p‑Carborane Conjugation in Radical Anions of Cage–Cage and Cage–Phenyl Compounds

Optical electron transfer (intervalence) transitions in radical anions of p-carborane oligomers attest to delocalization of electrons between two p-carboranes cages or a p-carborane and a phenyl ring. Oligomers of the 12 vertex p-carborane (C2B10H12) cage, [12], with up to 3 cages were synthesized,...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2018-01, Vol.122 (3), p.798-810
Hauptverfasser:	Cook, Andrew R, Valášek, Michal, Funston, Alison M, Poliakov, Pavel, Michl, Josef, Miller, John R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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