Synthesis of medium-sized aryl-fused nitrogenous heterocycles via sequential aryne aza-Claisen rearrangement/ring-closing metathesis

The reaction of arynes and secondary allylamines furnished ortho-allyl-substituted N-arylanilines via an aza-Claisen rearrangement. In this transformation, the sequential formation of C-C and C-N bonds occurred by involving two aryne molecules under metal-free reaction conditions to provide moderate...

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Veröffentlicht in:	Organic & biomolecular chemistry 2018-03, Vol.16 (12), p.2134-2142
Hauptverfasser:	Rao Mangina, N S V M, Guduru, Ravinder, Karunakar, Galla V
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Chemical bonds Decomposition reactions Metathesis Substitutes
Online-Zugang:	Volltext
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