No evidence for acid-catalyzed secondary organic aerosol formation in power plant plumes over metropolitan Atlanta, Georgia
Aircraft‐based measurements of the water‐soluble fraction of fine PM organic carbon (WSOC) and inorganic salt composition in the Atlanta, GA region were conducted in the summer of 2004. Five notable plumes of SO2, apparently from coal‐fired power plants, were intercepted, and had NH4+/SO42− molar ra...
Gespeichert in:
| Veröffentlicht in: | Geophysical research letters 2007-03, Vol.34 (6), p.n/a |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 6 |
| container_start_page | |
| container_title | Geophysical research letters |
| container_volume | 34 |
| creator | Peltier, R. E. Sullivan, A. P. Weber, R. J. Wollny, A. G. Holloway, J. S. Brock, C. A. de Gouw, J. A. Atlas, E. L. |
| description | Aircraft‐based measurements of the water‐soluble fraction of fine PM organic carbon (WSOC) and inorganic salt composition in the Atlanta, GA region were conducted in the summer of 2004. Five notable plumes of SO2, apparently from coal‐fired power plants, were intercepted, and had NH4+/SO42− molar ratios ranging from approximately 0.8 to 1.4 compared to molar ratios near 2 outside of the plumes. Sulfate aerosol concentrations increased from a regional background of 5–8 μg m−3 to as high as 19.5 μg m−3 within these plumes. No increase in WSOC concentrations was observed in plumes compared to out‐of‐plumes within a WSOC measurement uncertainty of 8%. These measurements suggest that secondary organic aerosol formation via heterogeneous acid‐catalyzed reactions within power plant plumes are not likely a significant contributor to the ambient aerosol mass loading in Atlanta and the surrounding region. Because this region is rich in both biogenic and anthropogenic volatile organic carbon (VOC), the results may be widely applicable. |
| doi_str_mv | 10.1029/2006GL028780 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_19591773</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>19591773</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4150-47e2ef65bea50d7777af94f57dbb71942ed4efecb8ce33abf9da2e37d67ef3d63</originalsourceid><addsrcrecordid>eNp9kEtv1DAUhS0EEkNhxw_wBlYN-JHEybIaQaAKRSBeYmPd2NfIkMSpnWkZ-ufxaCpgha9kX9nfOfK5hDzm7Blnon0uGKu7nolGNewO2fC2LIuGMXWXbBhrcy9UfZ88SOk7Y0wyyTfk5iJQvPIWZ4PUhUjBeFsYWGHc_0JLE5owW4h7GuI3mL2hgDGkMB7gCVYfZupnuoRrjHQZYV7zvpsw0XCVbyZcY1jC6FeY6dl6eIdT2mE28_CQ3HMwJnx0e56Qjy9ffNi-Kvq33evtWV-YklesKBUKdHU1IFTMqrzAtaWrlB0GlTMKtCU6NENjUEoYXGtBoFS2VuikreUJeXr0XWK43GFa9eSTwTH_BsMuad5WLVdKZvD0CJocMUV0eol-yuE1Z_owYf3vhDP-5NYXkoHRRZiNT381jRJlrsyJI3ftR9z_11N373shFD-YF0eRTyv-_COC-EPXSqpKf77o9Ls320_nbf9Ff5W_AfWMnEo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>19591773</pqid></control><display><type>article</type><title>No evidence for acid-catalyzed secondary organic aerosol formation in power plant plumes over metropolitan Atlanta, Georgia</title><source>Wiley Free Content</source><source>Wiley-Blackwell AGU Digital Library</source><source>Wiley Online Library Journals Frontfile Complete</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><creator>Peltier, R. E. ; Sullivan, A. P. ; Weber, R. J. ; Wollny, A. G. ; Holloway, J. S. ; Brock, C. A. ; de Gouw, J. A. ; Atlas, E. L.</creator><creatorcontrib>Peltier, R. E. ; Sullivan, A. P. ; Weber, R. J. ; Wollny, A. G. ; Holloway, J. S. ; Brock, C. A. ; de Gouw, J. A. ; Atlas, E. L.</creatorcontrib><description>Aircraft‐based measurements of the water‐soluble fraction of fine PM organic carbon (WSOC) and inorganic salt composition in the Atlanta, GA region were conducted in the summer of 2004. Five notable plumes of SO2, apparently from coal‐fired power plants, were intercepted, and had NH4+/SO42− molar ratios ranging from approximately 0.8 to 1.4 compared to molar ratios near 2 outside of the plumes. Sulfate aerosol concentrations increased from a regional background of 5–8 μg m−3 to as high as 19.5 μg m−3 within these plumes. No increase in WSOC concentrations was observed in plumes compared to out‐of‐plumes within a WSOC measurement uncertainty of 8%. These measurements suggest that secondary organic aerosol formation via heterogeneous acid‐catalyzed reactions within power plant plumes are not likely a significant contributor to the ambient aerosol mass loading in Atlanta and the surrounding region. Because this region is rich in both biogenic and anthropogenic volatile organic carbon (VOC), the results may be widely applicable.</description><identifier>ISSN: 0094-8276</identifier><identifier>EISSN: 1944-8007</identifier><identifier>DOI: 10.1029/2006GL028780</identifier><identifier>CODEN: GPRLAJ</identifier><language>eng</language><publisher>Washington, DC: Blackwell Publishing Ltd</publisher><subject>Earth sciences ; Earth, ocean, space ; Exact sciences and technology ; organic ; SOA ; WSOC</subject><ispartof>Geophysical research letters, 2007-03, Vol.34 (6), p.n/a</ispartof><rights>Copyright 2007 by the American Geophysical Union.</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4150-47e2ef65bea50d7777af94f57dbb71942ed4efecb8ce33abf9da2e37d67ef3d63</citedby><cites>FETCH-LOGICAL-c4150-47e2ef65bea50d7777af94f57dbb71942ed4efecb8ce33abf9da2e37d67ef3d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1029%2F2006GL028780$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1029%2F2006GL028780$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,1427,11493,27901,27902,45550,45551,46384,46443,46808,46867</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18724242$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Peltier, R. E.</creatorcontrib><creatorcontrib>Sullivan, A. P.</creatorcontrib><creatorcontrib>Weber, R. J.</creatorcontrib><creatorcontrib>Wollny, A. G.</creatorcontrib><creatorcontrib>Holloway, J. S.</creatorcontrib><creatorcontrib>Brock, C. A.</creatorcontrib><creatorcontrib>de Gouw, J. A.</creatorcontrib><creatorcontrib>Atlas, E. L.</creatorcontrib><title>No evidence for acid-catalyzed secondary organic aerosol formation in power plant plumes over metropolitan Atlanta, Georgia</title><title>Geophysical research letters</title><addtitle>Geophys. Res. Lett</addtitle><description>Aircraft‐based measurements of the water‐soluble fraction of fine PM organic carbon (WSOC) and inorganic salt composition in the Atlanta, GA region were conducted in the summer of 2004. Five notable plumes of SO2, apparently from coal‐fired power plants, were intercepted, and had NH4+/SO42− molar ratios ranging from approximately 0.8 to 1.4 compared to molar ratios near 2 outside of the plumes. Sulfate aerosol concentrations increased from a regional background of 5–8 μg m−3 to as high as 19.5 μg m−3 within these plumes. No increase in WSOC concentrations was observed in plumes compared to out‐of‐plumes within a WSOC measurement uncertainty of 8%. These measurements suggest that secondary organic aerosol formation via heterogeneous acid‐catalyzed reactions within power plant plumes are not likely a significant contributor to the ambient aerosol mass loading in Atlanta and the surrounding region. Because this region is rich in both biogenic and anthropogenic volatile organic carbon (VOC), the results may be widely applicable.</description><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Exact sciences and technology</subject><subject>organic</subject><subject>SOA</subject><subject>WSOC</subject><issn>0094-8276</issn><issn>1944-8007</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp9kEtv1DAUhS0EEkNhxw_wBlYN-JHEybIaQaAKRSBeYmPd2NfIkMSpnWkZ-ufxaCpgha9kX9nfOfK5hDzm7Blnon0uGKu7nolGNewO2fC2LIuGMXWXbBhrcy9UfZ88SOk7Y0wyyTfk5iJQvPIWZ4PUhUjBeFsYWGHc_0JLE5owW4h7GuI3mL2hgDGkMB7gCVYfZupnuoRrjHQZYV7zvpsw0XCVbyZcY1jC6FeY6dl6eIdT2mE28_CQ3HMwJnx0e56Qjy9ffNi-Kvq33evtWV-YklesKBUKdHU1IFTMqrzAtaWrlB0GlTMKtCU6NENjUEoYXGtBoFS2VuikreUJeXr0XWK43GFa9eSTwTH_BsMuad5WLVdKZvD0CJocMUV0eol-yuE1Z_owYf3vhDP-5NYXkoHRRZiNT381jRJlrsyJI3ftR9z_11N373shFD-YF0eRTyv-_COC-EPXSqpKf77o9Ls320_nbf9Ff5W_AfWMnEo</recordid><startdate>200703</startdate><enddate>200703</enddate><creator>Peltier, R. E.</creator><creator>Sullivan, A. P.</creator><creator>Weber, R. J.</creator><creator>Wollny, A. G.</creator><creator>Holloway, J. S.</creator><creator>Brock, C. A.</creator><creator>de Gouw, J. A.</creator><creator>Atlas, E. L.</creator><general>Blackwell Publishing Ltd</general><general>American Geophysical Union</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7TG</scope><scope>7TV</scope><scope>7U6</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>KL.</scope><scope>L.G</scope></search><sort><creationdate>200703</creationdate><title>No evidence for acid-catalyzed secondary organic aerosol formation in power plant plumes over metropolitan Atlanta, Georgia</title><author>Peltier, R. E. ; Sullivan, A. P. ; Weber, R. J. ; Wollny, A. G. ; Holloway, J. S. ; Brock, C. A. ; de Gouw, J. A. ; Atlas, E. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4150-47e2ef65bea50d7777af94f57dbb71942ed4efecb8ce33abf9da2e37d67ef3d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Exact sciences and technology</topic><topic>organic</topic><topic>SOA</topic><topic>WSOC</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peltier, R. E.</creatorcontrib><creatorcontrib>Sullivan, A. P.</creatorcontrib><creatorcontrib>Weber, R. J.</creatorcontrib><creatorcontrib>Wollny, A. G.</creatorcontrib><creatorcontrib>Holloway, J. S.</creatorcontrib><creatorcontrib>Brock, C. A.</creatorcontrib><creatorcontrib>de Gouw, J. A.</creatorcontrib><creatorcontrib>Atlas, E. L.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Geophysical research letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peltier, R. E.</au><au>Sullivan, A. P.</au><au>Weber, R. J.</au><au>Wollny, A. G.</au><au>Holloway, J. S.</au><au>Brock, C. A.</au><au>de Gouw, J. A.</au><au>Atlas, E. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>No evidence for acid-catalyzed secondary organic aerosol formation in power plant plumes over metropolitan Atlanta, Georgia</atitle><jtitle>Geophysical research letters</jtitle><addtitle>Geophys. Res. Lett</addtitle><date>2007-03</date><risdate>2007</risdate><volume>34</volume><issue>6</issue><epage>n/a</epage><issn>0094-8276</issn><eissn>1944-8007</eissn><coden>GPRLAJ</coden><abstract>Aircraft‐based measurements of the water‐soluble fraction of fine PM organic carbon (WSOC) and inorganic salt composition in the Atlanta, GA region were conducted in the summer of 2004. Five notable plumes of SO2, apparently from coal‐fired power plants, were intercepted, and had NH4+/SO42− molar ratios ranging from approximately 0.8 to 1.4 compared to molar ratios near 2 outside of the plumes. Sulfate aerosol concentrations increased from a regional background of 5–8 μg m−3 to as high as 19.5 μg m−3 within these plumes. No increase in WSOC concentrations was observed in plumes compared to out‐of‐plumes within a WSOC measurement uncertainty of 8%. These measurements suggest that secondary organic aerosol formation via heterogeneous acid‐catalyzed reactions within power plant plumes are not likely a significant contributor to the ambient aerosol mass loading in Atlanta and the surrounding region. Because this region is rich in both biogenic and anthropogenic volatile organic carbon (VOC), the results may be widely applicable.</abstract><cop>Washington, DC</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1029/2006GL028780</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-8276 |
| ispartof | Geophysical research letters, 2007-03, Vol.34 (6), p.n/a |
| issn | 0094-8276 1944-8007 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_19591773 |
| source | Wiley Free Content; Wiley-Blackwell AGU Digital Library; Wiley Online Library Journals Frontfile Complete; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| subjects | Earth sciences Earth, ocean, space Exact sciences and technology organic SOA WSOC |
| title | No evidence for acid-catalyzed secondary organic aerosol formation in power plant plumes over metropolitan Atlanta, Georgia |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T08%3A22%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=No%20evidence%20for%20acid-catalyzed%20secondary%20organic%20aerosol%20formation%20in%20power%20plant%20plumes%20over%20metropolitan%20Atlanta,%20Georgia&rft.jtitle=Geophysical%20research%20letters&rft.au=Peltier,%20R.%20E.&rft.date=2007-03&rft.volume=34&rft.issue=6&rft.epage=n/a&rft.issn=0094-8276&rft.eissn=1944-8007&rft.coden=GPRLAJ&rft_id=info:doi/10.1029/2006GL028780&rft_dat=%3Cproquest_cross%3E19591773%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=19591773&rft_id=info:pmid/&rfr_iscdi=true |