Evaluation of advanced treatment technologies for the elimination of pharmaceutical compounds

Pharmaceuticals and their metabolites have developed as ecotoxicologically relevant micropollutants in the aquatic environment. During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or compl...

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Veröffentlicht in:Water science and technology 2007-01, Vol.56 (5), p.1-8
Hauptverfasser: Baumgarten, S, Schroder, H.F, Charwath, C, Lange, M, Beier, S, Pinnekamp, J
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container_end_page 8
container_issue 5
container_start_page 1
container_title Water science and technology
container_volume 56
creator Baumgarten, S
Schroder, H.F
Charwath, C
Lange, M
Beier, S
Pinnekamp, J
description Pharmaceuticals and their metabolites have developed as ecotoxicologically relevant micropollutants in the aquatic environment. During conventional biological wastewater treatment they are eliminated insufficiently and therefore reach surface waters via discharges. They are either partially or completely non-biodegradable and/or hardly eliminable by activated sludge adsorption because they often have polar structures. Membrane bioreactor treatment (MBR) was applied to pre-treat wastewater containing pharmaceutical compounds, e.g., antibiotics like floxacins and their synthetic precursor compounds. Our objectives were to eliminate these persistent target compounds from wastewater prior to discharge into receiving waters. Therefore an advanced treatment applying MBR combined with different chemical and physicochemical processes was performed. The addition of powdered activated carbon (PAC), nano filtration (NF), reverse osmosis (UO) or ozone (O3) and O3/UV were applied to MBR permeate spiked with the selected target compounds. Treatment efficiency was assessed using conventional inorganic and organic chemical analyses besides advanced physicochemical methods like liquid chromatography coupled with mass and tandem mass spectrometry (LC-MS and -MS-MS).
doi_str_mv 10.2166/wst.2007.550
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subjects Activated carbon
Activated sludge
Ammonium nitrogen
Anti-Bacterial Agents - analysis
Antibiotics
Aquatic environment
artificial membranes
Biodegradability
Biodegradation
Biodegradation, Environmental
Biological wastewater treatment
Bioreactors
carbon
Charcoal - chemistry
Chemical analysis
Chromatography, Liquid
Discharge
drugs
Ecotoxicology
Evaluation
filtration
floxacins
Liquid chromatography
Mass spectrometry
Mass spectroscopy
Metabolites
nutrients
Organic chemicals
osmotic treatment
Ozone
Ozone - chemistry
Pharmaceutical Preparations - analysis
Pharmaceuticals
physical chemistry
Receiving waters
Reverse osmosis
Sewage - microbiology
Sludge
Surface water
Tandem Mass Spectrometry
Technology - methods
Ultrafiltration
Ultraviolet radiation
Ultraviolet Rays
Wastewater
Wastewater treatment
Water Pollutants, Chemical - analysis
water pollution
Water Purification - methods
Water treatment plants
title Evaluation of advanced treatment technologies for the elimination of pharmaceutical compounds
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