Cooperative Au(I)···Au(I) Interactions and Hydrogen Bonding as Origin of a Luminescent Adeninate Hydrogel Formed by Ultrathin Molecular Nanowires

Two water-soluble [Au­(9 N-adeninate)­(PR3)] complexes (PR3 = PMe3 (1); PTA (3)) were synthesized by the coordination of the respective cationic [Au­(PR3)]+ fragment to the 9 N position of the adeninate anion. Both complexes crystallize as dimers by aurophilic contacts of 3.2081(6) Å in 1 and 3.0942...

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Veröffentlicht in:	Inorganic chemistry 2018-04, Vol.57 (7), p.3805-3817
Hauptverfasser:	Blasco, Daniel, López-de-Luzuriaga, José M, Monge, Miguel, Olmos, M. Elena, Pascual, David, Rodríguez-Castillo, María
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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