Copper-Catalyzed Ligand-Free Diazidation of Olefins with TMSN3 in CH3CN or in H2O

An environmentally benign, copper-catalyzed diazidation of a broad range of olefins, including vinylarenes, unactivated alkenes, allene, and dienes, under mild conditions with TMSN3 (trimethylazidosilane) as azido source, has been developed. This reaction can be carried out in organic solvent or in...

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Veröffentlicht in:	Organic letters 2017-11, Vol.19 (22), p.6120-6123
Hauptverfasser:	Zhou, Huan, Jian, Wujun, Qian, Bo, Ye, Changqing, Li, Daliang, Zhou, Jing, Bao, Hongli
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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