Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers

The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably...

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Veröffentlicht in:Environmental pollution (1987) 2007-02, Vol.145 (3), p.920-927
Hauptverfasser: Schubert, Michael, Paschke, Albrecht, Lau, Steffen, Geyer, Wolfgang, Knöller, Kay
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container_end_page 927
container_issue 3
container_start_page 920
container_title Environmental pollution (1987)
container_volume 145
creator Schubert, Michael
Paschke, Albrecht
Lau, Steffen
Geyer, Wolfgang
Knöller, Kay
description The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably into the NAPL. The magnitude of the resulting radon deficit in the groundwater depends on the NAPL-specific radon partition coefficient and on the NAPL saturation of the pore space. Hence, if the partition coefficient is known, the NAPL saturation is attainable by determination of the radon deficit. After a concise discussion of theoretical aspects regarding radon partitioning into NAPL, related experimental data and results of a field investigation are presented. Aim of the laboratory experiments was the determination of radon partition coefficients of multi-component NAPLs of environmental concern. The on-site activities were carried out in order to confirm the applicability of the “radon method” under field conditions. The paper presents the theoretical concept and experimental results which confirm the applicability of naturally occurring radon for assessing residual NAPL contamination of aquifers.
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That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably into the NAPL. The magnitude of the resulting radon deficit in the groundwater depends on the NAPL-specific radon partition coefficient and on the NAPL saturation of the pore space. Hence, if the partition coefficient is known, the NAPL saturation is attainable by determination of the radon deficit. After a concise discussion of theoretical aspects regarding radon partitioning into NAPL, related experimental data and results of a field investigation are presented. Aim of the laboratory experiments was the determination of radon partition coefficients of multi-component NAPLs of environmental concern. The on-site activities were carried out in order to confirm the applicability of the “radon method” under field conditions. 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Geothermics</topic><topic>environmental monitoring</topic><topic>Environmental Pollutants - analysis</topic><topic>Exact sciences and technology</topic><topic>field experimentation</topic><topic>Fresh Water - analysis</topic><topic>groundwater</topic><topic>groundwater contamination</topic><topic>Groundwaters</topic><topic>laboratory techniques</topic><topic>liquids</topic><topic>Mathematics</topic><topic>NAPL</topic><topic>Natural water pollution</topic><topic>partition coefficients</topic><topic>Partitioning tracer</topic><topic>pollutants</topic><topic>Pollution</topic><topic>Pollution, environment geology</topic><topic>Radioactive Tracers</topic><topic>Radon</topic><topic>Radon - analysis</topic><topic>simulation models</topic><topic>Soil Pollutants</topic><topic>Solubility</topic><topic>Thermodynamics</topic><topic>Water Pollutants - analysis</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schubert, Michael</creatorcontrib><creatorcontrib>Paschke, Albrecht</creatorcontrib><creatorcontrib>Lau, Steffen</creatorcontrib><creatorcontrib>Geyer, Wolfgang</creatorcontrib><creatorcontrib>Knöller, Kay</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Meteorological &amp; Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Meteorological &amp; Geoastrophysical Abstracts - Academic</collection><jtitle>Environmental pollution (1987)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schubert, Michael</au><au>Paschke, Albrecht</au><au>Lau, Steffen</au><au>Geyer, Wolfgang</au><au>Knöller, Kay</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers</atitle><jtitle>Environmental pollution (1987)</jtitle><addtitle>Environ Pollut</addtitle><date>2007-02-01</date><risdate>2007</risdate><volume>145</volume><issue>3</issue><spage>920</spage><epage>927</epage><pages>920-927</pages><issn>0269-7491</issn><eissn>1873-6424</eissn><coden>ENVPAF</coden><abstract>The noble gas radon has a strong affinity to non-aqueous phase-liquids (NAPLs). That property makes it applicable as naturally occurring partitioning tracer for assessing residual NAPL contamination of aquifers. In a NAPL contaminated aquifer, radon dissolved in the groundwater partitions preferably into the NAPL. The magnitude of the resulting radon deficit in the groundwater depends on the NAPL-specific radon partition coefficient and on the NAPL saturation of the pore space. Hence, if the partition coefficient is known, the NAPL saturation is attainable by determination of the radon deficit. After a concise discussion of theoretical aspects regarding radon partitioning into NAPL, related experimental data and results of a field investigation are presented. Aim of the laboratory experiments was the determination of radon partition coefficients of multi-component NAPLs of environmental concern. The on-site activities were carried out in order to confirm the applicability of the “radon method” under field conditions. 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source MEDLINE; Access via ScienceDirect (Elsevier)
subjects Applied sciences
aquifers
Contamination
Earth sciences
Earth, ocean, space
Engineering and environment geology. Geothermics
environmental monitoring
Environmental Pollutants - analysis
Exact sciences and technology
field experimentation
Fresh Water - analysis
groundwater
groundwater contamination
Groundwaters
laboratory techniques
liquids
Mathematics
NAPL
Natural water pollution
partition coefficients
Partitioning tracer
pollutants
Pollution
Pollution, environment geology
Radioactive Tracers
Radon
Radon - analysis
simulation models
Soil Pollutants
Solubility
Thermodynamics
Water Pollutants - analysis
Water treatment and pollution
title Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers
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