Amine assisted top-down delamination of the two-dimensional metal–organic framework Cu2(bdc)2
A chemically assisted top-down method for the synthesis of MOF-nanoplates was developed applying amine based delamination agents. Applied on a well described model structure, the layered MOF Cu2(bdc)2(DMF)2 (bdc – 1,4-benzenedicarboxylate), two different strategies of amine assisted delamination tur...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2017, Vol.46 (47), p.16480-16484 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 16484 |
|---|---|
| container_issue | 47 |
| container_start_page | 16480 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 46 |
| creator | Kutzscher, Christel Gelbert, André Ehrling, Sebastian Schenk, Claudia Senkovska, Irena Kaskel, Stefan |
| description | A chemically assisted top-down method for the synthesis of MOF-nanoplates was developed applying amine based delamination agents. Applied on a well described model structure, the layered MOF Cu2(bdc)2(DMF)2 (bdc – 1,4-benzenedicarboxylate), two different strategies of amine assisted delamination turned out to be successful to obtain nanoplates. Particles with thicknesses of around 70 nm were obtained by direct delamination of crystals using octylamine. The surfactant (polyvinylpyrrolidone) assisted synthesis combined with a post-synthetic amine delamination step enabled a further reduction of the thickness of the MOF nanoplates down to 4–14 nm. |
| doi_str_mv | 10.1039/c7dt03890a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1966240282</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1966240282</sourcerecordid><originalsourceid>FETCH-LOGICAL-p131t-46bb5c4ee70e4f5895bae23c032b9b0fdd34adad2c83bf44875d6817806ef7d43</originalsourceid><addsrcrecordid>eNpdj89KxDAYxIMouK5efIKAl_VQTb6kSXpcFv_Bghc9l7T5ol3bZm1SevUdfEOfxILiwdMMMz8GhpBzzq44E8V1rV1iwhTMHpAFl1pnBQh5-OdBHZOTGHeMAbAcFqRcd02P1MbYxISOprDPXJh66rC1c2VTE3oaPE2vSNMUMtd02Mc5tC3tMNn26-MzDC-2b2rqB9vhFIY3uhlhVbn6Ek7JkbdtxLNfXZLn25unzX22fbx72Ky32Z4LnjKpqiqvJaJmKH1uiryyCKJmAqqiYt45Ia2zDmojKi-l0blThmvDFHrtpFiS1c_ufgjvI8ZUdk2ssW1tj2GMJS-UAsnAwIxe_EN3YRzmP7EExplRWoAR33KpZSA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2010867328</pqid></control><display><type>article</type><title>Amine assisted top-down delamination of the two-dimensional metal–organic framework Cu2(bdc)2</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Kutzscher, Christel ; Gelbert, André ; Ehrling, Sebastian ; Schenk, Claudia ; Senkovska, Irena ; Kaskel, Stefan</creator><creatorcontrib>Kutzscher, Christel ; Gelbert, André ; Ehrling, Sebastian ; Schenk, Claudia ; Senkovska, Irena ; Kaskel, Stefan</creatorcontrib><description>A chemically assisted top-down method for the synthesis of MOF-nanoplates was developed applying amine based delamination agents. Applied on a well described model structure, the layered MOF Cu2(bdc)2(DMF)2 (bdc – 1,4-benzenedicarboxylate), two different strategies of amine assisted delamination turned out to be successful to obtain nanoplates. Particles with thicknesses of around 70 nm were obtained by direct delamination of crystals using octylamine. The surfactant (polyvinylpyrrolidone) assisted synthesis combined with a post-synthetic amine delamination step enabled a further reduction of the thickness of the MOF nanoplates down to 4–14 nm.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt03890a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Delamination ; Metal-organic frameworks ; Polyvinylpyrrolidone ; Synthesis ; Thickness ; Two dimensional materials</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2017, Vol.46 (47), p.16480-16484</ispartof><rights>Copyright Royal Society of Chemistry 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,4025,27928,27929,27930</link.rule.ids></links><search><creatorcontrib>Kutzscher, Christel</creatorcontrib><creatorcontrib>Gelbert, André</creatorcontrib><creatorcontrib>Ehrling, Sebastian</creatorcontrib><creatorcontrib>Schenk, Claudia</creatorcontrib><creatorcontrib>Senkovska, Irena</creatorcontrib><creatorcontrib>Kaskel, Stefan</creatorcontrib><title>Amine assisted top-down delamination of the two-dimensional metal–organic framework Cu2(bdc)2</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A chemically assisted top-down method for the synthesis of MOF-nanoplates was developed applying amine based delamination agents. Applied on a well described model structure, the layered MOF Cu2(bdc)2(DMF)2 (bdc – 1,4-benzenedicarboxylate), two different strategies of amine assisted delamination turned out to be successful to obtain nanoplates. Particles with thicknesses of around 70 nm were obtained by direct delamination of crystals using octylamine. The surfactant (polyvinylpyrrolidone) assisted synthesis combined with a post-synthetic amine delamination step enabled a further reduction of the thickness of the MOF nanoplates down to 4–14 nm.</description><subject>Delamination</subject><subject>Metal-organic frameworks</subject><subject>Polyvinylpyrrolidone</subject><subject>Synthesis</subject><subject>Thickness</subject><subject>Two dimensional materials</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNpdj89KxDAYxIMouK5efIKAl_VQTb6kSXpcFv_Bghc9l7T5ol3bZm1SevUdfEOfxILiwdMMMz8GhpBzzq44E8V1rV1iwhTMHpAFl1pnBQh5-OdBHZOTGHeMAbAcFqRcd02P1MbYxISOprDPXJh66rC1c2VTE3oaPE2vSNMUMtd02Mc5tC3tMNn26-MzDC-2b2rqB9vhFIY3uhlhVbn6Ek7JkbdtxLNfXZLn25unzX22fbx72Ky32Z4LnjKpqiqvJaJmKH1uiryyCKJmAqqiYt45Ia2zDmojKi-l0blThmvDFHrtpFiS1c_ufgjvI8ZUdk2ssW1tj2GMJS-UAsnAwIxe_EN3YRzmP7EExplRWoAR33KpZSA</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Kutzscher, Christel</creator><creator>Gelbert, André</creator><creator>Ehrling, Sebastian</creator><creator>Schenk, Claudia</creator><creator>Senkovska, Irena</creator><creator>Kaskel, Stefan</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>2017</creationdate><title>Amine assisted top-down delamination of the two-dimensional metal–organic framework Cu2(bdc)2</title><author>Kutzscher, Christel ; Gelbert, André ; Ehrling, Sebastian ; Schenk, Claudia ; Senkovska, Irena ; Kaskel, Stefan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p131t-46bb5c4ee70e4f5895bae23c032b9b0fdd34adad2c83bf44875d6817806ef7d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Delamination</topic><topic>Metal-organic frameworks</topic><topic>Polyvinylpyrrolidone</topic><topic>Synthesis</topic><topic>Thickness</topic><topic>Two dimensional materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kutzscher, Christel</creatorcontrib><creatorcontrib>Gelbert, André</creatorcontrib><creatorcontrib>Ehrling, Sebastian</creatorcontrib><creatorcontrib>Schenk, Claudia</creatorcontrib><creatorcontrib>Senkovska, Irena</creatorcontrib><creatorcontrib>Kaskel, Stefan</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kutzscher, Christel</au><au>Gelbert, André</au><au>Ehrling, Sebastian</au><au>Schenk, Claudia</au><au>Senkovska, Irena</au><au>Kaskel, Stefan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Amine assisted top-down delamination of the two-dimensional metal–organic framework Cu2(bdc)2</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2017</date><risdate>2017</risdate><volume>46</volume><issue>47</issue><spage>16480</spage><epage>16484</epage><pages>16480-16484</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A chemically assisted top-down method for the synthesis of MOF-nanoplates was developed applying amine based delamination agents. Applied on a well described model structure, the layered MOF Cu2(bdc)2(DMF)2 (bdc – 1,4-benzenedicarboxylate), two different strategies of amine assisted delamination turned out to be successful to obtain nanoplates. Particles with thicknesses of around 70 nm were obtained by direct delamination of crystals using octylamine. The surfactant (polyvinylpyrrolidone) assisted synthesis combined with a post-synthetic amine delamination step enabled a further reduction of the thickness of the MOF nanoplates down to 4–14 nm.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c7dt03890a</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2017, Vol.46 (47), p.16480-16484 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1966240282 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Delamination Metal-organic frameworks Polyvinylpyrrolidone Synthesis Thickness Two dimensional materials |
| title | Amine assisted top-down delamination of the two-dimensional metal–organic framework Cu2(bdc)2 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T19%3A59%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Amine%20assisted%20top-down%20delamination%20of%20the%20two-dimensional%20metal%E2%80%93organic%20framework%20Cu2(bdc)2&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Kutzscher,%20Christel&rft.date=2017&rft.volume=46&rft.issue=47&rft.spage=16480&rft.epage=16484&rft.pages=16480-16484&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c7dt03890a&rft_dat=%3Cproquest%3E1966240282%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2010867328&rft_id=info:pmid/&rfr_iscdi=true |