Landfill leachate treatment with ozone and ozone/hydrogen peroxide systems

In the search for an efficient and economical method to treat a leachate generated from a controlled municipal solid waste landfill site (Jebel Chakir) in the region of greater Tunis in Tunisia, ozone alone and ozone combined with hydrogen peroxide were studied. The leachate was characterised by hig...

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Veröffentlicht in:Journal of hazardous materials 2007-02, Vol.140 (1), p.316-324
Hauptverfasser: Tizaoui, Chedly, Bouselmi, Latifa, Mansouri, Loubna, Ghrabi, Ahmed
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container_title Journal of hazardous materials
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creator Tizaoui, Chedly
Bouselmi, Latifa
Mansouri, Loubna
Ghrabi, Ahmed
description In the search for an efficient and economical method to treat a leachate generated from a controlled municipal solid waste landfill site (Jebel Chakir) in the region of greater Tunis in Tunisia, ozone alone and ozone combined with hydrogen peroxide were studied. The leachate was characterised by high COD, low biodegradability and intense dark colour. A purpose-built reactor, to avoid foaming, was used for the study. It was found that ozone efficacy was almost doubled when combined with hydrogen peroxide at 2 g/L but higher H 2O 2 concentrations gave lower performances. Enhancement in the leachate biodegradability from about 0.1 to about 0.7 was achieved by the O 3/H 2O 2 system. Insignificant changes in pH that may due to buffering effect of bicarbonate was found. A small decrease in sulphate concentrations were also observed. In contrast, chloride concentration declined at the beginning of the experiment then increased to reach its initial value. Estimates of the operating costs were made for comparison purposes and it was found that the O 3/H 2O 2 system at 2 g/L H 2O 2 gave the lowest cost of about 3.1 TND (∼2.3 USD)/kg COD removed.
doi_str_mv 10.1016/j.jhazmat.2006.09.023
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source MEDLINE; Elsevier ScienceDirect Journals
subjects Advanced oxidation processes
Applied sciences
Biodegradation, Environmental
Chemical engineering
Chlorides
Costs and Cost Analysis
Environmental Restoration and Remediation - economics
Environmental Restoration and Remediation - methods
Exact sciences and technology
General treatment and storage processes
Hydrogen Peroxide
Jebel Chakir
Landfill leachate
Ozone
Pollution
Reactors
Sulfates
Urban and domestic wastes
Wastes
Water Pollutants, Chemical
title Landfill leachate treatment with ozone and ozone/hydrogen peroxide systems
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