Carbon nanotube-modified monolithic polymethacrylate pipette tips for (micro)solid-phase extraction of antidepressants from urine samples
This work evaluates the potential of methacrylate monoliths with multi-walled carbon nanotubes incorporated into the polymeric network for the extraction of antidepressants from human urine. The method is based on a micropipette solid-phase extraction tip containing a hybrid monolithic material cova...
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| Veröffentlicht in: | Mikrochimica acta (1966) 2018-02, Vol.185 (2), p.127-7, Article 127 |
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| container_title | Mikrochimica acta (1966) |
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| creator | Fresco-Cala, Beatriz Mompó-Roselló, Óscar Simó-Alfonso, Ernesto F. Cárdenas, Soledad Herrero-Martínez, José Manuel |
| description | This work evaluates the potential of methacrylate monoliths with multi-walled carbon nanotubes incorporated into the polymeric network for the extraction of antidepressants from human urine. The method is based on a micropipette solid-phase extraction tip containing a hybrid monolithic material covalently attached to the polypropylene housing. A polymer layer made from poly(ethylene dimethacrylate) was bound to the inner surface of a polypropylene tip via UV grafting. The preparation of the monolith and the microextraction steps were optimized in terms of adsorption capacity. Limits of detection ranged from 9 to 15 μg·L
−1
. The average precision of the method varied between 3 and 5% (intra-tips), and from 4 to 14% (inter-tips). The accuracy of the method was evaluated through a recovery study by using spiked samples.
Graphical abstract
Hybrid polymer monoliths containing multi-walled carbon nanotubes (MWCNTs) were prepared in pipette tips by photo-polymerization approach. The extraction devices were used for the extraction of antidepressants in urine samples. |
| doi_str_mv | 10.1007/s00604-017-2659-4 |
| format | Article |
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−1
. The average precision of the method varied between 3 and 5% (intra-tips), and from 4 to 14% (inter-tips). The accuracy of the method was evaluated through a recovery study by using spiked samples.
Graphical abstract
Hybrid polymer monoliths containing multi-walled carbon nanotubes (MWCNTs) were prepared in pipette tips by photo-polymerization approach. The extraction devices were used for the extraction of antidepressants in urine samples.</description><identifier>ISSN: 0026-3672</identifier><identifier>EISSN: 1436-5073</identifier><identifier>DOI: 10.1007/s00604-017-2659-4</identifier><identifier>PMID: 29594510</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Adsorption ; Analytical Chemistry ; Antidepressants ; Antidepressants, Tricyclic ; Carbon nanotubes ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Ethylene ; Methods ; Microengineering ; Multi wall carbon nanotubes ; Nanochemistry ; Nanotechnology ; Nanotubes ; Original Paper ; Polypropylene ; Solids ; Tips ; Urine</subject><ispartof>Mikrochimica acta (1966), 2018-02, Vol.185 (2), p.127-7, Article 127</ispartof><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Microchimica Acta is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-92b7ee76ad1c0f79d4230b2535a5dc416834bd9c00fde04356329bf022b39ca63</citedby><cites>FETCH-LOGICAL-c439t-92b7ee76ad1c0f79d4230b2535a5dc416834bd9c00fde04356329bf022b39ca63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00604-017-2659-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00604-017-2659-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29594510$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fresco-Cala, Beatriz</creatorcontrib><creatorcontrib>Mompó-Roselló, Óscar</creatorcontrib><creatorcontrib>Simó-Alfonso, Ernesto F.</creatorcontrib><creatorcontrib>Cárdenas, Soledad</creatorcontrib><creatorcontrib>Herrero-Martínez, José Manuel</creatorcontrib><title>Carbon nanotube-modified monolithic polymethacrylate pipette tips for (micro)solid-phase extraction of antidepressants from urine samples</title><title>Mikrochimica acta (1966)</title><addtitle>Microchim Acta</addtitle><addtitle>Mikrochim Acta</addtitle><description>This work evaluates the potential of methacrylate monoliths with multi-walled carbon nanotubes incorporated into the polymeric network for the extraction of antidepressants from human urine. The method is based on a micropipette solid-phase extraction tip containing a hybrid monolithic material covalently attached to the polypropylene housing. A polymer layer made from poly(ethylene dimethacrylate) was bound to the inner surface of a polypropylene tip via UV grafting. The preparation of the monolith and the microextraction steps were optimized in terms of adsorption capacity. Limits of detection ranged from 9 to 15 μg·L
−1
. The average precision of the method varied between 3 and 5% (intra-tips), and from 4 to 14% (inter-tips). The accuracy of the method was evaluated through a recovery study by using spiked samples.
Graphical abstract
Hybrid polymer monoliths containing multi-walled carbon nanotubes (MWCNTs) were prepared in pipette tips by photo-polymerization approach. The extraction devices were used for the extraction of antidepressants in urine samples.</description><subject>Adsorption</subject><subject>Analytical Chemistry</subject><subject>Antidepressants</subject><subject>Antidepressants, Tricyclic</subject><subject>Carbon nanotubes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Ethylene</subject><subject>Methods</subject><subject>Microengineering</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Nanotubes</subject><subject>Original Paper</subject><subject>Polypropylene</subject><subject>Solids</subject><subject>Tips</subject><subject>Urine</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kc1u1DAUhS0EotOBB2CDIrEpi5Tr39TLagQUqRIbWFtOfNNxldjBdiTmEXhrPJryK5AX17K_c3TvPYS8oHBJAbo3GUCBaIF2LVNSt-IR2VDBVSuh44_JBoCplquOnZHznO-hgoqJp-SMaamFpLAh33Y29TE0wYZY1h7bOTo_enTNHEOcfNn7oVnidJix7O2QDpMt2Cx-wVJr8Utuxpiai9kPKb7OVeHaZW8zNvi1JDsUX83j2NhQvMMlYc71WkUpzs2afMAm23mZMD8jT0Y7ZXz-ULfk87u3n3Y37e3H9x9217ftILgurWZ9h9gp6-gAY6edYBx6Jrm00g2CqisueqcHgNEhCC4VZ7ofgbGe68EqviUXJ98lxS8r5mJmnwecJhswrtkwoPoKNChZ0Vd_ofdxTaF2Z6jWXHAqOvqLurMTGh_GeBz8aGquOypBaqihbMnlP6h6HNbdxYCjr-9_COhJUBebc8LRLMnPNh0MBXOM35ziNzVVc4zfHDUvHxpe-xndT8WPvCvATkCuX-EO028T_df1O9jJu3Y</recordid><startdate>20180201</startdate><enddate>20180201</enddate><creator>Fresco-Cala, Beatriz</creator><creator>Mompó-Roselló, Óscar</creator><creator>Simó-Alfonso, Ernesto F.</creator><creator>Cárdenas, Soledad</creator><creator>Herrero-Martínez, José Manuel</creator><general>Springer Vienna</general><general>Springer</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>KB.</scope><scope>M0S</scope><scope>M1P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope></search><sort><creationdate>20180201</creationdate><title>Carbon nanotube-modified monolithic polymethacrylate pipette tips for (micro)solid-phase extraction of antidepressants from urine samples</title><author>Fresco-Cala, Beatriz ; Mompó-Roselló, Óscar ; Simó-Alfonso, Ernesto F. ; Cárdenas, Soledad ; Herrero-Martínez, José Manuel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-92b7ee76ad1c0f79d4230b2535a5dc416834bd9c00fde04356329bf022b39ca63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Adsorption</topic><topic>Analytical Chemistry</topic><topic>Antidepressants</topic><topic>Antidepressants, Tricyclic</topic><topic>Carbon nanotubes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Ethylene</topic><topic>Methods</topic><topic>Microengineering</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Nanotubes</topic><topic>Original Paper</topic><topic>Polypropylene</topic><topic>Solids</topic><topic>Tips</topic><topic>Urine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fresco-Cala, Beatriz</creatorcontrib><creatorcontrib>Mompó-Roselló, Óscar</creatorcontrib><creatorcontrib>Simó-Alfonso, Ernesto F.</creatorcontrib><creatorcontrib>Cárdenas, Soledad</creatorcontrib><creatorcontrib>Herrero-Martínez, José Manuel</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fresco-Cala, Beatriz</au><au>Mompó-Roselló, Óscar</au><au>Simó-Alfonso, Ernesto F.</au><au>Cárdenas, Soledad</au><au>Herrero-Martínez, José Manuel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbon nanotube-modified monolithic polymethacrylate pipette tips for (micro)solid-phase extraction of antidepressants from urine samples</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><addtitle>Mikrochim Acta</addtitle><date>2018-02-01</date><risdate>2018</risdate><volume>185</volume><issue>2</issue><spage>127</spage><epage>7</epage><pages>127-7</pages><artnum>127</artnum><issn>0026-3672</issn><eissn>1436-5073</eissn><abstract>This work evaluates the potential of methacrylate monoliths with multi-walled carbon nanotubes incorporated into the polymeric network for the extraction of antidepressants from human urine. The method is based on a micropipette solid-phase extraction tip containing a hybrid monolithic material covalently attached to the polypropylene housing. A polymer layer made from poly(ethylene dimethacrylate) was bound to the inner surface of a polypropylene tip via UV grafting. The preparation of the monolith and the microextraction steps were optimized in terms of adsorption capacity. Limits of detection ranged from 9 to 15 μg·L
−1
. The average precision of the method varied between 3 and 5% (intra-tips), and from 4 to 14% (inter-tips). The accuracy of the method was evaluated through a recovery study by using spiked samples.
Graphical abstract
Hybrid polymer monoliths containing multi-walled carbon nanotubes (MWCNTs) were prepared in pipette tips by photo-polymerization approach. The extraction devices were used for the extraction of antidepressants in urine samples.</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><pmid>29594510</pmid><doi>10.1007/s00604-017-2659-4</doi><tpages>7</tpages></addata></record> |
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| subjects | Adsorption Analytical Chemistry Antidepressants Antidepressants, Tricyclic Carbon nanotubes Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Ethylene Methods Microengineering Multi wall carbon nanotubes Nanochemistry Nanotechnology Nanotubes Original Paper Polypropylene Solids Tips Urine |
| title | Carbon nanotube-modified monolithic polymethacrylate pipette tips for (micro)solid-phase extraction of antidepressants from urine samples |
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