Monitoring photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic kinetic study of [Pd(Bu4dien)NO2]BPh4
We present a detailed kinetic study of photo-induced solid state linkage isomerism in the compound [Pd(Bu4dien)NO2]BPh4 (Bu4dien = N,N,N′,N′-tetrabutyldiethylenetriamine) using in situ photocrystallographic techniques. We explore the key variables that influence the photoconversion and develop a det...
Gespeichert in:
| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2018, Vol.20 (8), p.5874-5886 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5886 |
|---|---|
| container_issue | 8 |
| container_start_page | 5874 |
| container_title | Physical chemistry chemical physics : PCCP |
| container_volume | 20 |
| creator | Hatcher, Lauren E Skelton, Jonathan M Warren, Mark R Stubbs, Clare Lora da Silva, E Raithby, Paul R |
| description | We present a detailed kinetic study of photo-induced solid state linkage isomerism in the compound [Pd(Bu4dien)NO2]BPh4 (Bu4dien = N,N,N′,N′-tetrabutyldiethylenetriamine) using in situ photocrystallographic techniques. We explore the key variables that influence the photoconversion and develop a detailed kinetic model for the excitation and decay processes and the temperature dependence of the conversion rates. We show that by varying the temperature the lifetime of the excited state can be varied over orders of magnitude, making these systems ideal test cases for the development of new time-resolved X-ray diffraction methods. The kinetic model is used to build a numerical-simulation tool, which we use to explore the practicalities of pump–probe single-crystal diffraction experiments with minute and second time-resolution. |
| doi_str_mv | 10.1039/c7cp05422j |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1999678979</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2010865801</sourcerecordid><originalsourceid>FETCH-LOGICAL-j318t-75aa96f1c74ae279d04ec019bd66d4dfa6d4fc91aea4770cf215e7291032e08e3</originalsourceid><addsrcrecordid>eNpdUL1OwzAYtBBIlMLCE1hiKUPAdpw4ZqMVfxLQDjAhVLn2l9ZpYofYGfoOPDSR-BlY7k660-l0CJ1SckFJKi-10C3JOGPVHhpRnqeJJAXf_9MiP0RHIVSEEJrRdIQ-n7yz0XfWrXG78dEn1pleg8Gtb_taResdNjunGqsDtg43EFWIalUDrq3bqjVgG3wDHdbdbjDqcIXVr679ulPtxmq8tQ7iwCH2Zod9id8WZjLtubHgzp_n7H262PBjdFAOBXDyw2P0envzMrtPHud3D7Prx6RKaRETkSkl85JqwRUwIQ3hoAmVK5PnhptSDVhqSRUoLgTRJaMZCCaHhxiQAtIxmnz3tp3_6CHEZWODhrpWDnwfllRKmYtCCjlEz_5FK993bli3ZISSIs8KQtMvJB91Nw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2010865801</pqid></control><display><type>article</type><title>Monitoring photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic kinetic study of [Pd(Bu4dien)NO2]BPh4</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Hatcher, Lauren E ; Skelton, Jonathan M ; Warren, Mark R ; Stubbs, Clare ; Lora da Silva, E ; Raithby, Paul R</creator><creatorcontrib>Hatcher, Lauren E ; Skelton, Jonathan M ; Warren, Mark R ; Stubbs, Clare ; Lora da Silva, E ; Raithby, Paul R</creatorcontrib><description>We present a detailed kinetic study of photo-induced solid state linkage isomerism in the compound [Pd(Bu4dien)NO2]BPh4 (Bu4dien = N,N,N′,N′-tetrabutyldiethylenetriamine) using in situ photocrystallographic techniques. We explore the key variables that influence the photoconversion and develop a detailed kinetic model for the excitation and decay processes and the temperature dependence of the conversion rates. We show that by varying the temperature the lifetime of the excited state can be varied over orders of magnitude, making these systems ideal test cases for the development of new time-resolved X-ray diffraction methods. The kinetic model is used to build a numerical-simulation tool, which we use to explore the practicalities of pump–probe single-crystal diffraction experiments with minute and second time-resolution.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c7cp05422j</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Computer simulation ; Crystallography ; Kinetics ; Nitrogen dioxide ; Single crystals ; Temperature dependence ; X-ray diffraction</subject><ispartof>Physical chemistry chemical physics : PCCP, 2018, Vol.20 (8), p.5874-5886</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Hatcher, Lauren E</creatorcontrib><creatorcontrib>Skelton, Jonathan M</creatorcontrib><creatorcontrib>Warren, Mark R</creatorcontrib><creatorcontrib>Stubbs, Clare</creatorcontrib><creatorcontrib>Lora da Silva, E</creatorcontrib><creatorcontrib>Raithby, Paul R</creatorcontrib><title>Monitoring photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic kinetic study of [Pd(Bu4dien)NO2]BPh4</title><title>Physical chemistry chemical physics : PCCP</title><description>We present a detailed kinetic study of photo-induced solid state linkage isomerism in the compound [Pd(Bu4dien)NO2]BPh4 (Bu4dien = N,N,N′,N′-tetrabutyldiethylenetriamine) using in situ photocrystallographic techniques. We explore the key variables that influence the photoconversion and develop a detailed kinetic model for the excitation and decay processes and the temperature dependence of the conversion rates. We show that by varying the temperature the lifetime of the excited state can be varied over orders of magnitude, making these systems ideal test cases for the development of new time-resolved X-ray diffraction methods. The kinetic model is used to build a numerical-simulation tool, which we use to explore the practicalities of pump–probe single-crystal diffraction experiments with minute and second time-resolution.</description><subject>Computer simulation</subject><subject>Crystallography</subject><subject>Kinetics</subject><subject>Nitrogen dioxide</subject><subject>Single crystals</subject><subject>Temperature dependence</subject><subject>X-ray diffraction</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdUL1OwzAYtBBIlMLCE1hiKUPAdpw4ZqMVfxLQDjAhVLn2l9ZpYofYGfoOPDSR-BlY7k660-l0CJ1SckFJKi-10C3JOGPVHhpRnqeJJAXf_9MiP0RHIVSEEJrRdIQ-n7yz0XfWrXG78dEn1pleg8Gtb_taResdNjunGqsDtg43EFWIalUDrq3bqjVgG3wDHdbdbjDqcIXVr679ulPtxmq8tQ7iwCH2Zod9id8WZjLtubHgzp_n7H262PBjdFAOBXDyw2P0envzMrtPHud3D7Prx6RKaRETkSkl85JqwRUwIQ3hoAmVK5PnhptSDVhqSRUoLgTRJaMZCCaHhxiQAtIxmnz3tp3_6CHEZWODhrpWDnwfllRKmYtCCjlEz_5FK993bli3ZISSIs8KQtMvJB91Nw</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Hatcher, Lauren E</creator><creator>Skelton, Jonathan M</creator><creator>Warren, Mark R</creator><creator>Stubbs, Clare</creator><creator>Lora da Silva, E</creator><creator>Raithby, Paul R</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>2018</creationdate><title>Monitoring photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic kinetic study of [Pd(Bu4dien)NO2]BPh4</title><author>Hatcher, Lauren E ; Skelton, Jonathan M ; Warren, Mark R ; Stubbs, Clare ; Lora da Silva, E ; Raithby, Paul R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j318t-75aa96f1c74ae279d04ec019bd66d4dfa6d4fc91aea4770cf215e7291032e08e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Computer simulation</topic><topic>Crystallography</topic><topic>Kinetics</topic><topic>Nitrogen dioxide</topic><topic>Single crystals</topic><topic>Temperature dependence</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hatcher, Lauren E</creatorcontrib><creatorcontrib>Skelton, Jonathan M</creatorcontrib><creatorcontrib>Warren, Mark R</creatorcontrib><creatorcontrib>Stubbs, Clare</creatorcontrib><creatorcontrib>Lora da Silva, E</creatorcontrib><creatorcontrib>Raithby, Paul R</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hatcher, Lauren E</au><au>Skelton, Jonathan M</au><au>Warren, Mark R</au><au>Stubbs, Clare</au><au>Lora da Silva, E</au><au>Raithby, Paul R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monitoring photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic kinetic study of [Pd(Bu4dien)NO2]BPh4</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><date>2018</date><risdate>2018</risdate><volume>20</volume><issue>8</issue><spage>5874</spage><epage>5886</epage><pages>5874-5886</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>We present a detailed kinetic study of photo-induced solid state linkage isomerism in the compound [Pd(Bu4dien)NO2]BPh4 (Bu4dien = N,N,N′,N′-tetrabutyldiethylenetriamine) using in situ photocrystallographic techniques. We explore the key variables that influence the photoconversion and develop a detailed kinetic model for the excitation and decay processes and the temperature dependence of the conversion rates. We show that by varying the temperature the lifetime of the excited state can be varied over orders of magnitude, making these systems ideal test cases for the development of new time-resolved X-ray diffraction methods. The kinetic model is used to build a numerical-simulation tool, which we use to explore the practicalities of pump–probe single-crystal diffraction experiments with minute and second time-resolution.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c7cp05422j</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2018, Vol.20 (8), p.5874-5886 |
| issn | 1463-9076 1463-9084 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1999678979 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Computer simulation Crystallography Kinetics Nitrogen dioxide Single crystals Temperature dependence X-ray diffraction |
| title | Monitoring photo-induced population dynamics in metastable linkage isomer crystals: a crystallographic kinetic study of [Pd(Bu4dien)NO2]BPh4 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T13%3A53%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Monitoring%20photo-induced%20population%20dynamics%20in%20metastable%20linkage%20isomer%20crystals:%20a%20crystallographic%20kinetic%20study%20of%20%5BPd(Bu4dien)NO2%5DBPh4&rft.jtitle=Physical%20chemistry%20chemical%20physics%20:%20PCCP&rft.au=Hatcher,%20Lauren%20E&rft.date=2018&rft.volume=20&rft.issue=8&rft.spage=5874&rft.epage=5886&rft.pages=5874-5886&rft.issn=1463-9076&rft.eissn=1463-9084&rft_id=info:doi/10.1039/c7cp05422j&rft_dat=%3Cproquest%3E2010865801%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2010865801&rft_id=info:pmid/&rfr_iscdi=true |