Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates

Benzylation and allylation of aldehyde acyl anions were enabled by the merger of a thiazolium N‐heterocyclic carbene (NHC) catalyst and a palladium/bisphosphine catalyst in a synergistic manner. Owing to the mildness of the reaction conditions, various functional groups were tolerated in the substra...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-03, Vol.57 (11), p.2938-2942
Hauptverfasser:	Yasuda, Shigeo, Ishii, Takuya, Takemoto, Shunsuke, Haruki, Hiroki, Ohmiya, Hirohisa
Format:	Artikel
Sprache:	eng
Schlagworte:	aldehydes Allyl compounds Anions carbenes Carbonates Catalysis Catalysts Chemical reactions Functional groups ketones Palladium Substrates synthetic methods
Online-Zugang:	Volltext
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