Iron-catalyzed peroxidation-carbamoylation of alkenes with hydroperoxides and formamides via formyl C(sp 2 )-H functionalization

A reaction protocol in which FeCl and tert-butyl hydroperoxide facilitated a selective radical coupling reaction of aryl alkenes or 1,3-enynes with tert-butyl hydroperoxide and formamides to prepare an array of β-peroxy amides has been achieved. The β-peroxy amide could serve as a synthetic precurso...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2017, Vol.53 (95), p.12830-12833
Hauptverfasser:	Cheng, Jun-Kee, Shen, Liang, Wu, Liu-Hai, Hu, Xu-Hong, Loh, Teck-Peng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Amides Aromatic compounds Butyl hydroperoxide Iron chlorides
Online-Zugang:	Volltext
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