Macroemulsion-based dispersive magnetic solid phase extraction for preconcentration and determination of copper(II) in gasoline
A new method referred to as microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDM-SPE) is presented for use in the extraction and preconcentration of metal ions from complex organic matrices. MDM-SPE combines the features of magnetic nanoparticles (MNPs) and microemulsions. It was succ...
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| Veröffentlicht in: | Mikrochimica acta (1966) 2018-02, Vol.185 (2), p.99-8, Article 99 |
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| creator | Cunha, Francisco Antônio S. Ferreira, Danilo Tadeu S. Andrade, Willy C. R. Fernandes, Julys Pablo A. Lyra, Wellington S. Pessoa, Amália G. G. de Araujo, Mario Cesar Ugulino |
| description | A new method referred to as microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDM-SPE) is presented for use in the extraction and preconcentration of metal ions from complex organic matrices. MDM-SPE combines the features of magnetic nanoparticles (MNPs) and microemulsions. It was successfully applied to the extraction of copper(II) from gasoline prior to its determination by Graphite Furnace Atomic Absorption Spectrometry (GF-AAS). The material for use in MDM-SPE was obtained by first functionalizing MNPs of the type Fe
3
O
4
@Al
2
O
3
with sodium dodecyl sulfate and the chelator 1-(2-pyridylazo)-2-naphthol (PAN) dispersed in 1-propanol. The resulting functionalized magnetic MNPs were dispersed in a microemulsion prepared from gasoline, buffer, and 1-propanol. After waiting for 5 s (during which the formation of the copper complex on the MNPs is complete), the MNPs are magnetically separated. The complex was then eluted with 2 mol L
−1
HNO
3
, and the eluate submitted to GF-AAS. Various parameters were optimized. Copper(II) can be quantified by this method over a linear range that extends from 2.0 to 10.0 μg·L
−1
. Other figures of merit include (a) a 37 ng·L
−1
detection limit, (b) a repeatability of 1.1%, (c) a reproducibility of 2.1%, and (d) an enrichment factor of nine. The high surface-to-volume ratio of the microemulsion containing the dispersed magnetic sorbent warrants an efficient contact for reaction between copper(II) and the complexing agent, and this results in fast (about 40 s) extraction and pre-concentration of copper(II). MDM-SPE is accurate, precise and efficient. Microemulsions do not break down, and phase separation, heating, laborious, and time-consuming sample preparation, and incorporation of impurities into the graphite furnace (which can generate inaccuracies in GF-AAS analysis) are not needed.
Graphical abstract
Schematic of a new method for Microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDMSPE) using functionalized magnetic nanoparticles (FMNPs). It was applied to the preconcentration of copper(II) in gasoline. |
| doi_str_mv | 10.1007/s00604-017-2634-0 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_2019810105</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A715059034</galeid><sourcerecordid>A715059034</sourcerecordid><originalsourceid>FETCH-LOGICAL-c439t-4dc43b31ddcf8730b873d7eebd176559650fe4869f364fb0b0d2325b3c217e3a3</originalsourceid><addsrcrecordid>eNp1kUtv1TAQhSMEoreFH8AGRWLTLlLGdmLfLKuKx5WK2MDacuzJxVViBztBsOKvMyHlKZAljzX-zpE9pyieMLhkAOp5BpBQV8BUxaWgw71ix2ohqwaUuF_sALishFT8pDjN-RYIlLx-WJzwtmlrKWFXfH1jbIo4LkP2MVSdyehK5_OEKftPWI7mGHD2tsxx8K6cPhBQ4uc5GTuToOxjKqeENgaLgbrfmyaQB86YRh-2TuxLGycyPT8cLkofyqNZDQM-Kh70Zsj4-K6eFe9fvnh3_bq6efvqcH11U9latHNVO6qdYM7Zfq8EdLQ5hdg5-lLTtLKBHuu9bHsh676DDhwXvOmE5UyhMOKsON98pxQ_LphnPfpscRhMwLhkzYG1ewYMGkKf_YXexiUFep1mbcvVXinOf1FHM6D2oY_rTFZTfaVYA00Loibq8h8ULYejp6Fh76n_h4BtAkol54S9npIfTfqiGeg1dL2FrilLvYaugTRP7x68dCO6n4ofKRPANyDTVThi-u1H_3X9BkTRtxA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1992787722</pqid></control><display><type>article</type><title>Macroemulsion-based dispersive magnetic solid phase extraction for preconcentration and determination of copper(II) in gasoline</title><source>SpringerLink Journals</source><creator>Cunha, Francisco Antônio S. ; Ferreira, Danilo Tadeu S. ; Andrade, Willy C. R. ; Fernandes, Julys Pablo A. ; Lyra, Wellington S. ; Pessoa, Amália G. G. ; de Araujo, Mario Cesar Ugulino</creator><creatorcontrib>Cunha, Francisco Antônio S. ; Ferreira, Danilo Tadeu S. ; Andrade, Willy C. R. ; Fernandes, Julys Pablo A. ; Lyra, Wellington S. ; Pessoa, Amália G. G. ; de Araujo, Mario Cesar Ugulino</creatorcontrib><description>A new method referred to as microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDM-SPE) is presented for use in the extraction and preconcentration of metal ions from complex organic matrices. MDM-SPE combines the features of magnetic nanoparticles (MNPs) and microemulsions. It was successfully applied to the extraction of copper(II) from gasoline prior to its determination by Graphite Furnace Atomic Absorption Spectrometry (GF-AAS). The material for use in MDM-SPE was obtained by first functionalizing MNPs of the type Fe
3
O
4
@Al
2
O
3
with sodium dodecyl sulfate and the chelator 1-(2-pyridylazo)-2-naphthol (PAN) dispersed in 1-propanol. The resulting functionalized magnetic MNPs were dispersed in a microemulsion prepared from gasoline, buffer, and 1-propanol. After waiting for 5 s (during which the formation of the copper complex on the MNPs is complete), the MNPs are magnetically separated. The complex was then eluted with 2 mol L
−1
HNO
3
, and the eluate submitted to GF-AAS. Various parameters were optimized. Copper(II) can be quantified by this method over a linear range that extends from 2.0 to 10.0 μg·L
−1
. Other figures of merit include (a) a 37 ng·L
−1
detection limit, (b) a repeatability of 1.1%, (c) a reproducibility of 2.1%, and (d) an enrichment factor of nine. The high surface-to-volume ratio of the microemulsion containing the dispersed magnetic sorbent warrants an efficient contact for reaction between copper(II) and the complexing agent, and this results in fast (about 40 s) extraction and pre-concentration of copper(II). MDM-SPE is accurate, precise and efficient. Microemulsions do not break down, and phase separation, heating, laborious, and time-consuming sample preparation, and incorporation of impurities into the graphite furnace (which can generate inaccuracies in GF-AAS analysis) are not needed.
Graphical abstract
Schematic of a new method for Microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDMSPE) using functionalized magnetic nanoparticles (FMNPs). It was applied to the preconcentration of copper(II) in gasoline.</description><identifier>ISSN: 0026-3672</identifier><identifier>EISSN: 1436-5073</identifier><identifier>DOI: 10.1007/s00604-017-2634-0</identifier><identifier>PMID: 29594660</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Aluminum oxide ; Anabolic steroids ; Analysis ; Analytical Chemistry ; Atomic absorption analysis ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Copper ; Copper compounds ; Dispersion ; Gasoline ; Graphite ; Iron oxides ; Microemulsions ; Microengineering ; Nanochemistry ; Nanotechnology ; Naphthol ; Original Paper ; Phase separation ; Pyridylazonaphthol ; Reproducibility ; Sodium dodecyl sulfate</subject><ispartof>Mikrochimica acta (1966), 2018-02, Vol.185 (2), p.99-8, Article 99</ispartof><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Microchimica Acta is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-4dc43b31ddcf8730b873d7eebd176559650fe4869f364fb0b0d2325b3c217e3a3</citedby><cites>FETCH-LOGICAL-c439t-4dc43b31ddcf8730b873d7eebd176559650fe4869f364fb0b0d2325b3c217e3a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00604-017-2634-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00604-017-2634-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29594660$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cunha, Francisco Antônio S.</creatorcontrib><creatorcontrib>Ferreira, Danilo Tadeu S.</creatorcontrib><creatorcontrib>Andrade, Willy C. R.</creatorcontrib><creatorcontrib>Fernandes, Julys Pablo A.</creatorcontrib><creatorcontrib>Lyra, Wellington S.</creatorcontrib><creatorcontrib>Pessoa, Amália G. G.</creatorcontrib><creatorcontrib>de Araujo, Mario Cesar Ugulino</creatorcontrib><title>Macroemulsion-based dispersive magnetic solid phase extraction for preconcentration and determination of copper(II) in gasoline</title><title>Mikrochimica acta (1966)</title><addtitle>Microchim Acta</addtitle><addtitle>Mikrochim Acta</addtitle><description>A new method referred to as microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDM-SPE) is presented for use in the extraction and preconcentration of metal ions from complex organic matrices. MDM-SPE combines the features of magnetic nanoparticles (MNPs) and microemulsions. It was successfully applied to the extraction of copper(II) from gasoline prior to its determination by Graphite Furnace Atomic Absorption Spectrometry (GF-AAS). The material for use in MDM-SPE was obtained by first functionalizing MNPs of the type Fe
3
O
4
@Al
2
O
3
with sodium dodecyl sulfate and the chelator 1-(2-pyridylazo)-2-naphthol (PAN) dispersed in 1-propanol. The resulting functionalized magnetic MNPs were dispersed in a microemulsion prepared from gasoline, buffer, and 1-propanol. After waiting for 5 s (during which the formation of the copper complex on the MNPs is complete), the MNPs are magnetically separated. The complex was then eluted with 2 mol L
−1
HNO
3
, and the eluate submitted to GF-AAS. Various parameters were optimized. Copper(II) can be quantified by this method over a linear range that extends from 2.0 to 10.0 μg·L
−1
. Other figures of merit include (a) a 37 ng·L
−1
detection limit, (b) a repeatability of 1.1%, (c) a reproducibility of 2.1%, and (d) an enrichment factor of nine. The high surface-to-volume ratio of the microemulsion containing the dispersed magnetic sorbent warrants an efficient contact for reaction between copper(II) and the complexing agent, and this results in fast (about 40 s) extraction and pre-concentration of copper(II). MDM-SPE is accurate, precise and efficient. Microemulsions do not break down, and phase separation, heating, laborious, and time-consuming sample preparation, and incorporation of impurities into the graphite furnace (which can generate inaccuracies in GF-AAS analysis) are not needed.
Graphical abstract
Schematic of a new method for Microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDMSPE) using functionalized magnetic nanoparticles (FMNPs). It was applied to the preconcentration of copper(II) in gasoline.</description><subject>Aluminum oxide</subject><subject>Anabolic steroids</subject><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Atomic absorption analysis</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Dispersion</subject><subject>Gasoline</subject><subject>Graphite</subject><subject>Iron oxides</subject><subject>Microemulsions</subject><subject>Microengineering</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Naphthol</subject><subject>Original Paper</subject><subject>Phase separation</subject><subject>Pyridylazonaphthol</subject><subject>Reproducibility</subject><subject>Sodium dodecyl sulfate</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kUtv1TAQhSMEoreFH8AGRWLTLlLGdmLfLKuKx5WK2MDacuzJxVViBztBsOKvMyHlKZAljzX-zpE9pyieMLhkAOp5BpBQV8BUxaWgw71ix2ohqwaUuF_sALishFT8pDjN-RYIlLx-WJzwtmlrKWFXfH1jbIo4LkP2MVSdyehK5_OEKftPWI7mGHD2tsxx8K6cPhBQ4uc5GTuToOxjKqeENgaLgbrfmyaQB86YRh-2TuxLGycyPT8cLkofyqNZDQM-Kh70Zsj4-K6eFe9fvnh3_bq6efvqcH11U9latHNVO6qdYM7Zfq8EdLQ5hdg5-lLTtLKBHuu9bHsh676DDhwXvOmE5UyhMOKsON98pxQ_LphnPfpscRhMwLhkzYG1ewYMGkKf_YXexiUFep1mbcvVXinOf1FHM6D2oY_rTFZTfaVYA00Loibq8h8ULYejp6Fh76n_h4BtAkol54S9npIfTfqiGeg1dL2FrilLvYaugTRP7x68dCO6n4ofKRPANyDTVThi-u1H_3X9BkTRtxA</recordid><startdate>20180201</startdate><enddate>20180201</enddate><creator>Cunha, Francisco Antônio S.</creator><creator>Ferreira, Danilo Tadeu S.</creator><creator>Andrade, Willy C. R.</creator><creator>Fernandes, Julys Pablo A.</creator><creator>Lyra, Wellington S.</creator><creator>Pessoa, Amália G. G.</creator><creator>de Araujo, Mario Cesar Ugulino</creator><general>Springer Vienna</general><general>Springer</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>KB.</scope><scope>M0S</scope><scope>M1P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope></search><sort><creationdate>20180201</creationdate><title>Macroemulsion-based dispersive magnetic solid phase extraction for preconcentration and determination of copper(II) in gasoline</title><author>Cunha, Francisco Antônio S. ; Ferreira, Danilo Tadeu S. ; Andrade, Willy C. R. ; Fernandes, Julys Pablo A. ; Lyra, Wellington S. ; Pessoa, Amália G. G. ; de Araujo, Mario Cesar Ugulino</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-4dc43b31ddcf8730b873d7eebd176559650fe4869f364fb0b0d2325b3c217e3a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aluminum oxide</topic><topic>Anabolic steroids</topic><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Atomic absorption analysis</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Dispersion</topic><topic>Gasoline</topic><topic>Graphite</topic><topic>Iron oxides</topic><topic>Microemulsions</topic><topic>Microengineering</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Naphthol</topic><topic>Original Paper</topic><topic>Phase separation</topic><topic>Pyridylazonaphthol</topic><topic>Reproducibility</topic><topic>Sodium dodecyl sulfate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cunha, Francisco Antônio S.</creatorcontrib><creatorcontrib>Ferreira, Danilo Tadeu S.</creatorcontrib><creatorcontrib>Andrade, Willy C. R.</creatorcontrib><creatorcontrib>Fernandes, Julys Pablo A.</creatorcontrib><creatorcontrib>Lyra, Wellington S.</creatorcontrib><creatorcontrib>Pessoa, Amália G. G.</creatorcontrib><creatorcontrib>de Araujo, Mario Cesar Ugulino</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cunha, Francisco Antônio S.</au><au>Ferreira, Danilo Tadeu S.</au><au>Andrade, Willy C. R.</au><au>Fernandes, Julys Pablo A.</au><au>Lyra, Wellington S.</au><au>Pessoa, Amália G. G.</au><au>de Araujo, Mario Cesar Ugulino</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Macroemulsion-based dispersive magnetic solid phase extraction for preconcentration and determination of copper(II) in gasoline</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><addtitle>Mikrochim Acta</addtitle><date>2018-02-01</date><risdate>2018</risdate><volume>185</volume><issue>2</issue><spage>99</spage><epage>8</epage><pages>99-8</pages><artnum>99</artnum><issn>0026-3672</issn><eissn>1436-5073</eissn><abstract>A new method referred to as microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDM-SPE) is presented for use in the extraction and preconcentration of metal ions from complex organic matrices. MDM-SPE combines the features of magnetic nanoparticles (MNPs) and microemulsions. It was successfully applied to the extraction of copper(II) from gasoline prior to its determination by Graphite Furnace Atomic Absorption Spectrometry (GF-AAS). The material for use in MDM-SPE was obtained by first functionalizing MNPs of the type Fe
3
O
4
@Al
2
O
3
with sodium dodecyl sulfate and the chelator 1-(2-pyridylazo)-2-naphthol (PAN) dispersed in 1-propanol. The resulting functionalized magnetic MNPs were dispersed in a microemulsion prepared from gasoline, buffer, and 1-propanol. After waiting for 5 s (during which the formation of the copper complex on the MNPs is complete), the MNPs are magnetically separated. The complex was then eluted with 2 mol L
−1
HNO
3
, and the eluate submitted to GF-AAS. Various parameters were optimized. Copper(II) can be quantified by this method over a linear range that extends from 2.0 to 10.0 μg·L
−1
. Other figures of merit include (a) a 37 ng·L
−1
detection limit, (b) a repeatability of 1.1%, (c) a reproducibility of 2.1%, and (d) an enrichment factor of nine. The high surface-to-volume ratio of the microemulsion containing the dispersed magnetic sorbent warrants an efficient contact for reaction between copper(II) and the complexing agent, and this results in fast (about 40 s) extraction and pre-concentration of copper(II). MDM-SPE is accurate, precise and efficient. Microemulsions do not break down, and phase separation, heating, laborious, and time-consuming sample preparation, and incorporation of impurities into the graphite furnace (which can generate inaccuracies in GF-AAS analysis) are not needed.
Graphical abstract
Schematic of a new method for Microemulsion-based Dispersive Magnetic Solid-Phase Extraction (MDMSPE) using functionalized magnetic nanoparticles (FMNPs). It was applied to the preconcentration of copper(II) in gasoline.</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><pmid>29594660</pmid><doi>10.1007/s00604-017-2634-0</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0026-3672 |
| ispartof | Mikrochimica acta (1966), 2018-02, Vol.185 (2), p.99-8, Article 99 |
| issn | 0026-3672 1436-5073 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Aluminum oxide Anabolic steroids Analysis Analytical Chemistry Atomic absorption analysis Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Coordination compounds Copper Copper compounds Dispersion Gasoline Graphite Iron oxides Microemulsions Microengineering Nanochemistry Nanotechnology Naphthol Original Paper Phase separation Pyridylazonaphthol Reproducibility Sodium dodecyl sulfate |
| title | Macroemulsion-based dispersive magnetic solid phase extraction for preconcentration and determination of copper(II) in gasoline |
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