Ratio-Controlled Precursors of Anderson–Evans Polyoxometalates: Synthesis, Structural Transformation, and Magnetic and Catalytic Properties of a Series of Triol Ligand-Decorated {M2Mo6} Clusters (M = Cu2+, Co2+, Ni2+, Zn2+)

A series of triol ligand [CH3C­(CH2OH)3] covalently decorated polyoxometalates (POMs), which could be ascribed to the primary complexes with structural formulas {M2[Mo2O4(CH3C­(CH2O)3)2]3}2– (M = Cu2+, Co2+, Ni2+, Zn2+), have been synthesized in organic solvents. Single-crystal X-ray structural anal...

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Veröffentlicht in:	Inorganic chemistry 2018-04, Vol.57 (7), p.3731-3741
Hauptverfasser:	Wang, Yang, Kong, Xueping, Xu, Wei, Jiang, Fengrui, Li, Bao, Wu, Lixin
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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