Central-to-axial chirality induction in biphenyl chiroptical probes for the stereochemical characterization of chiral primary amines

Flexible biphenyls have been applied as efficient and practical chiroptical probes for absolute configuration assignment to chiral primary amines. The mechanism of the central-to-axial chirality transfer from the amine moiety to the conformationally flexible biphenyl system has been determined by NM...

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Veröffentlicht in:	Organic & biomolecular chemistry 2018, Vol.16 (4), p.555-565
Hauptverfasser:	Vergura, S, Pisani, L, Scafato, P, Casarini, D, Superchi, S
Format:	Artikel
Sprache:	eng
Schlagworte:	Absolute configuration Amines Biphenyl Chirality Computer applications Configurations NMR Nuclear magnetic resonance Probes
Online-Zugang:	Volltext
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