Polymerization of Isoprene Promoted by Aminophosphine(ory)-Fused Bipyridine Cobalt Complexes: Precise Control of Molecular Weight and cis-1,4-alt-3,4 Sequence

Ligands N-(dialkyl or arylphosphino)-(2,2′-bipyridin)-6-amine (L1, aryl = Ph; L2, alkyl = t Bu; L3, alkyl = adamantyl (Ad)) as well as the corresponding oxidized N-(2,2′-bipyridin-6-yl)-P,P-dialkyl or aryl phosphinic amide (L4, aryl = Ph; L5, alkyl = t Bu; L6, alkyl = Ad) congeners were designed and...

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Veröffentlicht in:Inorganic chemistry 2018-04, Vol.57 (7), p.4088-4097
Hauptverfasser: Zhao, Junyi, Chen, Huafeng, Li, Wenxin, Jia, Xiaoyu, Zhang, Xuequan, Gong, Dirong
Format: Artikel
Sprache:eng
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