Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells
A novel n‐type polymer of PTDI‐T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When usin...
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Veröffentlicht in: | Macromolecular rapid communications. 2018-07, Vol.39 (14), p.e1700715-n/a |
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creator | Yang, Jing Chen, Fan Ran, Huijuan Hu, Jian‐Yong Xiao, Bo Tang, Ailing Wang, Xiaochen Zhou, Erjun |
description | A novel n‐type polymer of PTDI‐T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When using PBDB‐T as a donor, an open‐circuit voltage (VOC) as high as 1.03 V is obtained. The results indicate asymmetric rylene diimide is a kind of promising building block to construct n‐type photovoltaic polymers.
The first n‐type polymer based on the asymmetric rylene diimide is designed and synthesized. PTDI‐T could realize a power conversion efficiency of 4.70% by using PTB7‐Th as a donor polymer, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. |
doi_str_mv | 10.1002/marc.201700715 |
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The first n‐type polymer based on the asymmetric rylene diimide is designed and synthesized. PTDI‐T could realize a power conversion efficiency of 4.70% by using PTB7‐Th as a donor polymer, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.201700715</identifier><identifier>PMID: 29292584</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>all‐polymer solar cells (all‐PSC) ; Asymmetry ; Chemical synthesis ; Diimide ; Energy conversion efficiency ; naphthalene diimide (NDI) ; non‐fullerene acceptors ; Photovoltaic cells ; Photovoltaics ; Polymers ; PTB7‐Th ; Solar cells ; thianaphthene‐fused perylenediimde (TDI)</subject><ispartof>Macromolecular rapid communications., 2018-07, Vol.39 (14), p.e1700715-n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4105-76e5c17a39698f885c834a2ce3dbfe24caa822f4eec541734af510f873b1a3b53</citedby><cites>FETCH-LOGICAL-c4105-76e5c17a39698f885c834a2ce3dbfe24caa822f4eec541734af510f873b1a3b53</cites><orcidid>0000-0003-1182-311X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.201700715$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.201700715$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29292584$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Jing</creatorcontrib><creatorcontrib>Chen, Fan</creatorcontrib><creatorcontrib>Ran, Huijuan</creatorcontrib><creatorcontrib>Hu, Jian‐Yong</creatorcontrib><creatorcontrib>Xiao, Bo</creatorcontrib><creatorcontrib>Tang, Ailing</creatorcontrib><creatorcontrib>Wang, Xiaochen</creatorcontrib><creatorcontrib>Zhou, Erjun</creatorcontrib><title>Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells</title><title>Macromolecular rapid communications.</title><addtitle>Macromol Rapid Commun</addtitle><description>A novel n‐type polymer of PTDI‐T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When using PBDB‐T as a donor, an open‐circuit voltage (VOC) as high as 1.03 V is obtained. The results indicate asymmetric rylene diimide is a kind of promising building block to construct n‐type photovoltaic polymers.
The first n‐type polymer based on the asymmetric rylene diimide is designed and synthesized. PTDI‐T could realize a power conversion efficiency of 4.70% by using PTB7‐Th as a donor polymer, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI.</description><subject>all‐polymer solar cells (all‐PSC)</subject><subject>Asymmetry</subject><subject>Chemical synthesis</subject><subject>Diimide</subject><subject>Energy conversion efficiency</subject><subject>naphthalene diimide (NDI)</subject><subject>non‐fullerene acceptors</subject><subject>Photovoltaic cells</subject><subject>Photovoltaics</subject><subject>Polymers</subject><subject>PTB7‐Th</subject><subject>Solar cells</subject><subject>thianaphthene‐fused perylenediimde (TDI)</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkbFuFDEQhi1EREKgpUSWaGj2GNvrXW95XAhBSgAlobZ83jE48q4X-45oOwoegGfkSeLokiDRIBfj0XzzaaSfkBcMFgyAvxlMsgsOrAVomXxEDpjkrBIdbx-XP3BeMSGaffI05ysAUDXwJ2Sfd-VJVR-QX0eY_deRmrGnF_O4-VbaTKOjhn6MPzDQ8c_P35fzhPRzDPOAib41GXsaR7rM8zDgJnlLz-eAI9Ij7wffI3Ux0WKiy2kK3pqNL7QvCyEU2b3nIgaT6ApDyM_InjMh4_O7eki-HL-7XJ1Up5_ef1gtTytbM5BV26C0rDWiazrllJJWidpwi6JfO-S1NUZx7mpEK2vWlpmTDJxqxZoZsZbikLzeeacUv28xb_Tgsy0XmBHjNmvWKaFkXUso6Kt_0Ku4TWO5TnNoOUCjZFOoxY6yKeac0Okp-RLJrBno23z0bT76IZ-y8PJOu10P2D_g94EUoNsB1z7g_B-dPluer_7KbwDZaZ4W</recordid><startdate>201807</startdate><enddate>201807</enddate><creator>Yang, Jing</creator><creator>Chen, Fan</creator><creator>Ran, Huijuan</creator><creator>Hu, Jian‐Yong</creator><creator>Xiao, Bo</creator><creator>Tang, Ailing</creator><creator>Wang, Xiaochen</creator><creator>Zhou, Erjun</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1182-311X</orcidid></search><sort><creationdate>201807</creationdate><title>Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells</title><author>Yang, Jing ; Chen, Fan ; Ran, Huijuan ; Hu, Jian‐Yong ; Xiao, Bo ; Tang, Ailing ; Wang, Xiaochen ; Zhou, Erjun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4105-76e5c17a39698f885c834a2ce3dbfe24caa822f4eec541734af510f873b1a3b53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>all‐polymer solar cells (all‐PSC)</topic><topic>Asymmetry</topic><topic>Chemical synthesis</topic><topic>Diimide</topic><topic>Energy conversion efficiency</topic><topic>naphthalene diimide (NDI)</topic><topic>non‐fullerene acceptors</topic><topic>Photovoltaic cells</topic><topic>Photovoltaics</topic><topic>Polymers</topic><topic>PTB7‐Th</topic><topic>Solar cells</topic><topic>thianaphthene‐fused perylenediimde (TDI)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Jing</creatorcontrib><creatorcontrib>Chen, Fan</creatorcontrib><creatorcontrib>Ran, Huijuan</creatorcontrib><creatorcontrib>Hu, Jian‐Yong</creatorcontrib><creatorcontrib>Xiao, Bo</creatorcontrib><creatorcontrib>Tang, Ailing</creatorcontrib><creatorcontrib>Wang, Xiaochen</creatorcontrib><creatorcontrib>Zhou, Erjun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Jing</au><au>Chen, Fan</au><au>Ran, Huijuan</au><au>Hu, Jian‐Yong</au><au>Xiao, Bo</au><au>Tang, Ailing</au><au>Wang, Xiaochen</au><au>Zhou, Erjun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol Rapid Commun</addtitle><date>2018-07</date><risdate>2018</risdate><volume>39</volume><issue>14</issue><spage>e1700715</spage><epage>n/a</epage><pages>e1700715-n/a</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>A novel n‐type polymer of PTDI‐T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7‐Th:PTDI‐T‐based devices, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI. When using PBDB‐T as a donor, an open‐circuit voltage (VOC) as high as 1.03 V is obtained. The results indicate asymmetric rylene diimide is a kind of promising building block to construct n‐type photovoltaic polymers.
The first n‐type polymer based on the asymmetric rylene diimide is designed and synthesized. PTDI‐T could realize a power conversion efficiency of 4.70% by using PTB7‐Th as a donor polymer, which is obviously higher than those of the analogue polymers of PPDI‐2T and PDTCDI.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>29292584</pmid><doi>10.1002/marc.201700715</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-1182-311X</orcidid></addata></record> |
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subjects | all‐polymer solar cells (all‐PSC) Asymmetry Chemical synthesis Diimide Energy conversion efficiency naphthalene diimide (NDI) non‐fullerene acceptors Photovoltaic cells Photovoltaics Polymers PTB7‐Th Solar cells thianaphthene‐fused perylenediimde (TDI) |
title | Design and Synthesis of a Novel n‐Type Polymer Based on Asymmetric Rylene Diimide for the Application in All‐Polymer Solar Cells |
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