Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers
The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably...
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Veröffentlicht in: | Environmental pollution (1987) 2007-02, Vol.145 (3), p.920-927 |
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creator | Schubert, Michael Paschke, Albrecht Lau, Steffen Geyer, Wolfgang Knöller, Kay |
description | The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably into the NAPL. The magnitude of the resulting radon deficit in the groundwater depends on the NAPL-specific radon partition coefficient and on the NAPL saturation of the pore space. Hence, if the partition coefficient is known, the NAPL saturation is attainable by determination of the radon deficit. After a concise discussion of theoretical aspects regarding radon partitioning into NAPL, related experimental data and results of a field investigation are presented. Aim of the laboratory experiments was the determination of radon partition coefficients of multi-component NAPLs of environmental concern. The on-site activities were carried out in order to confirm the applicability of the “radon method” under field conditions.
The paper presents the theoretical concept and experimental results which confirm the applicability of naturally occurring radon for assessing residual NAPL contamination of aquifers. |
doi_str_mv | 10.1016/j.envpol.2006.04.029 |
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The paper presents the theoretical concept and experimental results which confirm the applicability of naturally occurring radon for assessing residual NAPL contamination of aquifers.</description><identifier>ISSN: 0269-7491</identifier><identifier>EISSN: 1873-6424</identifier><identifier>DOI: 10.1016/j.envpol.2006.04.029</identifier><identifier>PMID: 16781031</identifier><identifier>CODEN: ENVPAF</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; aquifers ; Contamination ; Earth sciences ; Earth, ocean, space ; Engineering and environment geology. Geothermics ; environmental monitoring ; Environmental Pollutants - analysis ; Exact sciences and technology ; field experimentation ; Fresh Water - analysis ; groundwater ; groundwater contamination ; Groundwaters ; laboratory techniques ; liquids ; Mathematics ; NAPL ; Natural water pollution ; partition coefficients ; Partitioning tracer ; pollutants ; Pollution ; Pollution, environment geology ; Radioactive Tracers ; Radon ; Radon - analysis ; simulation models ; Soil Pollutants ; Solubility ; Thermodynamics ; Water Pollutants - analysis ; Water treatment and pollution</subject><ispartof>Environmental pollution (1987), 2007-02, Vol.145 (3), p.920-927</ispartof><rights>2006 Elsevier Ltd</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a468t-272e91ad23226bc76c08591fc1e1d9bcca4fd04391fa1327e157fda6c9c6dd4a3</citedby><cites>FETCH-LOGICAL-a468t-272e91ad23226bc76c08591fc1e1d9bcca4fd04391fa1327e157fda6c9c6dd4a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.envpol.2006.04.029$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18491918$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16781031$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schubert, Michael</creatorcontrib><creatorcontrib>Paschke, Albrecht</creatorcontrib><creatorcontrib>Lau, Steffen</creatorcontrib><creatorcontrib>Geyer, Wolfgang</creatorcontrib><creatorcontrib>Knöller, Kay</creatorcontrib><title>Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers</title><title>Environmental pollution (1987)</title><addtitle>Environ Pollut</addtitle><description>The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably into the NAPL. The magnitude of the resulting radon deficit in the groundwater depends on the NAPL-specific radon partition coefficient and on the NAPL saturation of the pore space. Hence, if the partition coefficient is known, the NAPL saturation is attainable by determination of the radon deficit. After a concise discussion of theoretical aspects regarding radon partitioning into NAPL, related experimental data and results of a field investigation are presented. Aim of the laboratory experiments was the determination of radon partition coefficients of multi-component NAPLs of environmental concern. The on-site activities were carried out in order to confirm the applicability of the “radon method” under field conditions.
The paper presents the theoretical concept and experimental results which confirm the applicability of naturally occurring radon for assessing residual NAPL contamination of aquifers.</description><subject>Applied sciences</subject><subject>aquifers</subject><subject>Contamination</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. Geothermics</subject><subject>environmental monitoring</subject><subject>Environmental Pollutants - analysis</subject><subject>Exact sciences and technology</subject><subject>field experimentation</subject><subject>Fresh Water - analysis</subject><subject>groundwater</subject><subject>groundwater contamination</subject><subject>Groundwaters</subject><subject>laboratory techniques</subject><subject>liquids</subject><subject>Mathematics</subject><subject>NAPL</subject><subject>Natural water pollution</subject><subject>partition coefficients</subject><subject>Partitioning tracer</subject><subject>pollutants</subject><subject>Pollution</subject><subject>Pollution, environment geology</subject><subject>Radioactive Tracers</subject><subject>Radon</subject><subject>Radon - analysis</subject><subject>simulation models</subject><subject>Soil Pollutants</subject><subject>Solubility</subject><subject>Thermodynamics</subject><subject>Water Pollutants - analysis</subject><subject>Water treatment and pollution</subject><issn>0269-7491</issn><issn>1873-6424</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kU2LFDEQhoMo7jj6D0Rz0Vu3-Zqk-yIsi18wqKh7DjVJZc3Q3ZlNuhf235ulB_bmKVB56qXqKUJec9ZyxvWHY4vT3SkNrWBMt0y1TPRPyIZ3RjZaCfWUbJjQfWNUzy_Ii1KOjDElpXxOLrg2HWeSb4j7BT5NFAoFOsG8ZBiGe5qcW3KO0w2dMzjMNKRM579YuYKljDjNNAWasUS_wEC_X_7cU5emGcZYU2JNrN9wu8SAubwkzwIMBV-d3y25_vzpz9XXZv_jy7ery30DSndzI4zAnoMXUgh9cEY71u16HhxH7vuDc6CCrxvUEnApDPKdCR606532XoHckvdr7imn2wXLbMdYHA4DTJiWYnm_M50wpoJqBV1OpWQM9pTjCPnecmYf5NqjXeXaB7mWKVvl1rY35_zlMKJ_bDrbrMC7MwDFwRAyTC6WR66rp-h5V7m3KxcgWbjJlbn-LRiXjBktWb3RlnxcCay-7iJmW1zEyaGPGd1sfYr_n_Ufk1WkVw</recordid><startdate>20070201</startdate><enddate>20070201</enddate><creator>Schubert, Michael</creator><creator>Paschke, Albrecht</creator><creator>Lau, Steffen</creator><creator>Geyer, Wolfgang</creator><creator>Knöller, Kay</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7TG</scope><scope>7TV</scope><scope>7U7</scope><scope>7UA</scope><scope>C1K</scope><scope>KL.</scope></search><sort><creationdate>20070201</creationdate><title>Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers</title><author>Schubert, Michael ; Paschke, Albrecht ; Lau, Steffen ; Geyer, Wolfgang ; Knöller, Kay</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a468t-272e91ad23226bc76c08591fc1e1d9bcca4fd04391fa1327e157fda6c9c6dd4a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>aquifers</topic><topic>Contamination</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Engineering and environment geology. Geothermics</topic><topic>environmental monitoring</topic><topic>Environmental Pollutants - analysis</topic><topic>Exact sciences and technology</topic><topic>field experimentation</topic><topic>Fresh Water - analysis</topic><topic>groundwater</topic><topic>groundwater contamination</topic><topic>Groundwaters</topic><topic>laboratory techniques</topic><topic>liquids</topic><topic>Mathematics</topic><topic>NAPL</topic><topic>Natural water pollution</topic><topic>partition coefficients</topic><topic>Partitioning tracer</topic><topic>pollutants</topic><topic>Pollution</topic><topic>Pollution, environment geology</topic><topic>Radioactive Tracers</topic><topic>Radon</topic><topic>Radon - analysis</topic><topic>simulation models</topic><topic>Soil Pollutants</topic><topic>Solubility</topic><topic>Thermodynamics</topic><topic>Water Pollutants - analysis</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schubert, Michael</creatorcontrib><creatorcontrib>Paschke, Albrecht</creatorcontrib><creatorcontrib>Lau, Steffen</creatorcontrib><creatorcontrib>Geyer, Wolfgang</creatorcontrib><creatorcontrib>Knöller, Kay</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><jtitle>Environmental pollution (1987)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schubert, Michael</au><au>Paschke, Albrecht</au><au>Lau, Steffen</au><au>Geyer, Wolfgang</au><au>Knöller, Kay</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers</atitle><jtitle>Environmental pollution (1987)</jtitle><addtitle>Environ Pollut</addtitle><date>2007-02-01</date><risdate>2007</risdate><volume>145</volume><issue>3</issue><spage>920</spage><epage>927</epage><pages>920-927</pages><issn>0269-7491</issn><eissn>1873-6424</eissn><coden>ENVPAF</coden><abstract>The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably into the NAPL. The magnitude of the resulting radon deficit in the groundwater depends on the NAPL-specific radon partition coefficient and on the NAPL saturation of the pore space. Hence, if the partition coefficient is known, the NAPL saturation is attainable by determination of the radon deficit. After a concise discussion of theoretical aspects regarding radon partitioning into NAPL, related experimental data and results of a field investigation are presented. Aim of the laboratory experiments was the determination of radon partition coefficients of multi-component NAPLs of environmental concern. The on-site activities were carried out in order to confirm the applicability of the “radon method” under field conditions.
The paper presents the theoretical concept and experimental results which confirm the applicability of naturally occurring radon for assessing residual NAPL contamination of aquifers.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>16781031</pmid><doi>10.1016/j.envpol.2006.04.029</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences aquifers Contamination Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics environmental monitoring Environmental Pollutants - analysis Exact sciences and technology field experimentation Fresh Water - analysis groundwater groundwater contamination Groundwaters laboratory techniques liquids Mathematics NAPL Natural water pollution partition coefficients Partitioning tracer pollutants Pollution Pollution, environment geology Radioactive Tracers Radon Radon - analysis simulation models Soil Pollutants Solubility Thermodynamics Water Pollutants - analysis Water treatment and pollution |
title | Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers |
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