Effect of plasma immersion ion implantation on polycaprolactone with various molecular weights and crystallinity
Polycaprolactone with five different molecular weights was spin-coated on silicon wafers and plasma immersion ion implanted (PIII) with ion fluence in the range 5 × 10 14 –2 × 10 16 ions/cm 2 . The effects of PIII treatment on the optical properties, chemical structure, crystallinity, morphology, g...
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| Veröffentlicht in: | Journal of materials science. Materials in medicine 2018-01, Vol.29 (1), p.5-18, Article 5 |
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| creator | Kosobrodova, Elena Kondyurin, Alexey Chrzanowski, Wojciech Theodoropoulos, Christina Morganti, Elena Hutmacher, Dietmar Bilek, Marcela M. M. |
| description | Polycaprolactone with five different molecular weights was spin-coated on silicon wafers and plasma immersion ion implanted (PIII) with ion fluence in the range 5 × 10
14
–2 × 10
16
ions/cm
2
. The effects of PIII treatment on the optical properties, chemical structure, crystallinity, morphology, gel fraction formation and wettability were investigated. As in the case of a number of previously studied polymers, oxidation and hydrophobic recovery of the PIII treated PCL follow second order kinetics. CAPA 6250, which has the lowest molecular weight and the highest degree of crystallinity of the untreated PCL films studied, has the highest carbonization of the modified layer after PIII treatment. Untreated medical grade PCL films, mPCL PC12 (Perstorp) and mPCL Osteopore
TM
have similar chemical structures and crystallinity. Accordingly, the chemical and structural transformations caused by PIII treatment and post-treatment oxidation are almost identical for these two polymers. In general, PIII treatment destroys the nano-scale lamellar structure and results in a reduction of PCL crystallinity. Examination after washing PIII treated PCL films in toluene confirmed our hypothesis that cross-linking due to PIII treatment is significantly higher in semi-crystalline PCL as compared with amorphous polymers.
Graphical abstract |
| doi_str_mv | 10.1007/s10856-017-6009-1 |
| format | Article |
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14
–2 × 10
16
ions/cm
2
. The effects of PIII treatment on the optical properties, chemical structure, crystallinity, morphology, gel fraction formation and wettability were investigated. As in the case of a number of previously studied polymers, oxidation and hydrophobic recovery of the PIII treated PCL follow second order kinetics. CAPA 6250, which has the lowest molecular weight and the highest degree of crystallinity of the untreated PCL films studied, has the highest carbonization of the modified layer after PIII treatment. Untreated medical grade PCL films, mPCL PC12 (Perstorp) and mPCL Osteopore
TM
have similar chemical structures and crystallinity. Accordingly, the chemical and structural transformations caused by PIII treatment and post-treatment oxidation are almost identical for these two polymers. In general, PIII treatment destroys the nano-scale lamellar structure and results in a reduction of PCL crystallinity. Examination after washing PIII treated PCL films in toluene confirmed our hypothesis that cross-linking due to PIII treatment is significantly higher in semi-crystalline PCL as compared with amorphous polymers.
Graphical abstract</description><identifier>ISSN: 0957-4530</identifier><identifier>EISSN: 1573-4838</identifier><identifier>DOI: 10.1007/s10856-017-6009-1</identifier><identifier>PMID: 29243087</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Biocompatibility ; Biomaterials ; Biomaterials Synthesis and Characterization ; Biomedical Engineering and Bioengineering ; Biomedical materials ; Carbonization ; Ceramics ; Chemistry and Materials Science ; Composites ; Crosslinking ; Crystal structure ; Crystallinity ; Degree of crystallinity ; Glass ; Hydrophobicity ; Immersion ; Ion implantation ; Kinetics ; Lamellar structure ; Materials Science ; Molecular weight ; Natural Materials ; Optical properties ; Oxidation ; Polycaprolactone ; Polymer Sciences ; Polymers ; Regenerative Medicine/Tissue Engineering ; Silicon wafers ; Surfaces and Interfaces ; Thin Films ; Toluene ; Wettability</subject><ispartof>Journal of materials science. Materials in medicine, 2018-01, Vol.29 (1), p.5-18, Article 5</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2017</rights><rights>Journal of Materials Science: Materials in Medicine is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c372t-4c7046d3dab1db14c5fbd9636e2e963fd0e66ab380659784a898b2a5cbcfea23</citedby><cites>FETCH-LOGICAL-c372t-4c7046d3dab1db14c5fbd9636e2e963fd0e66ab380659784a898b2a5cbcfea23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10856-017-6009-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10856-017-6009-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29243087$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kosobrodova, Elena</creatorcontrib><creatorcontrib>Kondyurin, Alexey</creatorcontrib><creatorcontrib>Chrzanowski, Wojciech</creatorcontrib><creatorcontrib>Theodoropoulos, Christina</creatorcontrib><creatorcontrib>Morganti, Elena</creatorcontrib><creatorcontrib>Hutmacher, Dietmar</creatorcontrib><creatorcontrib>Bilek, Marcela M. M.</creatorcontrib><title>Effect of plasma immersion ion implantation on polycaprolactone with various molecular weights and crystallinity</title><title>Journal of materials science. Materials in medicine</title><addtitle>J Mater Sci: Mater Med</addtitle><addtitle>J Mater Sci Mater Med</addtitle><description>Polycaprolactone with five different molecular weights was spin-coated on silicon wafers and plasma immersion ion implanted (PIII) with ion fluence in the range 5 × 10
14
–2 × 10
16
ions/cm
2
. The effects of PIII treatment on the optical properties, chemical structure, crystallinity, morphology, gel fraction formation and wettability were investigated. As in the case of a number of previously studied polymers, oxidation and hydrophobic recovery of the PIII treated PCL follow second order kinetics. CAPA 6250, which has the lowest molecular weight and the highest degree of crystallinity of the untreated PCL films studied, has the highest carbonization of the modified layer after PIII treatment. Untreated medical grade PCL films, mPCL PC12 (Perstorp) and mPCL Osteopore
TM
have similar chemical structures and crystallinity. Accordingly, the chemical and structural transformations caused by PIII treatment and post-treatment oxidation are almost identical for these two polymers. In general, PIII treatment destroys the nano-scale lamellar structure and results in a reduction of PCL crystallinity. Examination after washing PIII treated PCL films in toluene confirmed our hypothesis that cross-linking due to PIII treatment is significantly higher in semi-crystalline PCL as compared with amorphous polymers.
Graphical abstract</description><subject>Biocompatibility</subject><subject>Biomaterials</subject><subject>Biomaterials Synthesis and Characterization</subject><subject>Biomedical Engineering and Bioengineering</subject><subject>Biomedical materials</subject><subject>Carbonization</subject><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Crosslinking</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Degree of crystallinity</subject><subject>Glass</subject><subject>Hydrophobicity</subject><subject>Immersion</subject><subject>Ion implantation</subject><subject>Kinetics</subject><subject>Lamellar structure</subject><subject>Materials Science</subject><subject>Molecular weight</subject><subject>Natural Materials</subject><subject>Optical properties</subject><subject>Oxidation</subject><subject>Polycaprolactone</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Regenerative Medicine/Tissue Engineering</subject><subject>Silicon wafers</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Toluene</subject><subject>Wettability</subject><issn>0957-4530</issn><issn>1573-4838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kU1r3DAQhkVp6G42-QG9FEEvvbgZWdaHj2FJm0Cgl9yFLMuJFtlyJbnL_vtos2kpgYDEMNIzr0bzIvSZwHcCIK4SAcl4BURUHKCtyAe0JkzQqpFUfkRraJmoGkZhhc5T2gFA0zL2Ca3qtm4oSLFG880wWJNxGPDsdRo1duNoY3Jhwi97LMdT1vmYlDUHfzB6jsFrk8Nk8d7lJ_xHRxeWhMfgrVm8jnhv3eNTTlhPPTbxkLL23k0uHy7Q2aB9spevcYMeftw8bG-r-18_77bX95Whos5VYwQ0vKe97kjfkcawoetbTrmtbQlDD5Zz3VEJnLVCNlq2sqs1M50ZrK7pBn07yZZWfy82ZTW6ZKwvn7GlU0VaIYSkAnhBv75Bd2GJU2nuhSKE8jLTDSInysSQUrSDmqMbdTwoAurohjq5oYob6uiGIqXmy6vy0o22_1fxd_wFqE9AKlfTo43_Pf2u6jNDqZeR</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Kosobrodova, Elena</creator><creator>Kondyurin, Alexey</creator><creator>Chrzanowski, Wojciech</creator><creator>Theodoropoulos, Christina</creator><creator>Morganti, Elena</creator><creator>Hutmacher, Dietmar</creator><creator>Bilek, Marcela M. 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Materials in medicine</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kosobrodova, Elena</au><au>Kondyurin, Alexey</au><au>Chrzanowski, Wojciech</au><au>Theodoropoulos, Christina</au><au>Morganti, Elena</au><au>Hutmacher, Dietmar</au><au>Bilek, Marcela M. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of plasma immersion ion implantation on polycaprolactone with various molecular weights and crystallinity</atitle><jtitle>Journal of materials science. Materials in medicine</jtitle><stitle>J Mater Sci: Mater Med</stitle><addtitle>J Mater Sci Mater Med</addtitle><date>2018-01-01</date><risdate>2018</risdate><volume>29</volume><issue>1</issue><spage>5</spage><epage>18</epage><pages>5-18</pages><artnum>5</artnum><issn>0957-4530</issn><eissn>1573-4838</eissn><abstract>Polycaprolactone with five different molecular weights was spin-coated on silicon wafers and plasma immersion ion implanted (PIII) with ion fluence in the range 5 × 10
14
–2 × 10
16
ions/cm
2
. The effects of PIII treatment on the optical properties, chemical structure, crystallinity, morphology, gel fraction formation and wettability were investigated. As in the case of a number of previously studied polymers, oxidation and hydrophobic recovery of the PIII treated PCL follow second order kinetics. CAPA 6250, which has the lowest molecular weight and the highest degree of crystallinity of the untreated PCL films studied, has the highest carbonization of the modified layer after PIII treatment. Untreated medical grade PCL films, mPCL PC12 (Perstorp) and mPCL Osteopore
TM
have similar chemical structures and crystallinity. Accordingly, the chemical and structural transformations caused by PIII treatment and post-treatment oxidation are almost identical for these two polymers. In general, PIII treatment destroys the nano-scale lamellar structure and results in a reduction of PCL crystallinity. Examination after washing PIII treated PCL films in toluene confirmed our hypothesis that cross-linking due to PIII treatment is significantly higher in semi-crystalline PCL as compared with amorphous polymers.
Graphical abstract</abstract><cop>New York</cop><pub>Springer US</pub><pmid>29243087</pmid><doi>10.1007/s10856-017-6009-1</doi><tpages>18</tpages></addata></record> |
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| identifier | ISSN: 0957-4530 |
| ispartof | Journal of materials science. Materials in medicine, 2018-01, Vol.29 (1), p.5-18, Article 5 |
| issn | 0957-4530 1573-4838 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Biocompatibility Biomaterials Biomaterials Synthesis and Characterization Biomedical Engineering and Bioengineering Biomedical materials Carbonization Ceramics Chemistry and Materials Science Composites Crosslinking Crystal structure Crystallinity Degree of crystallinity Glass Hydrophobicity Immersion Ion implantation Kinetics Lamellar structure Materials Science Molecular weight Natural Materials Optical properties Oxidation Polycaprolactone Polymer Sciences Polymers Regenerative Medicine/Tissue Engineering Silicon wafers Surfaces and Interfaces Thin Films Toluene Wettability |
| title | Effect of plasma immersion ion implantation on polycaprolactone with various molecular weights and crystallinity |
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