Direct Decarboxylative–Decarbonylative Alkylation of α‑Oxo Acids with Electrophilic Olefins via Visible-Light Photoredox Catalysis

The decarbonylation of primary, secondary, and tertiary alkyl-substituted acyl radicals has been investigated through photoredox catalysis. A series of quaternary carbons and γ-ketoesters have been directly constructed by the photoredox 1,4-conjugate addition of the corresponding alkyl ketoacids wit...

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Veröffentlicht in:	Journal of organic chemistry 2018-01, Vol.83 (1), p.253-259
Hauptverfasser:	Chen, Jian-Qiang, Chang, Rui, Wei, Yun-Long, Mo, Jia-Nan, Wang, Zhu-Yin, Xu, Peng-Fei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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