Sonogashira (Cu and amine free) and Suzuki coupling in air catalyzed via nanoparticles formed in situ from Pd(ii) complexes of chalcogenated Schiff bases of 1-naphthaldehyde and their reduced forms

The reaction of 1-naphthaldehyde with 2-(phenylthio/seleno)ethylamine afforded air- and moisture-insensitive Schiff bases: C H -1-CH[double bond, length as m-dash]N-CH CH EPh (L1: E = S; L2: E = Se). Then, on treatment with NaOAc and Li PdCl , palladacycles, [Pd(L1-H/L2-H)Cl] (1/2) were formed at ro...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2017, Vol.46 (44), p.15235-15248
Hauptverfasser:	Bhaskar, Renu, Sharma, Alpesh K, Yadav, Manoj K, Singh, Ajai K
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysis Catalysts Chemical reactions Conversion Copper Coupling Crystal structure Halides Imines Ligands Nanoparticles NMR Nuclear magnetic resonance Palladium Single crystals Substrates
Online-Zugang:	Volltext
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