Insights into the Rb–Mg–N–H System: an Ordered Mixed Amide/Imide Phase and a Disordered Amide/Hydride Solid Solution

The crystal structure of a mixed amide-imide phase, RbMgND2ND, has been solved in the orthorhombic space group Pnma (a = 9.55256(31), b = 3.70772(11) and c = 10.08308(32) Å). A new metal amide-hydride solid solution, Rb­(NH2) x H(1–x), has been isolated and characterized in the entire compositional range. The profound analogies, as well as the subtle differences, with the crystal chemistry of KMgND2ND and K­(NH2) x H1–x are thoroughly discussed. This approach suggests that the comparable performances obtained using K- and Rb-based additives for the Mg­(NH2)2-2LiH and 2LiNH2–MgH2 hydrogen storage systems are likely to depend on the structural similarities of possible reaction products and intermediates.