A laboratory heterodyne emission spectrometer at submillimeter wavelengths

We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receive...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Physical chemistry chemical physics : PCCP 2018, Vol.20 (8), p.5530-5544
Hauptverfasser: Wehres, N, Maßen, J, Borisov, K, Schmidt, B, Lewen, F, Graf, U U, Honingh, C E, Higgins, D R, Schlemmer, S
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 5544
container_issue 8
container_start_page 5530
container_title Physical chemistry chemical physics : PCCP
container_volume 20
creator Wehres, N
Maßen, J
Borisov, K
Schmidt, B
Lewen, F
Graf, U U
Honingh, C E
Higgins, D R
Schlemmer, S
description We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receiver operates at RF frequencies between 270 and 390 GHz, coincident with Band 7 of the ALMA telescope. The instantaneous bandwidth is 5 GHz (DSB). In this work the full spectrometer and its components are described. Its performance, in particular its sensitivity, stability, reproducibility and systematic errors, is characterized in detail. For this purpose very broad band emission spectra of methyl cyanide have been recorded and compared to theoretical spectra. Isotopic variants are found in natural abundance and features attributed to vibrationally excited species are all recorded in the same spectrum. The performance of the new spectrometer is compared extensively to that of a traditional FM-absorption spectrometer and to recent versions of chirped-pulse spectrometers operated in the mm-wave regime. Further applications and future advancements of the current instrument are discussed.
doi_str_mv 10.1039/c7cp06394f
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1967860170</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2010863539</sourcerecordid><originalsourceid>FETCH-LOGICAL-c422t-1f6a5f2f5276c8f87fa3f773bf1cfe5ad00614e585257f8fd4f719f1ca8d24a13</originalsourceid><addsrcrecordid>eNpdkE1Lw0AQhhdRbK1e_AES8CJCdGc3-5FjCdYPCnrQc9hudm1Kko27SaX_3tTWHjzNMO_Dy_AgdAn4DjBN77XQLeY0TewRGkPCaZximRwfdsFH6CyEFcYYGNBTNCIpcMkAj9HLNKrUwnnVOb-JlqYz3hWbxkSmLkMoXROF1ujOu3obRaqLQr-oy6oqd4dvtTaVaT67ZThHJ1ZVwVzs5wR9zB7es6d4_vr4nE3nsU4I6WKwXDFLLCOCa2mlsIpaIejCgraGqQJjDolhkhEmrLRFYgWkQ6hkQRIFdIJudr2td1-9CV0-vKpNVanGuD7kkHIhOQaBB_T6H7pyvW-G73KCAUtOGU0H6nZHae9C8MbmrS9r5Tc54HxrOM9E9vZreDbAV_vKwYMpDuifUvoDmN52zg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2010863539</pqid></control><display><type>article</type><title>A laboratory heterodyne emission spectrometer at submillimeter wavelengths</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Wehres, N ; Maßen, J ; Borisov, K ; Schmidt, B ; Lewen, F ; Graf, U U ; Honingh, C E ; Higgins, D R ; Schlemmer, S</creator><creatorcontrib>Wehres, N ; Maßen, J ; Borisov, K ; Schmidt, B ; Lewen, F ; Graf, U U ; Honingh, C E ; Higgins, D R ; Schlemmer, S</creatorcontrib><description>We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receiver operates at RF frequencies between 270 and 390 GHz, coincident with Band 7 of the ALMA telescope. The instantaneous bandwidth is 5 GHz (DSB). In this work the full spectrometer and its components are described. Its performance, in particular its sensitivity, stability, reproducibility and systematic errors, is characterized in detail. For this purpose very broad band emission spectra of methyl cyanide have been recorded and compared to theoretical spectra. Isotopic variants are found in natural abundance and features attributed to vibrationally excited species are all recorded in the same spectrum. The performance of the new spectrometer is compared extensively to that of a traditional FM-absorption spectrometer and to recent versions of chirped-pulse spectrometers operated in the mm-wave regime. Further applications and future advancements of the current instrument are discussed.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c7cp06394f</identifier><identifier>PMID: 29168510</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acetonitrile ; Broadband ; Cyanides ; Emission spectra ; Laboratories ; Millimeter waves ; Radio frequency ; Radio telescopes ; Reproducibility ; Spectrometers ; Spectrum analysis ; Systematic errors</subject><ispartof>Physical chemistry chemical physics : PCCP, 2018, Vol.20 (8), p.5530-5544</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-1f6a5f2f5276c8f87fa3f773bf1cfe5ad00614e585257f8fd4f719f1ca8d24a13</citedby><cites>FETCH-LOGICAL-c422t-1f6a5f2f5276c8f87fa3f773bf1cfe5ad00614e585257f8fd4f719f1ca8d24a13</cites><orcidid>0000-0001-8881-2916 ; 0000-0003-4439-6716 ; 0000-0002-1421-7281</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29168510$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wehres, N</creatorcontrib><creatorcontrib>Maßen, J</creatorcontrib><creatorcontrib>Borisov, K</creatorcontrib><creatorcontrib>Schmidt, B</creatorcontrib><creatorcontrib>Lewen, F</creatorcontrib><creatorcontrib>Graf, U U</creatorcontrib><creatorcontrib>Honingh, C E</creatorcontrib><creatorcontrib>Higgins, D R</creatorcontrib><creatorcontrib>Schlemmer, S</creatorcontrib><title>A laboratory heterodyne emission spectrometer at submillimeter wavelengths</title><title>Physical chemistry chemical physics : PCCP</title><addtitle>Phys Chem Chem Phys</addtitle><description>We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receiver operates at RF frequencies between 270 and 390 GHz, coincident with Band 7 of the ALMA telescope. The instantaneous bandwidth is 5 GHz (DSB). In this work the full spectrometer and its components are described. Its performance, in particular its sensitivity, stability, reproducibility and systematic errors, is characterized in detail. For this purpose very broad band emission spectra of methyl cyanide have been recorded and compared to theoretical spectra. Isotopic variants are found in natural abundance and features attributed to vibrationally excited species are all recorded in the same spectrum. The performance of the new spectrometer is compared extensively to that of a traditional FM-absorption spectrometer and to recent versions of chirped-pulse spectrometers operated in the mm-wave regime. Further applications and future advancements of the current instrument are discussed.</description><subject>Acetonitrile</subject><subject>Broadband</subject><subject>Cyanides</subject><subject>Emission spectra</subject><subject>Laboratories</subject><subject>Millimeter waves</subject><subject>Radio frequency</subject><subject>Radio telescopes</subject><subject>Reproducibility</subject><subject>Spectrometers</subject><subject>Spectrum analysis</subject><subject>Systematic errors</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkE1Lw0AQhhdRbK1e_AES8CJCdGc3-5FjCdYPCnrQc9hudm1Kko27SaX_3tTWHjzNMO_Dy_AgdAn4DjBN77XQLeY0TewRGkPCaZximRwfdsFH6CyEFcYYGNBTNCIpcMkAj9HLNKrUwnnVOb-JlqYz3hWbxkSmLkMoXROF1ujOu3obRaqLQr-oy6oqd4dvtTaVaT67ZThHJ1ZVwVzs5wR9zB7es6d4_vr4nE3nsU4I6WKwXDFLLCOCa2mlsIpaIejCgraGqQJjDolhkhEmrLRFYgWkQ6hkQRIFdIJudr2td1-9CV0-vKpNVanGuD7kkHIhOQaBB_T6H7pyvW-G73KCAUtOGU0H6nZHae9C8MbmrS9r5Tc54HxrOM9E9vZreDbAV_vKwYMpDuifUvoDmN52zg</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Wehres, N</creator><creator>Maßen, J</creator><creator>Borisov, K</creator><creator>Schmidt, B</creator><creator>Lewen, F</creator><creator>Graf, U U</creator><creator>Honingh, C E</creator><creator>Higgins, D R</creator><creator>Schlemmer, S</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8881-2916</orcidid><orcidid>https://orcid.org/0000-0003-4439-6716</orcidid><orcidid>https://orcid.org/0000-0002-1421-7281</orcidid></search><sort><creationdate>2018</creationdate><title>A laboratory heterodyne emission spectrometer at submillimeter wavelengths</title><author>Wehres, N ; Maßen, J ; Borisov, K ; Schmidt, B ; Lewen, F ; Graf, U U ; Honingh, C E ; Higgins, D R ; Schlemmer, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-1f6a5f2f5276c8f87fa3f773bf1cfe5ad00614e585257f8fd4f719f1ca8d24a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Acetonitrile</topic><topic>Broadband</topic><topic>Cyanides</topic><topic>Emission spectra</topic><topic>Laboratories</topic><topic>Millimeter waves</topic><topic>Radio frequency</topic><topic>Radio telescopes</topic><topic>Reproducibility</topic><topic>Spectrometers</topic><topic>Spectrum analysis</topic><topic>Systematic errors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wehres, N</creatorcontrib><creatorcontrib>Maßen, J</creatorcontrib><creatorcontrib>Borisov, K</creatorcontrib><creatorcontrib>Schmidt, B</creatorcontrib><creatorcontrib>Lewen, F</creatorcontrib><creatorcontrib>Graf, U U</creatorcontrib><creatorcontrib>Honingh, C E</creatorcontrib><creatorcontrib>Higgins, D R</creatorcontrib><creatorcontrib>Schlemmer, S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wehres, N</au><au>Maßen, J</au><au>Borisov, K</au><au>Schmidt, B</au><au>Lewen, F</au><au>Graf, U U</au><au>Honingh, C E</au><au>Higgins, D R</au><au>Schlemmer, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A laboratory heterodyne emission spectrometer at submillimeter wavelengths</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2018</date><risdate>2018</risdate><volume>20</volume><issue>8</issue><spage>5530</spage><epage>5544</epage><pages>5530-5544</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>We present first results on a newly built broadband emission spectrometer for the laboratory making use of a double sideband (DSB) heterodyne receiver. The new spectrometer is perfectly suited for high-resolution emission spectroscopy of molecules of astrophysical importance. The current SIS receiver operates at RF frequencies between 270 and 390 GHz, coincident with Band 7 of the ALMA telescope. The instantaneous bandwidth is 5 GHz (DSB). In this work the full spectrometer and its components are described. Its performance, in particular its sensitivity, stability, reproducibility and systematic errors, is characterized in detail. For this purpose very broad band emission spectra of methyl cyanide have been recorded and compared to theoretical spectra. Isotopic variants are found in natural abundance and features attributed to vibrationally excited species are all recorded in the same spectrum. The performance of the new spectrometer is compared extensively to that of a traditional FM-absorption spectrometer and to recent versions of chirped-pulse spectrometers operated in the mm-wave regime. Further applications and future advancements of the current instrument are discussed.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>29168510</pmid><doi>10.1039/c7cp06394f</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0001-8881-2916</orcidid><orcidid>https://orcid.org/0000-0003-4439-6716</orcidid><orcidid>https://orcid.org/0000-0002-1421-7281</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1463-9076
ispartof Physical chemistry chemical physics : PCCP, 2018, Vol.20 (8), p.5530-5544
issn 1463-9076
1463-9084
language eng
recordid cdi_proquest_miscellaneous_1967860170
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acetonitrile
Broadband
Cyanides
Emission spectra
Laboratories
Millimeter waves
Radio frequency
Radio telescopes
Reproducibility
Spectrometers
Spectrum analysis
Systematic errors
title A laboratory heterodyne emission spectrometer at submillimeter wavelengths
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T23%3A10%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20laboratory%20heterodyne%20emission%20spectrometer%20at%20submillimeter%20wavelengths&rft.jtitle=Physical%20chemistry%20chemical%20physics%20:%20PCCP&rft.au=Wehres,%20N&rft.date=2018&rft.volume=20&rft.issue=8&rft.spage=5530&rft.epage=5544&rft.pages=5530-5544&rft.issn=1463-9076&rft.eissn=1463-9084&rft_id=info:doi/10.1039/c7cp06394f&rft_dat=%3Cproquest_cross%3E2010863539%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2010863539&rft_id=info:pmid/29168510&rfr_iscdi=true