Evaluation of advanced treatment technologies for the elimination of pharmaceutical compounds
Pharmaceuticals and their metabolites have developed as ecotoxicologically relevant micropollutants in the aquatic environment. During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or compl...
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description | Pharmaceuticals and their metabolites have developed as ecotoxicologically relevant micropollutants in the aquatic environment. During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or completely non-biodegradable and/or hardly eliminable by activated sludge adsorption because they often have polar structures. Membrane bioreactor treatment (MBR) was applied to pre-treat wastewater containing pharmaceutical compounds, e.g., antibiotics like floxacins and their synthetic precursor compounds. Our objectives were to eliminate these persistent target compounds from wastewater prior to discharge into receiving waters. Therefore an advanced treatment applying MBR combined with different chemical and physicochemical processes was performed. The addition of powdered activated carbon (PAC), nano filtration (NF), reverse osmosis (UO) or ozone (O3) and O3/UV were applied to MBR permeate spiked with the selected target compounds. Treatment efficiency was assessed using conventional inorganic and organic chemical analyses besides advanced physicochemical methods like liquid chromatography coupled with mass and tandem mass spectrometry (LC-MS and -MS-MS). |
doi_str_mv | 10.2166/wst.2007.550 |
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During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or completely non-biodegradable and/or hardly eliminable by activated sludge adsorption because they often have polar structures. Membrane bioreactor treatment (MBR) was applied to pre-treat wastewater containing pharmaceutical compounds, e.g., antibiotics like floxacins and their synthetic precursor compounds. Our objectives were to eliminate these persistent target compounds from wastewater prior to discharge into receiving waters. Therefore an advanced treatment applying MBR combined with different chemical and physicochemical processes was performed. The addition of powdered activated carbon (PAC), nano filtration (NF), reverse osmosis (UO) or ozone (O3) and O3/UV were applied to MBR permeate spiked with the selected target compounds. Treatment efficiency was assessed using conventional inorganic and organic chemical analyses besides advanced physicochemical methods like liquid chromatography coupled with mass and tandem mass spectrometry (LC-MS and -MS-MS).</description><identifier>ISSN: 0273-1223</identifier><identifier>ISBN: 9781843396017</identifier><identifier>ISBN: 1843396017</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.2166/wst.2007.550</identifier><identifier>PMID: 17881831</identifier><language>eng</language><publisher>England: IWA Publishing</publisher><subject>Activated carbon ; Activated sludge ; Ammonium nitrogen ; Anti-Bacterial Agents - analysis ; Antibiotics ; Aquatic environment ; artificial membranes ; Biodegradability ; Biodegradation ; Biodegradation, Environmental ; Biological wastewater treatment ; Bioreactors ; carbon ; Charcoal - chemistry ; Chemical analysis ; Chromatography, Liquid ; Discharge ; drugs ; Ecotoxicology ; Evaluation ; filtration ; floxacins ; Liquid chromatography ; Mass spectrometry ; Mass spectroscopy ; Metabolites ; nutrients ; Organic chemicals ; osmotic treatment ; Ozone ; Ozone - chemistry ; Pharmaceutical Preparations - analysis ; Pharmaceuticals ; physical chemistry ; Receiving waters ; Reverse osmosis ; Sewage - microbiology ; Sludge ; Surface water ; Tandem Mass Spectrometry ; Technology - methods ; Ultrafiltration ; Ultraviolet radiation ; Ultraviolet Rays ; Wastewater ; Wastewater treatment ; Water Pollutants, Chemical - analysis ; water pollution ; Water Purification - methods ; Water treatment plants</subject><ispartof>Water science and technology, 2007-01, Vol.56 (5), p.1-8</ispartof><rights>Copyright IWA Publishing Sep 2007</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c436t-233fb4d5f879be514ad0bcb23576b20c8d608cfa709b639f9cefd58c19a8b893</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17881831$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><contributor>Pinnekamp, J</contributor><creatorcontrib>Baumgarten, S</creatorcontrib><creatorcontrib>Schroder, H.F</creatorcontrib><creatorcontrib>Charwath, C</creatorcontrib><creatorcontrib>Lange, M</creatorcontrib><creatorcontrib>Beier, S</creatorcontrib><creatorcontrib>Pinnekamp, J</creatorcontrib><title>Evaluation of advanced treatment technologies for the elimination of pharmaceutical compounds</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>Pharmaceuticals and their metabolites have developed as ecotoxicologically relevant micropollutants in the aquatic environment. During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or completely non-biodegradable and/or hardly eliminable by activated sludge adsorption because they often have polar structures. Membrane bioreactor treatment (MBR) was applied to pre-treat wastewater containing pharmaceutical compounds, e.g., antibiotics like floxacins and their synthetic precursor compounds. Our objectives were to eliminate these persistent target compounds from wastewater prior to discharge into receiving waters. Therefore an advanced treatment applying MBR combined with different chemical and physicochemical processes was performed. The addition of powdered activated carbon (PAC), nano filtration (NF), reverse osmosis (UO) or ozone (O3) and O3/UV were applied to MBR permeate spiked with the selected target compounds. Treatment efficiency was assessed using conventional inorganic and organic chemical analyses besides advanced physicochemical methods like liquid chromatography coupled with mass and tandem mass spectrometry (LC-MS and -MS-MS).</description><subject>Activated carbon</subject><subject>Activated sludge</subject><subject>Ammonium nitrogen</subject><subject>Anti-Bacterial Agents - analysis</subject><subject>Antibiotics</subject><subject>Aquatic environment</subject><subject>artificial membranes</subject><subject>Biodegradability</subject><subject>Biodegradation</subject><subject>Biodegradation, Environmental</subject><subject>Biological wastewater treatment</subject><subject>Bioreactors</subject><subject>carbon</subject><subject>Charcoal - chemistry</subject><subject>Chemical analysis</subject><subject>Chromatography, Liquid</subject><subject>Discharge</subject><subject>drugs</subject><subject>Ecotoxicology</subject><subject>Evaluation</subject><subject>filtration</subject><subject>floxacins</subject><subject>Liquid chromatography</subject><subject>Mass spectrometry</subject><subject>Mass spectroscopy</subject><subject>Metabolites</subject><subject>nutrients</subject><subject>Organic chemicals</subject><subject>osmotic treatment</subject><subject>Ozone</subject><subject>Ozone - 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During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or completely non-biodegradable and/or hardly eliminable by activated sludge adsorption because they often have polar structures. Membrane bioreactor treatment (MBR) was applied to pre-treat wastewater containing pharmaceutical compounds, e.g., antibiotics like floxacins and their synthetic precursor compounds. Our objectives were to eliminate these persistent target compounds from wastewater prior to discharge into receiving waters. Therefore an advanced treatment applying MBR combined with different chemical and physicochemical processes was performed. The addition of powdered activated carbon (PAC), nano filtration (NF), reverse osmosis (UO) or ozone (O3) and O3/UV were applied to MBR permeate spiked with the selected target compounds. Treatment efficiency was assessed using conventional inorganic and organic chemical analyses besides advanced physicochemical methods like liquid chromatography coupled with mass and tandem mass spectrometry (LC-MS and -MS-MS).</abstract><cop>England</cop><pub>IWA Publishing</pub><pmid>17881831</pmid><doi>10.2166/wst.2007.550</doi><tpages>8</tpages></addata></record> |
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subjects | Activated carbon Activated sludge Ammonium nitrogen Anti-Bacterial Agents - analysis Antibiotics Aquatic environment artificial membranes Biodegradability Biodegradation Biodegradation, Environmental Biological wastewater treatment Bioreactors carbon Charcoal - chemistry Chemical analysis Chromatography, Liquid Discharge drugs Ecotoxicology Evaluation filtration floxacins Liquid chromatography Mass spectrometry Mass spectroscopy Metabolites nutrients Organic chemicals osmotic treatment Ozone Ozone - chemistry Pharmaceutical Preparations - analysis Pharmaceuticals physical chemistry Receiving waters Reverse osmosis Sewage - microbiology Sludge Surface water Tandem Mass Spectrometry Technology - methods Ultrafiltration Ultraviolet radiation Ultraviolet Rays Wastewater Wastewater treatment Water Pollutants, Chemical - analysis water pollution Water Purification - methods Water treatment plants |
title | Evaluation of advanced treatment technologies for the elimination of pharmaceutical compounds |
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