Cyclometalated Ir(iii) complexes incorporating a photoactive anthracene-based ligand: syntheses, crystal structures and luminescence switching by light irradiation

Two cyclometalated complexes [Ir(dfppy) (aip)](PF ) (1) and [Ir(ppy) (aip)](PF ) (2) have been synthesized based on a photoactive anthracene-based ligand aip and cyclometalating ligands dfppyH and ppyH [dfppyH = (2-(2,4-difluorophenyl)-pyridine), ppyH = 2-phenyl-pyridine]. Their crystal structures i...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2017, Vol.46 (44), p.15443-15450
Hauptverfasser:	Gao, Tai-Bao, Qu, Zhong-Ze, Tang, Zhe, Cao, Deng-Ke
Format:	Artikel
Sprache:	eng
Schlagworte:	Anthracene Chelates Crystal structure Emission Imidazole Iridium Ligands Light irradiation Luminescence Luminescence quenching Oxidation Switching
Online-Zugang:	Volltext
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