Organoactinide‐Catalyzed Monohydroboration of Carbodiimides
The organoactinide‐catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom‐efficient and highly selective fashion to afford the corresponding monohydroborated N‐borylformamidine products in high yields. A plausible...
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| Veröffentlicht in: | Chemistry : a European journal 2018-04, Vol.24 (22), p.5738-5742 |
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| container_issue | 22 |
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| container_title | Chemistry : a European journal |
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| creator | Liu, Heng Kulbitski, Kseniya Tamm, Matthias Eisen, Moris S. |
| description | The organoactinide‐catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom‐efficient and highly selective fashion to afford the corresponding monohydroborated N‐borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.
Actinides in a couple of Bs: The monohydroboration of carbodiimides catalyzed in a highly selective and atom‐efficient fashion by organoactinides has been developed. The corresponding monohydroborated N‐borylformamidine products are obtained under mild conditions in high yields. This reaction features a broad substrate scope. A plausible mechanism is proposed based on stoichiometric and kinetic studies. |
| doi_str_mv | 10.1002/chem.201705987 |
| format | Article |
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Actinides in a couple of Bs: The monohydroboration of carbodiimides catalyzed in a highly selective and atom‐efficient fashion by organoactinides has been developed. The corresponding monohydroborated N‐borylformamidine products are obtained under mild conditions in high yields. This reaction features a broad substrate scope. A plausible mechanism is proposed based on stoichiometric and kinetic studies.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201705987</identifier><identifier>PMID: 29465797</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>actinides ; boron ; carbodiimide ; Carbodiimides ; Catalysis ; Chemical reactions ; Chemistry ; hydroboration ; organoactinide</subject><ispartof>Chemistry : a European journal, 2018-04, Vol.24 (22), p.5738-5742</ispartof><rights>2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4107-35de0efccf48bea04993a96e342557f2a3aceb882fc84273a993c22a06f6ff1e3</citedby><cites>FETCH-LOGICAL-c4107-35de0efccf48bea04993a96e342557f2a3aceb882fc84273a993c22a06f6ff1e3</cites><orcidid>0000-0003-2925-4912 ; 0000-0002-5364-0357 ; 0000-0001-8915-0256 ; 0000-0002-6035-3428</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201705987$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201705987$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29465797$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Heng</creatorcontrib><creatorcontrib>Kulbitski, Kseniya</creatorcontrib><creatorcontrib>Tamm, Matthias</creatorcontrib><creatorcontrib>Eisen, Moris S.</creatorcontrib><title>Organoactinide‐Catalyzed Monohydroboration of Carbodiimides</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>The organoactinide‐catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom‐efficient and highly selective fashion to afford the corresponding monohydroborated N‐borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.
Actinides in a couple of Bs: The monohydroboration of carbodiimides catalyzed in a highly selective and atom‐efficient fashion by organoactinides has been developed. The corresponding monohydroborated N‐borylformamidine products are obtained under mild conditions in high yields. This reaction features a broad substrate scope. A plausible mechanism is proposed based on stoichiometric and kinetic studies.</description><subject>actinides</subject><subject>boron</subject><subject>carbodiimide</subject><subject>Carbodiimides</subject><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>hydroboration</subject><subject>organoactinide</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqF0LFOwzAQBmALgWgprIyoEgtLytmO43hgQFGhSK26wBw5jk1TJXGxE6Ew8Qg8I09CqhaQWJhuuO9-nX6EzjFMMAC5VitdTQhgDkzE_AANMSM4oDxih2gIIuRBxKgYoBPv1wAgIkqP0YCIMGJc8CG6WbpnWVupmqIucv35_pHIRpbdm87HC1vbVZc7m1knm8LWY2vGiXSZzYui6rU_RUdGll6f7ecIPd1NH5NZMF_ePyS380CFGHhAWa5BG6VMGGdaQigElSLSNCSMcUMklUpncUyMikPC-52gihAJkYmMwZqO0NUud-PsS6t9k1aFV7osZa1t61MCwDEmQuCeXv6ha9u6uv-uV4QJgAhEryY7pZz13mmTblxRSdelGNJtsem22PSn2P7gYh_bZpXOf_h3kz0QO_BalLr7Jy5NZtPFb_gX25GFpA</recordid><startdate>20180417</startdate><enddate>20180417</enddate><creator>Liu, Heng</creator><creator>Kulbitski, Kseniya</creator><creator>Tamm, Matthias</creator><creator>Eisen, Moris S.</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2925-4912</orcidid><orcidid>https://orcid.org/0000-0002-5364-0357</orcidid><orcidid>https://orcid.org/0000-0001-8915-0256</orcidid><orcidid>https://orcid.org/0000-0002-6035-3428</orcidid></search><sort><creationdate>20180417</creationdate><title>Organoactinide‐Catalyzed Monohydroboration of Carbodiimides</title><author>Liu, Heng ; Kulbitski, Kseniya ; Tamm, Matthias ; Eisen, Moris S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4107-35de0efccf48bea04993a96e342557f2a3aceb882fc84273a993c22a06f6ff1e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>actinides</topic><topic>boron</topic><topic>carbodiimide</topic><topic>Carbodiimides</topic><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>hydroboration</topic><topic>organoactinide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Heng</creatorcontrib><creatorcontrib>Kulbitski, Kseniya</creatorcontrib><creatorcontrib>Tamm, Matthias</creatorcontrib><creatorcontrib>Eisen, Moris S.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Heng</au><au>Kulbitski, Kseniya</au><au>Tamm, Matthias</au><au>Eisen, Moris S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Organoactinide‐Catalyzed Monohydroboration of Carbodiimides</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2018-04-17</date><risdate>2018</risdate><volume>24</volume><issue>22</issue><spage>5738</spage><epage>5742</epage><pages>5738-5742</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>The organoactinide‐catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom‐efficient and highly selective fashion to afford the corresponding monohydroborated N‐borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.
Actinides in a couple of Bs: The monohydroboration of carbodiimides catalyzed in a highly selective and atom‐efficient fashion by organoactinides has been developed. The corresponding monohydroborated N‐borylformamidine products are obtained under mild conditions in high yields. This reaction features a broad substrate scope. A plausible mechanism is proposed based on stoichiometric and kinetic studies.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>29465797</pmid><doi>10.1002/chem.201705987</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-2925-4912</orcidid><orcidid>https://orcid.org/0000-0002-5364-0357</orcidid><orcidid>https://orcid.org/0000-0001-8915-0256</orcidid><orcidid>https://orcid.org/0000-0002-6035-3428</orcidid></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | actinides boron carbodiimide Carbodiimides Catalysis Chemical reactions Chemistry hydroboration organoactinide |
| title | Organoactinide‐Catalyzed Monohydroboration of Carbodiimides |
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