Selective photocatalytic hydroxylation and epoxidation reactions by an iron complex using water as the oxygen source

The iron complex [(bTAML)Fe -OH ] ( ) selectively catalyses the photocatalytic hydroxylation and epoxidation reactions of alkanes and alkenes, respectively, using water as the oxygen-atom source. Upon the oxidation of unactivated alkanes, which included several substrates including natural products,...

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Veröffentlicht in:	Chemical science (Cambridge) 2017, Vol.8 (11), p.7545-7551
Hauptverfasser:	Chandra, Bittu, Singh, Kundan K, Gupta, Sayam Sen
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes Alkenes Disproportionation Epoxidation Hydroxylation Iron Natural products Oxidation Oxygen atoms Selectivity Substrates
Online-Zugang:	Volltext
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