Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells

A novel n‐type polymer of PTDI‐T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When usin...

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Veröffentlicht in:Macromolecular rapid communications. 2018-07, Vol.39 (14), p.e1700715-n/a
Hauptverfasser: Yang, Jing, Chen, Fan, Ran, Huijuan, Hu, Jian‐Yong, Xiao, Bo, Tang, Ailing, Wang, Xiaochen, Zhou, Erjun
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container_issue 14
container_start_page e1700715
container_title Macromolecular rapid communications.
container_volume 39
creator Yang, Jing
Chen, Fan
Ran, Huijuan
Hu, Jian‐Yong
Xiao, Bo
Tang, Ailing
Wang, Xiaochen
Zhou, Erjun
description A novel n‐type polymer of PTDI‐T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When using PBDB‐T as a donor, an open‐circuit voltage (VOC) as high as 1.03 V is obtained. The results indicate asymmetric rylene diimide is a kind of promising building block to construct n‐type photovoltaic polymers. The first n‐type polymer based on the asymmetric rylene diimide is designed and synthesized. PTDI‐T could realize a power conversion efficiency of 4.70% by using PTB7‐Th as a donor polymer, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI.
doi_str_mv 10.1002/marc.201700715
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The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When using PBDB‐T as a donor, an open‐circuit voltage (VOC) as high as 1.03 V is obtained. The results indicate asymmetric rylene diimide is a kind of promising building block to construct n‐type photovoltaic polymers. The first n‐type polymer based on the asymmetric rylene diimide is designed and synthesized. 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source Wiley Online Library Journals Frontfile Complete
subjects all‐polymer solar cells (all‐PSC)
Asymmetry
Chemical synthesis
Diimide
Energy conversion efficiency
naphthalene diimide (NDI)
non‐fullerene acceptors
Photovoltaic cells
Photovoltaics
Polymers
PTB7‐Th
Solar cells
thianaphthene‐fused perylenediimde (TDI)
title Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells
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