A laboratory heterodyne emission spectrometer at submillimeter wavelengths
We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receive...
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creator | Wehres, N Maßen, J Borisov, K Schmidt, B Lewen, F Graf, U U Honingh, C E Higgins, D R Schlemmer, S |
description | We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receiver operates at RF frequencies between 270 and 390 GHz, coincident with Band 7 of the ALMA telescope. The instantaneous bandwidth is 5 GHz (DSB). In this work the full spectrometer and its components are described. Its performance, in particular its sensitivity, stability, reproducibility and systematic errors, is characterized in detail. For this purpose very broad band emission spectra of methyl cyanide have been recorded and compared to theoretical spectra. Isotopic variants are found in natural abundance and features attributed to vibrationally excited species are all recorded in the same spectrum. The performance of the new spectrometer is compared extensively to that of a traditional FM-absorption spectrometer and to recent versions of chirped-pulse spectrometers operated in the mm-wave regime. Further applications and future advancements of the current instrument are discussed. |
doi_str_mv | 10.1039/c7cp06394f |
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The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receiver operates at RF frequencies between 270 and 390 GHz, coincident with Band 7 of the ALMA telescope. The instantaneous bandwidth is 5 GHz (DSB). In this work the full spectrometer and its components are described. Its performance, in particular its sensitivity, stability, reproducibility and systematic errors, is characterized in detail. For this purpose very broad band emission spectra of methyl cyanide have been recorded and compared to theoretical spectra. Isotopic variants are found in natural abundance and features attributed to vibrationally excited species are all recorded in the same spectrum. The performance of the new spectrometer is compared extensively to that of a traditional FM-absorption spectrometer and to recent versions of chirped-pulse spectrometers operated in the mm-wave regime. Further applications and future advancements of the current instrument are discussed.</description><subject>Acetonitrile</subject><subject>Broadband</subject><subject>Cyanides</subject><subject>Emission spectra</subject><subject>Laboratories</subject><subject>Millimeter waves</subject><subject>Radio frequency</subject><subject>Radio telescopes</subject><subject>Reproducibility</subject><subject>Spectrometers</subject><subject>Spectrum analysis</subject><subject>Systematic errors</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkE1Lw0AQhhdRbK1e_AES8CJCdGc3-5FjCdYPCnrQc9hudm1Kko27SaX_3tTWHjzNMO_Dy_AgdAn4DjBN77XQLeY0TewRGkPCaZximRwfdsFH6CyEFcYYGNBTNCIpcMkAj9HLNKrUwnnVOb-JlqYz3hWbxkSmLkMoXROF1ujOu3obRaqLQr-oy6oqd4dvtTaVaT67ZThHJ1ZVwVzs5wR9zB7es6d4_vr4nE3nsU4I6WKwXDFLLCOCa2mlsIpaIejCgraGqQJjDolhkhEmrLRFYgWkQ6hkQRIFdIJudr2td1-9CV0-vKpNVanGuD7kkHIhOQaBB_T6H7pyvW-G73KCAUtOGU0H6nZHae9C8MbmrS9r5Tc54HxrOM9E9vZreDbAV_vKwYMpDuifUvoDmN52zg</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Wehres, N</creator><creator>Maßen, J</creator><creator>Borisov, K</creator><creator>Schmidt, B</creator><creator>Lewen, F</creator><creator>Graf, U U</creator><creator>Honingh, C E</creator><creator>Higgins, D R</creator><creator>Schlemmer, S</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8881-2916</orcidid><orcidid>https://orcid.org/0000-0003-4439-6716</orcidid><orcidid>https://orcid.org/0000-0002-1421-7281</orcidid></search><sort><creationdate>2018</creationdate><title>A laboratory heterodyne emission spectrometer at submillimeter wavelengths</title><author>Wehres, N ; Maßen, J ; Borisov, K ; Schmidt, B ; Lewen, F ; Graf, U U ; Honingh, C E ; Higgins, D R ; Schlemmer, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-1f6a5f2f5276c8f87fa3f773bf1cfe5ad00614e585257f8fd4f719f1ca8d24a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Acetonitrile</topic><topic>Broadband</topic><topic>Cyanides</topic><topic>Emission spectra</topic><topic>Laboratories</topic><topic>Millimeter waves</topic><topic>Radio frequency</topic><topic>Radio telescopes</topic><topic>Reproducibility</topic><topic>Spectrometers</topic><topic>Spectrum analysis</topic><topic>Systematic errors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wehres, N</creatorcontrib><creatorcontrib>Maßen, J</creatorcontrib><creatorcontrib>Borisov, K</creatorcontrib><creatorcontrib>Schmidt, B</creatorcontrib><creatorcontrib>Lewen, F</creatorcontrib><creatorcontrib>Graf, U U</creatorcontrib><creatorcontrib>Honingh, C E</creatorcontrib><creatorcontrib>Higgins, D R</creatorcontrib><creatorcontrib>Schlemmer, S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wehres, N</au><au>Maßen, J</au><au>Borisov, K</au><au>Schmidt, B</au><au>Lewen, F</au><au>Graf, U U</au><au>Honingh, C E</au><au>Higgins, D R</au><au>Schlemmer, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A laboratory heterodyne emission spectrometer at submillimeter wavelengths</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2018</date><risdate>2018</risdate><volume>20</volume><issue>8</issue><spage>5530</spage><epage>5544</epage><pages>5530-5544</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. 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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Acetonitrile Broadband Cyanides Emission spectra Laboratories Millimeter waves Radio frequency Radio telescopes Reproducibility Spectrometers Spectrum analysis Systematic errors |
title | A laboratory heterodyne emission spectrometer at submillimeter wavelengths |
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