An access to 1,3-azasiline-fused quinolinones via oxidative heteroannulation involving silyl C(sp 3 )-H functionalization

A Mn-promoted intermolecular oxidative radical heteroannulation of N-(2-cyanoaryl)-acrylamides and tertiary silanes has been described, which provides an efficient route to produce silicon/nitrogen heterocycles, sila-analogues of the known carbon-based structural motifs prevalent in bioactive natura...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018, Vol.54 (11), p.1367-1370
Hauptverfasser:	Wu, Li-Jun, Yang, Yuan, Song, Ren-Jie, Yu, Jiang-Xi, Li, Jin-Heng, He, De-Liang
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactions Natural products Nitrogen Organic chemistry Silanes Silicon
Online-Zugang:	Volltext
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