Synthesis and Reactivity of the Phosphorus Analogues of Cyclopentadienone, Tricyclopentanone, and Housene

The phosphorus analogues of cyclopentadienone, tricyclopentanone, and housene were accessed from bis(cyclopropenyl)diphosphetanedione 3, which was prepared by mixing 1,2,3‐tris‐tert‐butylcyclopropenium tetrafluoroborate (1) and sodium phosphaethynolate [Na(OCP)(dioxane)n]. While photolysis of 3 resu...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-02, Vol.57 (6), p.1683-1687
Hauptverfasser:	Krachko, Tetiana, Ehlers, Andreas W., Nieger, Martin, Lutz, Martin, Slootweg, J. Chris
Format:	Artikel
Sprache:	eng
Schlagworte:	Isomerization main-group elements Pentanone pericyclic reactions Phosphorus Photolysis small ring systems Sodium valence isomerization
Online-Zugang:	Volltext
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