Remote C-H insertion of vinyl cations leading to cyclopentenones
We report a Lewis acid catalyzed reaction sequence involving a 1,2-shift and subsequent C-H insertion that gives monocyclic and fused bicyclic cyclopentenone products. This reaction sequence, which is initiated by treating β-hydroxy-α-diazo ketones with a Lewis acid, proceeds through vinyl cation in...
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| Veröffentlicht in: | Chemical science (Cambridge) 2017-10, Vol.8 (10), p.6810-6814 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
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