Synthesis of polyfluoroarene-substituted benzofuran derivatives via cooperative Pd/Cu catalysis

A cooperative Pd/Cu-catalyzed dual C-H bond activation of electron-deficient polyfluoroarenes with aryl halides is developed. This protocol provides a unique and strategically distinct access to a variety of polyfluoroarene-substituted benzofuran derivatives. This is the first example of the introdu...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018-03, Vol.54 (18), p.2256-2259
Hauptverfasser:	Shen, Yi, Wu, Xin-Xing, Chen, Si, Xia, Yu, Liang, Yong-Min
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysis Chemical synthesis Derivatives Halides Hydrogen bonds Substitutes
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creator	Shen, Yi Wu, Xin-Xing Chen, Si Xia, Yu Liang, Yong-Min
description	A cooperative Pd/Cu-catalyzed dual C-H bond activation of electron-deficient polyfluoroarenes with aryl halides is developed. This protocol provides a unique and strategically distinct access to a variety of polyfluoroarene-substituted benzofuran derivatives. This is the first example of the introduction of electron-deficient arenes to a Catellani-type reaction.
doi_str_mv	10.1039/c8cc00489g
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Aromatic compounds Catalysis Chemical synthesis Derivatives Halides Hydrogen bonds Substitutes
title	Synthesis of polyfluoroarene-substituted benzofuran derivatives via cooperative Pd/Cu catalysis
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