Stable Push–Pull Disilene: Substantial Donor–Acceptor Interactions through the SiSi Double Bond

The push–pull effect has been widely used to effectively tune π-electron systems. Herein, we report the synthesis and properties of 1-amino-2-boryldisilene 1 as the first push–pull disilene. Its spectroscopic and structural features show substantial interactions between the SiSi double bond and the...

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Veröffentlicht in:	Journal of the American Chemical Society 2017-12, Vol.139 (50), p.18146-18149
Hauptverfasser:	Kosai, Tomoyuki, Iwamoto, Takeaki
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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