Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide

The highly efficient catalytic oxidation and oxidative kinetic resolution (OKR) of secondary alcohols has been achieved using a synthetic manganese catalyst with low loading and hydrogen peroxide as an environmentally benign oxidant in the presence of a small amount of sulfuric acid as an additive....

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Veröffentlicht in:	Chemical science (Cambridge) 2017-11, Vol.8 (11), p.7476-7482
Hauptverfasser:	Miao, Chengxia, Li, Xiao-Xi, Lee, Yong-Min, Xia, Chungu, Wang, Yong, Nam, Wonwoo, Sun, Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Catalysis Catalytic oxidation Chemistry Density functional theory Enantiomers Hydrogen peroxide Manganese Oxidation Substrates Sulfuric acid
Online-Zugang:	Volltext
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