Cationic Metallo‐Polyelectrolytes for Robust Alkaline Anion‐Exchange Membranes
Chemically inert, mechanically tough, cationic metallo‐polyelectrolytes were conceptualized and designed as durable anion‐exchange membranes (AEMs). Ring‐opening metathesis polymerization (ROMP) of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydr...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2018-02, Vol.57 (9), p.2388-2392 |
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| creator | Zhu, Tianyu Xu, Shichao Rahman, Anisur Dogdibegovic, Emir Yang, Peng Pageni, Parasmani Kabir, Mohammad Pabel Zhou, Xiao‐dong Tang, Chuanbing |
| description | Chemically inert, mechanically tough, cationic metallo‐polyelectrolytes were conceptualized and designed as durable anion‐exchange membranes (AEMs). Ring‐opening metathesis polymerization (ROMP) of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, led to a new class of AEMs with a polyethylene‐like framework and alkaline‐stable cobaltocenium cation for ion transport. These AEMs exhibited excellent thermal, chemical and mechanical stability, as well as high ion conductivity.
Ring‐opening metathesis polymerization of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, has led to a new class of anion‐exchange membranes (AEMs) with a polyethylene‐like framework and alkaline‐stable cobaltocenium cations for the ion transport. The AEMs show excellent thermal, chemical and mechanical stability, as well as high ion conductivity. |
| doi_str_mv | 10.1002/anie.201712387 |
| format | Article |
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Ring‐opening metathesis polymerization of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, has led to a new class of anion‐exchange membranes (AEMs) with a polyethylene‐like framework and alkaline‐stable cobaltocenium cations for the ion transport. The AEMs show excellent thermal, chemical and mechanical stability, as well as high ion conductivity.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201712387</identifier><identifier>PMID: 29291260</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Anion exchanging ; anion-exchange membranes ; Cation exchanging ; ion conductivity ; Ion transport ; Ions ; Membranes ; Metallography ; Metathesis ; microphase separation ; Polyelectrolytes ; Polyethylene ; Polyethylenes ; Polymerization</subject><ispartof>Angewandte Chemie International Edition, 2018-02, Vol.57 (9), p.2388-2392</ispartof><rights>2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4107-77b8b836d07843667036c97d1780ed585edf08961f0af370dcff6eadc8335fe23</citedby><cites>FETCH-LOGICAL-c4107-77b8b836d07843667036c97d1780ed585edf08961f0af370dcff6eadc8335fe23</cites><orcidid>0000-0002-0242-8241</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201712387$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201712387$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29291260$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhu, Tianyu</creatorcontrib><creatorcontrib>Xu, Shichao</creatorcontrib><creatorcontrib>Rahman, Anisur</creatorcontrib><creatorcontrib>Dogdibegovic, Emir</creatorcontrib><creatorcontrib>Yang, Peng</creatorcontrib><creatorcontrib>Pageni, Parasmani</creatorcontrib><creatorcontrib>Kabir, Mohammad Pabel</creatorcontrib><creatorcontrib>Zhou, Xiao‐dong</creatorcontrib><creatorcontrib>Tang, Chuanbing</creatorcontrib><title>Cationic Metallo‐Polyelectrolytes for Robust Alkaline Anion‐Exchange Membranes</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>Chemically inert, mechanically tough, cationic metallo‐polyelectrolytes were conceptualized and designed as durable anion‐exchange membranes (AEMs). Ring‐opening metathesis polymerization (ROMP) of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, led to a new class of AEMs with a polyethylene‐like framework and alkaline‐stable cobaltocenium cation for ion transport. These AEMs exhibited excellent thermal, chemical and mechanical stability, as well as high ion conductivity.
Ring‐opening metathesis polymerization of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, has led to a new class of anion‐exchange membranes (AEMs) with a polyethylene‐like framework and alkaline‐stable cobaltocenium cations for the ion transport. The AEMs show excellent thermal, chemical and mechanical stability, as well as high ion conductivity.</description><subject>Anion exchanging</subject><subject>anion-exchange membranes</subject><subject>Cation exchanging</subject><subject>ion conductivity</subject><subject>Ion transport</subject><subject>Ions</subject><subject>Membranes</subject><subject>Metallography</subject><subject>Metathesis</subject><subject>microphase separation</subject><subject>Polyelectrolytes</subject><subject>Polyethylene</subject><subject>Polyethylenes</subject><subject>Polymerization</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkLlOxDAURS0EYm8pUSQamgxeEtspR6NhkdiEoLYc5xkCnhjsRDAdn8A38iUYDYtEQ_Vuce7V00Foh-ARwZge6K6FEcVEEMqkWELrpKQkZ0Kw5ZQLxnIhS7KGNmK8T7yUmK-iNVrRilCO19HVRPet71qTnUGvnfPvr2-X3s3BgelDCj3EzPqQXfl6iH02dg_atR1k4y7VEjx9MXe6u4XUn9VBdxC30IrVLsL2191EN4fT68lxfnpxdDIZn-amIFjkQtSylow3WMiCcS4w46YSDRESQ1PKEhqLZcWJxdoygRtjLQfdGMlYaYGyTbS_2H0M_mmA2KtZGw04l57wQ1SkkoyWnBRVQvf-oPd-CF36TtFkpRK4LGSiRgvKBB9jAKseQzvTYa4IVp-21adt9WM7FXa_Zod6Bs0P_q03AdUCeG4dzP-ZU-Pzk-nv-AfzwY0U</recordid><startdate>20180223</startdate><enddate>20180223</enddate><creator>Zhu, Tianyu</creator><creator>Xu, Shichao</creator><creator>Rahman, Anisur</creator><creator>Dogdibegovic, Emir</creator><creator>Yang, Peng</creator><creator>Pageni, Parasmani</creator><creator>Kabir, Mohammad Pabel</creator><creator>Zhou, Xiao‐dong</creator><creator>Tang, Chuanbing</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0242-8241</orcidid></search><sort><creationdate>20180223</creationdate><title>Cationic Metallo‐Polyelectrolytes for Robust Alkaline Anion‐Exchange Membranes</title><author>Zhu, Tianyu ; Xu, Shichao ; Rahman, Anisur ; Dogdibegovic, Emir ; Yang, Peng ; Pageni, Parasmani ; Kabir, Mohammad Pabel ; Zhou, Xiao‐dong ; Tang, Chuanbing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4107-77b8b836d07843667036c97d1780ed585edf08961f0af370dcff6eadc8335fe23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Anion exchanging</topic><topic>anion-exchange membranes</topic><topic>Cation exchanging</topic><topic>ion conductivity</topic><topic>Ion transport</topic><topic>Ions</topic><topic>Membranes</topic><topic>Metallography</topic><topic>Metathesis</topic><topic>microphase separation</topic><topic>Polyelectrolytes</topic><topic>Polyethylene</topic><topic>Polyethylenes</topic><topic>Polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, Tianyu</creatorcontrib><creatorcontrib>Xu, Shichao</creatorcontrib><creatorcontrib>Rahman, Anisur</creatorcontrib><creatorcontrib>Dogdibegovic, Emir</creatorcontrib><creatorcontrib>Yang, Peng</creatorcontrib><creatorcontrib>Pageni, Parasmani</creatorcontrib><creatorcontrib>Kabir, Mohammad Pabel</creatorcontrib><creatorcontrib>Zhou, Xiao‐dong</creatorcontrib><creatorcontrib>Tang, Chuanbing</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, Tianyu</au><au>Xu, Shichao</au><au>Rahman, Anisur</au><au>Dogdibegovic, Emir</au><au>Yang, Peng</au><au>Pageni, Parasmani</au><au>Kabir, Mohammad Pabel</au><au>Zhou, Xiao‐dong</au><au>Tang, Chuanbing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cationic Metallo‐Polyelectrolytes for Robust Alkaline Anion‐Exchange Membranes</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2018-02-23</date><risdate>2018</risdate><volume>57</volume><issue>9</issue><spage>2388</spage><epage>2392</epage><pages>2388-2392</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Chemically inert, mechanically tough, cationic metallo‐polyelectrolytes were conceptualized and designed as durable anion‐exchange membranes (AEMs). Ring‐opening metathesis polymerization (ROMP) of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, led to a new class of AEMs with a polyethylene‐like framework and alkaline‐stable cobaltocenium cation for ion transport. These AEMs exhibited excellent thermal, chemical and mechanical stability, as well as high ion conductivity.
Ring‐opening metathesis polymerization of cobaltocenium‐containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation, has led to a new class of anion‐exchange membranes (AEMs) with a polyethylene‐like framework and alkaline‐stable cobaltocenium cations for the ion transport. The AEMs show excellent thermal, chemical and mechanical stability, as well as high ion conductivity.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>29291260</pmid><doi>10.1002/anie.201712387</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-0242-8241</orcidid></addata></record> |
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| subjects | Anion exchanging anion-exchange membranes Cation exchanging ion conductivity Ion transport Ions Membranes Metallography Metathesis microphase separation Polyelectrolytes Polyethylene Polyethylenes Polymerization |
| title | Cationic Metallo‐Polyelectrolytes for Robust Alkaline Anion‐Exchange Membranes |
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