Stacking-interaction-induced host-guest chemistry and Borromean rings based on a polypyridyl ligand

Template-free molecular Borromean rings (BRs) and open-ended molecular capsules were realized by strategic selection of the polypyridyl ligand tetrapyrido[3,2- a :2′,3′- c :3′′,2′′- h :2′′′,3′′′- j ] phenazine ( TPPHZ ) with a large surface area and specific geometry. The topology of these intricate...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018-02, Vol.54 (13), p.1559-1562
Hauptverfasser: Zhang, Hai-Ning, Gao, Wen-Xi, Deng, Yu-Xin, Lin, Yue-Jian, Jin, Guo-Xin
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container_issue 13
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container_title Chemical communications (Cambridge, England)
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creator Zhang, Hai-Ning
Gao, Wen-Xi
Deng, Yu-Xin
Lin, Yue-Jian
Jin, Guo-Xin
description Template-free molecular Borromean rings (BRs) and open-ended molecular capsules were realized by strategic selection of the polypyridyl ligand tetrapyrido[3,2- a :2′,3′- c :3′′,2′′- h :2′′′,3′′′- j ] phenazine ( TPPHZ ) with a large surface area and specific geometry. The topology of these intricate architectures was constructed via precisely controlled stacking interactions, as evidenced from single-crystal X-ray analysis. Template-free molecular Borromean rings and open-ended molecular capsules were constructed via precisely controlled stacking interactions.
doi_str_mv 10.1039/c7cc09448e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Ligands
Single crystals
Stacking
X ray analysis
title Stacking-interaction-induced host-guest chemistry and Borromean rings based on a polypyridyl ligand
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