Matrix Infrared Spectra of Insertion and Metallacyclopropane Complexes [CH3CH2–MH and (CH2)2–MH2] Prepared in Reactions of Laser-Ablated Group 3 Metal Atoms with Ethane

CH3CH2–MH and (CH2)2–MH2 were identified in the matrix IR spectra from reactions of laser-ablated group 3 metal atoms with ethane, and they were characterized via theoretical investigations. The observed products are the most stable in the proposed reaction path. Because of the small number of valen...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2017-11, Vol.121 (45), p.8583-8595
Hauptverfasser:	Cho, Han-Gook, Andrews, Lester
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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