Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Concentration Profiles in Sediments and Flood-Plain Soils of the Tittabawassee River, Michigan
Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in sediments and flood-plain soils collected along the Tittabawassee River in Michigan ranged from 102 to 53 600 pg/g, dry wt. Mean PCDD/PCDF concentrations in downstream sediment and soil were from 10- to 20-fold...
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| Veröffentlicht in: | Environmental science & technology 2003-02, Vol.37 (3), p.468-474 |
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| creator | Hilscherova, Klara Kannan, Kurunthachalam Nakata, Haruhiko Hanari, Nobuyasu Yamashita, Nobuyoshi Bradley, Patrick W Mccabe, John M Taylor, Allan B Giesy, John P |
| description | Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in sediments and flood-plain soils collected along the Tittabawassee River in Michigan ranged from 102 to 53 600 pg/g, dry wt. Mean PCDD/PCDF concentrations in downstream sediment and soil were from 10- to 20-fold greater than those found at locations upstream of Midland, Michigan. Concentrations of PCDD/PCDF in sediments and flood-plain soils from the Tittabawassee watershed were comparable to those found in industrialized areas such as the Housatonic and lower Passaic Rivers in the U.S. Concentrations of PCDDs/PCDFs in soil and sediment were not correlated with total organic carbon (TOC) in sediments or soils. OCDD and 2,3,7,8-TeCDF were the predominant congeners in sediment/soil collected from locations downstream of Midland, Michigan. Principal component analysis of the PCDD/PCDF congener profile suggested the presence of sources originating from a mixture of chlorophenol and other chlorinated compound production. Mass balance analysis of TCDD equivalents (TCDD-EQs) derived from H4IIE-luc bioassay of sediment extracts and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents (TEQs) estimated from instrumental analysis suggested that PCDDs/PCDFs were the major dioxin-like compounds present in sediments. A significant correlation existed between bioassay-derived TCDD-EQs and instrumentally measured TEQs (r 2 = 0.94). |
| doi_str_mv | 10.1021/es020920c |
| format | Article |
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Mean PCDD/PCDF concentrations in downstream sediment and soil were from 10- to 20-fold greater than those found at locations upstream of Midland, Michigan. Concentrations of PCDD/PCDF in sediments and flood-plain soils from the Tittabawassee watershed were comparable to those found in industrialized areas such as the Housatonic and lower Passaic Rivers in the U.S. Concentrations of PCDDs/PCDFs in soil and sediment were not correlated with total organic carbon (TOC) in sediments or soils. OCDD and 2,3,7,8-TeCDF were the predominant congeners in sediment/soil collected from locations downstream of Midland, Michigan. Principal component analysis of the PCDD/PCDF congener profile suggested the presence of sources originating from a mixture of chlorophenol and other chlorinated compound production. Mass balance analysis of TCDD equivalents (TCDD-EQs) derived from H4IIE-luc bioassay of sediment extracts and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents (TEQs) estimated from instrumental analysis suggested that PCDDs/PCDFs were the major dioxin-like compounds present in sediments. A significant correlation existed between bioassay-derived TCDD-EQs and instrumentally measured TEQs (r 2 = 0.94).</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es020920c</identifier><identifier>PMID: 12630460</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Benzofurans - analysis ; Bioassays ; Dibenzofurans, Polychlorinated ; Dioxins ; Earth sciences ; Earth, ocean, space ; Engineering and environment geology. Geothermics ; Environmental Monitoring ; Exact sciences and technology ; Freshwater ; Geologic Sediments - chemistry ; Hydrocarbons ; Industry ; Michigan ; PCB ; Pollution ; Pollution sources. Measurement results ; Pollution, environment geology ; Polychlorinated biphenyls ; Polychlorinated Dibenzodioxins - analogs & derivatives ; Polychlorinated Dibenzodioxins - analysis ; Principal components analysis ; Rivers ; Sediments ; Soil and sediments pollution ; Soil Pollutants - analysis ; Soils ; Water Movements</subject><ispartof>Environmental science & technology, 2003-02, Vol.37 (3), p.468-474</ispartof><rights>Copyright © 2003 American Chemical Society</rights><rights>2003 INIST-CNRS</rights><rights>Copyright American Chemical Society Feb 1, 2003</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a503t-5ca265e22e89ba912ac7ec2a90a07627bd9f34520080c078170f9e41c6e158143</citedby><cites>FETCH-LOGICAL-a503t-5ca265e22e89ba912ac7ec2a90a07627bd9f34520080c078170f9e41c6e158143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/es020920c$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/es020920c$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14523664$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12630460$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hilscherova, Klara</creatorcontrib><creatorcontrib>Kannan, Kurunthachalam</creatorcontrib><creatorcontrib>Nakata, Haruhiko</creatorcontrib><creatorcontrib>Hanari, Nobuyasu</creatorcontrib><creatorcontrib>Yamashita, Nobuyoshi</creatorcontrib><creatorcontrib>Bradley, Patrick W</creatorcontrib><creatorcontrib>Mccabe, John M</creatorcontrib><creatorcontrib>Taylor, Allan B</creatorcontrib><creatorcontrib>Giesy, John P</creatorcontrib><title>Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Concentration Profiles in Sediments and Flood-Plain Soils of the Tittabawassee River, Michigan</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in sediments and flood-plain soils collected along the Tittabawassee River in Michigan ranged from 102 to 53 600 pg/g, dry wt. Mean PCDD/PCDF concentrations in downstream sediment and soil were from 10- to 20-fold greater than those found at locations upstream of Midland, Michigan. Concentrations of PCDD/PCDF in sediments and flood-plain soils from the Tittabawassee watershed were comparable to those found in industrialized areas such as the Housatonic and lower Passaic Rivers in the U.S. Concentrations of PCDDs/PCDFs in soil and sediment were not correlated with total organic carbon (TOC) in sediments or soils. OCDD and 2,3,7,8-TeCDF were the predominant congeners in sediment/soil collected from locations downstream of Midland, Michigan. Principal component analysis of the PCDD/PCDF congener profile suggested the presence of sources originating from a mixture of chlorophenol and other chlorinated compound production. Mass balance analysis of TCDD equivalents (TCDD-EQs) derived from H4IIE-luc bioassay of sediment extracts and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents (TEQs) estimated from instrumental analysis suggested that PCDDs/PCDFs were the major dioxin-like compounds present in sediments. A significant correlation existed between bioassay-derived TCDD-EQs and instrumentally measured TEQs (r 2 = 0.94).</description><subject>Applied sciences</subject><subject>Benzofurans - analysis</subject><subject>Bioassays</subject><subject>Dibenzofurans, Polychlorinated</subject><subject>Dioxins</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Environmental Monitoring</subject><subject>Exact sciences and technology</subject><subject>Freshwater</subject><subject>Geologic Sediments - chemistry</subject><subject>Hydrocarbons</subject><subject>Industry</subject><subject>Michigan</subject><subject>PCB</subject><subject>Pollution</subject><subject>Pollution sources. Measurement results</subject><subject>Pollution, environment geology</subject><subject>Polychlorinated biphenyls</subject><subject>Polychlorinated Dibenzodioxins - analogs & derivatives</subject><subject>Polychlorinated Dibenzodioxins - analysis</subject><subject>Principal components analysis</subject><subject>Rivers</subject><subject>Sediments</subject><subject>Soil and sediments pollution</subject><subject>Soil Pollutants - analysis</subject><subject>Soils</subject><subject>Water Movements</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNplkd1uEzEQhVcIREPhghdAFhKVkFgY2_t7iVJCgRYiGgR3q1nvLHFx7GDvQstT8Mg4JEokuLLk883ROTNJ8pDDcw6Cv6AAAmoB6lYy4bmANK9yfjuZAHCZ1rL4cpTcC-EKAISE6m5yxEUhIStgkvyeO3OjlsZ5bXGgjp3qluwvl67TTrtrbRna_Wc_erRs6qwiO3gctLNs7l2vDQUW0Uvq9CpK4e_QzDjXpXODG8VpE5jr2bAkttDDgC3-xBCI2Ef9g_wzdqHVUn9Fez-506MJ9GD3HiefZq8W07P0_MPrN9OX5ynmIIc0VyiKnISgqm6x5gJVSUpgDQhlIcq2q3uZxV1ABQrKipfQ15RxVRDPK57J4-Rk67v27vtIYWhWOigyBi25MTS8rrisSh7Bx_-AV270NmZr4ja5zECWEXq6hZR3IXjqm7XXK_Q3DYdmc6Nmf6PIPtoZju2KugO5O0oEnuwADApNH5eudDhwsZYsik2FdMvpMND1Xkf_rSlKWebNYn7ZnL17_3n2dnYRw-59UYVDif8D_gGypbSt</recordid><startdate>20030201</startdate><enddate>20030201</enddate><creator>Hilscherova, Klara</creator><creator>Kannan, Kurunthachalam</creator><creator>Nakata, Haruhiko</creator><creator>Hanari, Nobuyasu</creator><creator>Yamashita, Nobuyoshi</creator><creator>Bradley, Patrick W</creator><creator>Mccabe, John M</creator><creator>Taylor, Allan B</creator><creator>Giesy, John P</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope><scope>7QH</scope><scope>7TG</scope><scope>7TV</scope><scope>7UA</scope><scope>F1W</scope><scope>H97</scope><scope>KL.</scope><scope>L.G</scope></search><sort><creationdate>20030201</creationdate><title>Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Concentration Profiles in Sediments and Flood-Plain Soils of the Tittabawassee River, Michigan</title><author>Hilscherova, Klara ; Kannan, Kurunthachalam ; Nakata, Haruhiko ; Hanari, Nobuyasu ; Yamashita, Nobuyoshi ; Bradley, Patrick W ; Mccabe, John M ; Taylor, Allan B ; Giesy, John P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a503t-5ca265e22e89ba912ac7ec2a90a07627bd9f34520080c078170f9e41c6e158143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>Benzofurans - analysis</topic><topic>Bioassays</topic><topic>Dibenzofurans, Polychlorinated</topic><topic>Dioxins</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Engineering and environment geology. Geothermics</topic><topic>Environmental Monitoring</topic><topic>Exact sciences and technology</topic><topic>Freshwater</topic><topic>Geologic Sediments - chemistry</topic><topic>Hydrocarbons</topic><topic>Industry</topic><topic>Michigan</topic><topic>PCB</topic><topic>Pollution</topic><topic>Pollution sources. Measurement results</topic><topic>Pollution, environment geology</topic><topic>Polychlorinated biphenyls</topic><topic>Polychlorinated Dibenzodioxins - analogs & derivatives</topic><topic>Polychlorinated Dibenzodioxins - analysis</topic><topic>Principal components analysis</topic><topic>Rivers</topic><topic>Sediments</topic><topic>Soil and sediments pollution</topic><topic>Soil Pollutants - analysis</topic><topic>Soils</topic><topic>Water Movements</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hilscherova, Klara</creatorcontrib><creatorcontrib>Kannan, Kurunthachalam</creatorcontrib><creatorcontrib>Nakata, Haruhiko</creatorcontrib><creatorcontrib>Hanari, Nobuyasu</creatorcontrib><creatorcontrib>Yamashita, Nobuyoshi</creatorcontrib><creatorcontrib>Bradley, Patrick W</creatorcontrib><creatorcontrib>Mccabe, John M</creatorcontrib><creatorcontrib>Taylor, Allan B</creatorcontrib><creatorcontrib>Giesy, John P</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>Aqualine</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hilscherova, Klara</au><au>Kannan, Kurunthachalam</au><au>Nakata, Haruhiko</au><au>Hanari, Nobuyasu</au><au>Yamashita, Nobuyoshi</au><au>Bradley, Patrick W</au><au>Mccabe, John M</au><au>Taylor, Allan B</au><au>Giesy, John P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Concentration Profiles in Sediments and Flood-Plain Soils of the Tittabawassee River, Michigan</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>2003-02-01</date><risdate>2003</risdate><volume>37</volume><issue>3</issue><spage>468</spage><epage>474</epage><pages>468-474</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in sediments and flood-plain soils collected along the Tittabawassee River in Michigan ranged from 102 to 53 600 pg/g, dry wt. Mean PCDD/PCDF concentrations in downstream sediment and soil were from 10- to 20-fold greater than those found at locations upstream of Midland, Michigan. Concentrations of PCDD/PCDF in sediments and flood-plain soils from the Tittabawassee watershed were comparable to those found in industrialized areas such as the Housatonic and lower Passaic Rivers in the U.S. Concentrations of PCDDs/PCDFs in soil and sediment were not correlated with total organic carbon (TOC) in sediments or soils. OCDD and 2,3,7,8-TeCDF were the predominant congeners in sediment/soil collected from locations downstream of Midland, Michigan. Principal component analysis of the PCDD/PCDF congener profile suggested the presence of sources originating from a mixture of chlorophenol and other chlorinated compound production. Mass balance analysis of TCDD equivalents (TCDD-EQs) derived from H4IIE-luc bioassay of sediment extracts and 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents (TEQs) estimated from instrumental analysis suggested that PCDDs/PCDFs were the major dioxin-like compounds present in sediments. A significant correlation existed between bioassay-derived TCDD-EQs and instrumentally measured TEQs (r 2 = 0.94).</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>12630460</pmid><doi>10.1021/es020920c</doi><tpages>7</tpages></addata></record> |
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| subjects | Applied sciences Benzofurans - analysis Bioassays Dibenzofurans, Polychlorinated Dioxins Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Environmental Monitoring Exact sciences and technology Freshwater Geologic Sediments - chemistry Hydrocarbons Industry Michigan PCB Pollution Pollution sources. Measurement results Pollution, environment geology Polychlorinated biphenyls Polychlorinated Dibenzodioxins - analogs & derivatives Polychlorinated Dibenzodioxins - analysis Principal components analysis Rivers Sediments Soil and sediments pollution Soil Pollutants - analysis Soils Water Movements |
| title | Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Concentration Profiles in Sediments and Flood-Plain Soils of the Tittabawassee River, Michigan |
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