Real-time observation of the photoionization-induced water rearrangement dynamics in the 5-hydroxyindole-water cluster by time-resolved IR spectroscopy

Solvation plays an essential role in controlling the mechanism and dynamics of chemical reactions in solution. The present study reveals that changes in the local solute-solvent interaction have a great impact on the timescale of solvent rearrangement dynamics. Time-resolved IR spectroscopy has been...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2018-01, Vol.20 (5), p.3079-3091
Hauptverfasser:	Miyazaki, Mitsuhiko, Naito, Ayumi, Ikeda, Takamasa, Klyne, Johanna, Sakota, Kenji, Sekiya, Hiroshi, Dopfer, Otto, Fujii, Masaaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactions Clusters Dynamics Hydration Infrared spectroscopy Photoionization Reaction mechanisms Solvation Spectrum analysis Time constant
Online-Zugang:	Volltext
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