Regio- and Chemoselective Hydrogenation of Dienes to Monoenes Governed by a Well-Structured Bimetallic Surface

Unprecedented surface chemistry, governed by specific atomic arrangements and the steric effect of ordered alloys, is reported. Rh-based ordered alloys supported on SiO2 (Rh x M y /SiO2, M = Bi, Cu, Fe, Ga, In, Pb, Sn, and Zn) were prepared and tested as catalysts for selective hydrogenation of tran...

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Veröffentlicht in:Journal of the American Chemical Society 2017-12, Vol.139 (50), p.18231-18239
Hauptverfasser: Miyazaki, Masayoshi, Furukawa, Shinya, Komatsu, Takayuki
Format: Artikel
Sprache:eng
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