A Zn-doped Ni3S2 nanosheet array as a high-performance electrochemical water oxidation catalyst in alkaline solution
It is of high importance to design efficient electrocatalysts for the oxygen evolution reaction (OER) at alkaline pH. In this communication, we report the development of a Zn-doped Ni3S2 nanosheet array on Ni foam (Zn-Ni3S2/NF) as a high-performance and durable electrocatalyst for the OER. Such Zn-N...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2017, Vol.53 (92), p.12446-12449 |
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creator | Liu, Qin Xie, Lisi Liu, Zhiang Du, Gu Asiri, Abdullah M Sun, Xuping |
description | It is of high importance to design efficient electrocatalysts for the oxygen evolution reaction (OER) at alkaline pH. In this communication, we report the development of a Zn-doped Ni3S2 nanosheet array on Ni foam (Zn-Ni3S2/NF) as a high-performance and durable electrocatalyst for the OER. Such Zn-Ni3S2/NF drives a catalytic current density of 100 mA cm−2 with the requirement of an OER overpotential of 330 mV, 90 mV less than that for Ni3S2/NF. Furthermore, Zn-Ni3S2/NF demonstrates excellent long-term electrochemical durability maintaining its activity at an overpotential of 300 mV for 20 h. |
doi_str_mv | 10.1039/c7cc06668f |
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In this communication, we report the development of a Zn-doped Ni3S2 nanosheet array on Ni foam (Zn-Ni3S2/NF) as a high-performance and durable electrocatalyst for the OER. Such Zn-Ni3S2/NF drives a catalytic current density of 100 mA cm−2 with the requirement of an OER overpotential of 330 mV, 90 mV less than that for Ni3S2/NF. 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Furthermore, Zn-Ni3S2/NF demonstrates excellent long-term electrochemical durability maintaining its activity at an overpotential of 300 mV for 20 h.</description><subject>Catalysis</subject><subject>Durability</subject><subject>Electrocatalysts</subject><subject>Metal foams</subject><subject>Nanosheets</subject><subject>Oxidation</subject><subject>Oxygen evolution reactions</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNpdjk1LAzEYhIMoWKsXf0HAi5fVZLPJZo-l-AWiBxXES3k3edduTZM1yaL997boybnMwDwMQ8gpZxeciebS1MYwpZTu9siEC1UVstKv-7ssm6IWlTwkRymt2FZc6gnJM_rmCxsGtPShF08l9eBDWiJmCjHChkKiQJf9-7IYMHYhrsEbpOjQ5BjMEte9AUe_IGOk4bu3kPvgqYEMbpMy7T0F9wGu90hTcOOuPSYHHbiEJ38-JS_XV8_z2-L-8eZuPrsvhpKrXECtoW3QWmMaK7hAZBUAA921SmvWYs2twQ5a2TK0pagsZ6VlpjLSik4KMSXnv7tDDJ8jprxY98mgc-AxjGnBGyVLyWXdbNGzf-gqjNFv3y1KxpkWvJZK_AC9om05</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Liu, Qin</creator><creator>Xie, Lisi</creator><creator>Liu, Zhiang</creator><creator>Du, Gu</creator><creator>Asiri, Abdullah M</creator><creator>Sun, Xuping</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>2017</creationdate><title>A Zn-doped Ni3S2 nanosheet array as a high-performance electrochemical water oxidation catalyst in alkaline solution</title><author>Liu, Qin ; Xie, Lisi ; Liu, Zhiang ; Du, Gu ; Asiri, Abdullah M ; Sun, Xuping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-a78ab9eddcc9d313ee04aa0a8fb6880be71dcefab5b0ed234d102d0c4c5d3f533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Catalysis</topic><topic>Durability</topic><topic>Electrocatalysts</topic><topic>Metal foams</topic><topic>Nanosheets</topic><topic>Oxidation</topic><topic>Oxygen evolution reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Qin</creatorcontrib><creatorcontrib>Xie, Lisi</creatorcontrib><creatorcontrib>Liu, Zhiang</creatorcontrib><creatorcontrib>Du, Gu</creatorcontrib><creatorcontrib>Asiri, Abdullah M</creatorcontrib><creatorcontrib>Sun, Xuping</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Qin</au><au>Xie, Lisi</au><au>Liu, Zhiang</au><au>Du, Gu</au><au>Asiri, Abdullah M</au><au>Sun, Xuping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Zn-doped Ni3S2 nanosheet array as a high-performance electrochemical water oxidation catalyst in alkaline solution</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2017</date><risdate>2017</risdate><volume>53</volume><issue>92</issue><spage>12446</spage><epage>12449</epage><pages>12446-12449</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>It is of high importance to design efficient electrocatalysts for the oxygen evolution reaction (OER) at alkaline pH. In this communication, we report the development of a Zn-doped Ni3S2 nanosheet array on Ni foam (Zn-Ni3S2/NF) as a high-performance and durable electrocatalyst for the OER. Such Zn-Ni3S2/NF drives a catalytic current density of 100 mA cm−2 with the requirement of an OER overpotential of 330 mV, 90 mV less than that for Ni3S2/NF. Furthermore, Zn-Ni3S2/NF demonstrates excellent long-term electrochemical durability maintaining its activity at an overpotential of 300 mV for 20 h.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c7cc06668f</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Catalysis Durability Electrocatalysts Metal foams Nanosheets Oxidation Oxygen evolution reactions |
title | A Zn-doped Ni3S2 nanosheet array as a high-performance electrochemical water oxidation catalyst in alkaline solution |
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