID: 29604447</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Heterogeneous catalysis ; Lithium-ion batteries ; Metal-organic frameworks ; Nanoalloys ; Porous carbon nanocomposites</subject><ispartof>Journal of colloid and interface science, 2018-07, Vol.522, p.283-290</ispartof><rights>2018 Elsevier Inc.</rights><rights>Copyright © 2018 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c393t-cda5e5bbc75142a54ecc3cfa66aca55098d7ba95b10bec8ef2caaf36f83a4b2e3</citedby><cites>FETCH-LOGICAL-c393t-cda5e5bbc75142a54ecc3cfa66aca55098d7ba95b10bec8ef2caaf36f83a4b2e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0021979718303370$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29604447$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ke, Fei</creatorcontrib><creatorcontrib>Li, Yizhi</creatorcontrib><creatorcontrib>Zhang, Chunyan</creatorcontrib><creatorcontrib>Zhu, Jing</creatorcontrib><creatorcontrib>Chen, Peirong</creatorcontrib><creatorcontrib>Ju, Huanxin</creatorcontrib><creatorcontrib>Xu, Qian</creatorcontrib><creatorcontrib>Zhu, Junfa</creatorcontrib><title>MOG-derived porous FeCo/C nanocomposites as a potential platform for enhanced catalytic activity and lithium-ion batteries performance</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>[Display omitted]
The transition metal alloy nanoparticles (NPs) have received significant attention because of their unique physicochemical properties as well as low cost. Herein, we report a facile and clean synthetic route to prepare porous FeCo/C bimetallic alloy nanocomposites by using metal-organic gels (MOGs) as precursors. The bimetallic MOGs based on iron and cobalt bridged by tri-carboxylate organic ligands were first synthesized by a general and fast solvothermal method. The desired FeCo/C nanocomposites were then obtained by a one-step annealing process in which MOGs served as both the precursor and the self-sacrificing template. Significantly, the as-synthesized FeCo/C nanocomposites exhibit excellent catalytic activity and lithium-ion batteries performance. This fast and clean synthetic strategy is extended to synthesis diversity and range of potential applications of porous carbon-coated transition-metal alloy nanocomposites.</description><subject>Heterogeneous catalysis</subject><subject>Lithium-ion batteries</subject><subject>Metal-organic frameworks</subject><subject>Nanoalloys</subject><subject>Porous carbon nanocomposites</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kE1v1DAQhi0EotvCH-CAfOSS1B9xPiQuaEULUlEvcLYmk4nqVRIH27vS_gF-N462cKxkjS_v-4zmYeyDFKUUsr49lAd0sVRCtqXQpWjlK7aTojNFI4V-zXZCKFl0TddcsesYD0JIaUz3ll2prhZVVTU79ufH430xUHAnGvjqgz9Gfkd7f7vnCywe_bz66BJFDvnlRKIlOZj4OkEafZh5HpyWJ1gwExASTOfkkAMmd3LpzGEZ-OTSkzvOhfML7yGlvC8TVwobYWu-Y29GmCK9f_5v2K-7rz_334qHx_vv-y8PBepOpwIHMGT6HhsjKwWmIkSNI9Q1IBgjunZoeuhML0VP2NKoEGDU9dhqqHpF-oZ9unDX4H8fKSY7u4g0TbBQPt0qoUTVat2qHFWXKAYfY6DRrsHNEM5WCrv5twe7-bebfyu0zf5z6eMz_9jPNPyv_BOeA58vAcpXnhwFG9HR5s4FwmQH717i_wVUXpr-</recordid><startdate>20180715</startdate><enddate>20180715</enddate><creator>Ke, Fei</creator><creator>Li, Yizhi</creator><creator>Zhang, Chunyan</creator><creator>Zhu, Jing</creator><creator>Chen, Peirong</creator><creator>Ju, Huanxin</creator><creator>Xu, Qian</creator><creator>Zhu, Junfa</creator><general>Elsevier Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20180715</creationdate><title>MOG-derived porous FeCo/C nanocomposites as a potential platform for enhanced catalytic activity and lithium-ion batteries performance</title><author>Ke, Fei ; Li, Yizhi ; Zhang, Chunyan ; Zhu, Jing ; Chen, Peirong ; Ju, Huanxin ; Xu, Qian ; Zhu, Junfa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c393t-cda5e5bbc75142a54ecc3cfa66aca55098d7ba95b10bec8ef2caaf36f83a4b2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Heterogeneous catalysis</topic><topic>Lithium-ion batteries</topic><topic>Metal-organic frameworks</topic><topic>Nanoalloys</topic><topic>Porous carbon nanocomposites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ke, Fei</creatorcontrib><creatorcontrib>Li, Yizhi</creatorcontrib><creatorcontrib>Zhang, Chunyan</creatorcontrib><creatorcontrib>Zhu, Jing</creatorcontrib><creatorcontrib>Chen, Peirong</creatorcontrib><creatorcontrib>Ju, Huanxin</creatorcontrib><creatorcontrib>Xu, Qian</creatorcontrib><creatorcontrib>Zhu, Junfa</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ke, Fei</au><au>Li, Yizhi</au><au>Zhang, Chunyan</au><au>Zhu, Jing</au><au>Chen, Peirong</au><au>Ju, Huanxin</au><au>Xu, Qian</au><au>Zhu, Junfa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MOG-derived porous FeCo/C nanocomposites as a potential platform for enhanced catalytic activity and lithium-ion batteries performance</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2018-07-15</date><risdate>2018</risdate><volume>522</volume><spage>283</spage><epage>290</epage><pages>283-290</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><abstract>[Display omitted]
The transition metal alloy nanoparticles (NPs) have received significant attention because of their unique physicochemical properties as well as low cost. Herein, we report a facile and clean synthetic route to prepare porous FeCo/C bimetallic alloy nanocomposites by using metal-organic gels (MOGs) as precursors. The bimetallic MOGs based on iron and cobalt bridged by tri-carboxylate organic ligands were first synthesized by a general and fast solvothermal method. The desired FeCo/C nanocomposites were then obtained by a one-step annealing process in which MOGs served as both the precursor and the self-sacrificing template. Significantly, the as-synthesized FeCo/C nanocomposites exhibit excellent catalytic activity and lithium-ion batteries performance. This fast and clean synthetic strategy is extended to synthesis diversity and range of potential applications of porous carbon-coated transition-metal alloy nanocomposites.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>29604447</pmid><doi>10.1016/j.jcis.2018.03.081</doi><tpages>8</tpages></addata></record> |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Heterogeneous catalysis Lithium-ion batteries Metal-organic frameworks Nanoalloys Porous carbon nanocomposites |
| title | MOG-derived porous FeCo/C nanocomposites as a potential platform for enhanced catalytic activity and lithium-ion batteries performance |
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