Lewis Acid Triggered Vinylcyclopropane–Cyclopentene Rearrangement

We report a mild Lewis acid induced isomerization of donor–acceptor cyclopropanes, containing an alkenyl moiety and diverse electron-withdrawing group(s) at the adjacent positions, into substituted cyclopentenes. We have found that 1,1,2-trisubstituted cyclopent-3-enes were exclusively obtained in y...

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Veröffentlicht in:	Journal of organic chemistry 2018-01, Vol.83 (2), p.543-560
Hauptverfasser:	Ivanova, Olga A, Chagarovskiy, Alexey O, Shumsky, Alexey N, Krasnobrov, Vasiliy D, Levina, Irina I, Trushkov, Igor V
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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