Risk assessment of trace metals in an extreme environment sediment: shallow, hypersaline, alkaline, and industrial Lake Acıgöl, Denizli, Turkey

The major and trace element component of 48 recent sediment samples in three distinct intervals (0–10, 10–20, and 20–30 cm) from Lake Acıgöl is described to present the current contamination levels and grift structure of detrital and evaporate mineral patterns of these sediments in this extreme sali...

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Veröffentlicht in:Environmental monitoring and assessment 2018-03, Vol.190 (3), p.169-27, Article 169
Hauptverfasser: Budakoglu, Murat, Karaman, Muhittin, Kumral, Mustafa, Zeytuncu, Bihter, Doner, Zeynep, Yildirim, Demet Kiran, Taşdelen, Suat, Bülbül, Ali, Gumus, Lokman
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container_title Environmental monitoring and assessment
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creator Budakoglu, Murat
Karaman, Muhittin
Kumral, Mustafa
Zeytuncu, Bihter
Doner, Zeynep
Yildirim, Demet Kiran
Taşdelen, Suat
Bülbül, Ali
Gumus, Lokman
description The major and trace element component of 48 recent sediment samples in three distinct intervals (0–10, 10–20, and 20–30 cm) from Lake Acıgöl is described to present the current contamination levels and grift structure of detrital and evaporate mineral patterns of these sediments in this extreme saline environment. The spatial and vertical concentrations of major oxides were not uniform in the each subsurface interval. However, similar spatial distribution patterns were observed for some major element couples, due mainly to the detrital and evaporate origin of these elements. A sequential extraction procedure including five distinct steps was also performed to determine the different bonds of trace elements in the
doi_str_mv 10.1007/s10661-018-6495-8
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The spatial and vertical concentrations of major oxides were not uniform in the each subsurface interval. However, similar spatial distribution patterns were observed for some major element couples, due mainly to the detrital and evaporate origin of these elements. A sequential extraction procedure including five distinct steps was also performed to determine the different bonds of trace elements in the &lt; 60-μ particulate size of recent sediments. Eleven trace elements (Ni, Fe, Cd, Pb, Cu, Zn, As, Co, Cr, Al and Mn) in nine surface and subsurface sediment samples were analyzed with chemical partitioning procedures to determine the trace element percentage loads in these different sequential extraction phases. The obtained accuracy values via comparison of the bulk trace metal loads with the total loads of five extraction steps were satisfying for the Ni, Fe, Cd, Zn, and Co. While, bulk analysis results of the Cu, Ni, and V elements have good correlation with total organic matter, organic fraction of sequential extraction characterized by Cu, As, Cd, and Pb. Shallow Lake Acıgöl sediment is characteristic with two different redox layer a) oxic upper level sediments, where trace metals are mobilized, b) reduced subsurface level, where the trace metals are precipitated.</description><identifier>ISSN: 0167-6369</identifier><identifier>EISSN: 1573-2959</identifier><identifier>DOI: 10.1007/s10661-018-6495-8</identifier><identifier>PMID: 29476272</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Aluminum ; Atmospheric Protection/Air Quality Control/Air Pollution ; Cadmium ; Chemical bonds ; Chromium ; Cobalt ; Contamination ; Copper ; Distribution patterns ; Earth and Environmental Science ; Ecological risk assessment ; Ecology ; Ecotoxicology ; Environment ; Environmental Management ; Environmental monitoring ; Environmental science ; Heavy metals ; Iron ; Lake sediments ; Lakes ; Lead ; Loads (forces) ; Manganese ; Metals ; Monitoring/Environmental Analysis ; Nickel ; Organic matter ; Oxides ; Oxidoreductions ; Particulate size ; Procedures ; Recent sediments ; Risk assessment ; Sediment ; Sediment samplers ; Sediment samples ; Sediments ; Spatial distribution ; Trace elements ; Trace metals ; Zinc</subject><ispartof>Environmental monitoring and assessment, 2018-03, Vol.190 (3), p.169-27, Article 169</ispartof><rights>Springer International Publishing AG, part of Springer Nature 2018</rights><rights>Environmental Monitoring and Assessment is a copyright of Springer, (2018). 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While, bulk analysis results of the Cu, Ni, and V elements have good correlation with total organic matter, organic fraction of sequential extraction characterized by Cu, As, Cd, and Pb. 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The spatial and vertical concentrations of major oxides were not uniform in the each subsurface interval. However, similar spatial distribution patterns were observed for some major element couples, due mainly to the detrital and evaporate origin of these elements. A sequential extraction procedure including five distinct steps was also performed to determine the different bonds of trace elements in the &lt; 60-μ particulate size of recent sediments. Eleven trace elements (Ni, Fe, Cd, Pb, Cu, Zn, As, Co, Cr, Al and Mn) in nine surface and subsurface sediment samples were analyzed with chemical partitioning procedures to determine the trace element percentage loads in these different sequential extraction phases. The obtained accuracy values via comparison of the bulk trace metal loads with the total loads of five extraction steps were satisfying for the Ni, Fe, Cd, Zn, and Co. While, bulk analysis results of the Cu, Ni, and V elements have good correlation with total organic matter, organic fraction of sequential extraction characterized by Cu, As, Cd, and Pb. Shallow Lake Acıgöl sediment is characteristic with two different redox layer a) oxic upper level sediments, where trace metals are mobilized, b) reduced subsurface level, where the trace metals are precipitated.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><pmid>29476272</pmid><doi>10.1007/s10661-018-6495-8</doi><tpages>27</tpages></addata></record>
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subjects Aluminum
Atmospheric Protection/Air Quality Control/Air Pollution
Cadmium
Chemical bonds
Chromium
Cobalt
Contamination
Copper
Distribution patterns
Earth and Environmental Science
Ecological risk assessment
Ecology
Ecotoxicology
Environment
Environmental Management
Environmental monitoring
Environmental science
Heavy metals
Iron
Lake sediments
Lakes
Lead
Loads (forces)
Manganese
Metals
Monitoring/Environmental Analysis
Nickel
Organic matter
Oxides
Oxidoreductions
Particulate size
Procedures
Recent sediments
Risk assessment
Sediment
Sediment samplers
Sediment samples
Sediments
Spatial distribution
Trace elements
Trace metals
Zinc
title Risk assessment of trace metals in an extreme environment sediment: shallow, hypersaline, alkaline, and industrial Lake Acıgöl, Denizli, Turkey
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